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Study on Stereochemical Activity of Lone Pair Electrons in Sulfur and Halogen Coordinated Antimony(III) Complexes by 121Sb Mössbauer Spectroscopy

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LACAME 2004

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Abstract

We have measured 121Sb Mössbauer spectra at 20 K for 52 compounds of antimony(III). An Sb(III) atom with the electron configuration [Kr] 4d 105s 2 has a lone pair electrons. The stereochemical property of the lone pair has been found to depend very much on the kinds of atoms surrounding the antimony atom and the configurations of the coordinating atoms.

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Author information

Author notes

  1. Ryuhichi Ohyama

    Present address: Tama Chemicals Co., Ltd., 3-22-9, Shiohama, Kawasaki-ku, Kawasaki City, Kanagawa, 210-0826, Japan

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Toho University, Miyama, Funabashi, Chiba, 274-8510, Japan

    Ryuhichi Ohyama, Masashi Takahashi & Masuo Takeda

Authors
  1. Ryuhichi Ohyama
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  2. Masashi Takahashi
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  3. Masuo Takeda
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Corresponding author

Correspondence to Masuo Takeda .

Editor information

Editors and Affiliations

  1. Universidad Nacional de La Plata, La Plata, Argentina

    R. C. Mercader

  2. Instituto de Quimica Fisica Rocasolano, Madrid, Spain

    J. R. Gancedo

  3. Instituto Nacional de Investigaciones Nucleares, Mexico City, Mexico

    A. Cabral Prieto

  4. Centro Brasileiro de Pesquisas Físicas, Rio de Janeiro, Brazil

    E. Baggio-Saitovitch

Additional information

Dedicated to Prof. Philipp Gütlich’s 70th birthday.

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© 2005 Springer

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Ohyama, R., Takahashi, M., Takeda, M. (2005). Study on Stereochemical Activity of Lone Pair Electrons in Sulfur and Halogen Coordinated Antimony(III) Complexes by 121Sb Mössbauer Spectroscopy. In: Mercader, R.C., Gancedo, J.R., Cabral Prieto, A., Baggio-Saitovitch, E. (eds) LACAME 2004. Springer, Berlin, Heidelberg . https://doi.org/10.1007/3-540-28960-7_11

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