Skip to main content

The Selective Chemistry of Single Walled Carbon Nanotubes

  • Chapter
Book cover Applied Physics of Carbon Nanotubes

Part of the book series: NanoScience and Technology ((NANO))

Abstract

Functionalization of solution-phase carbon nanotubes has led to promising developments in nanotube science. Covalent interactions place organic functional groups on the nanotube sidewall, and certain moieties, such as diazonium salts exhibit preferential reactivity based on electronic structure. Concurrent developments in spectroscopic tools facilitate the monitoring of these reactions as well as the nanotubes' local environment. Non-covalent interactions on the nanotube surface are diverse and selective, including solvatochromatic shifts and charge transfer. This review describes covalent and non-covalent nanotube chemistries as well as methods of spectroscopic analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Avouris, P.: Acc. Chem. Res. 35, 1026, (2002)

    Article  PubMed  Google Scholar 

  2. Dresselhaus, M.S., Dresselhaus, G., and Eklund, P.C. Science of fullerenes and carbon nanotubes (San Diego: Academic Press, 1996)

    Google Scholar 

  3. Saito, R., Dresselhaus, G., and Dresselhaus, M.S. Physical Properties of Carbon Nanotubes (London: Imperial College Press, 1998)

    Google Scholar 

  4. Thess, A., Lee, R., Nikolaev, P., Dai, H.J., Petit, P., Robert, J., Xu, C.H., Lee, Y.H., Kim, S.G., Rinzler, A.G., Colbert, D.T., Scuseria, G.E., Tomanek, D., Fischer, J.E., and Smalley, R.E.: Science 273, 483,(1996)

    PubMed  Google Scholar 

  5. O'Connell, M.J., Boul, P., Ericson, L.M., Huffman, C., Wang, Y.H., Haroz, E., Kuper, C., Tour, J., Ausman, K.D., and Smalley, R.E.: Chemical Physics Letters 342, 265,(2001)

    Article  Google Scholar 

  6. Strano, M.S., Doorn, S.K., Haroz, E.H., Kittrell, C., Hauge, R.H., and Smalley, R.E.: Nano Letters 3, 1091,(2003)

    Article  Google Scholar 

  7. Bachilo, S.M., Strano, M.S., Kittrell, C., Hauge, R.H., Smalley, R.E., and Weisman, R.B.: Science 298, 2361,(2002)

    Article  PubMed  Google Scholar 

  8. Kukovecz, A., Kramberger, C., Georgakilas, V., Prato, M., and Kuzmany, H.: Eur. Phys. J. B 28, 223, (2002)

    Article  Google Scholar 

  9. Rao, A.M., Richter, E., Bandow, S., Chase, B., Eklund, P.C., Williams, K.A., Fang, S., Subbaswamy, K.R., Menon, M., Thess, A., Smalley, R.E., Dresselhaus, G., and Dresselhaus, M.S.: Science 275, 187, (1997)

    Article  PubMed  Google Scholar 

  10. Strano, M.S., Huffman, C.B., Moore, V.C., O'Connell, M.J., Haroz, E.H., Hubbard, J., Miller, M., Rialon, K., Kittrell, C., Ramesh, S., Hauge, R.H., and Smalley, R.E.: Journal of Physical Chemistry B 107, 6979, (2003)

    Article  Google Scholar 

  11. Bronikowski, M.J., Willis, P.A., Colbert, D.T., Smith, K.A., and Smalley, R., E. (2001): Journal of Vacuum Science & Technology,(2001)

    Google Scholar 

  12. Canonico, M., Adams, G.B., Poweleit, C., Menendez, J., Page, J.B., Harris, G., van der Meulen, H.P., Calleja, J.M., and Rubio, J.: Physical Review B 65, art. no.201402.(2002)

    Google Scholar 

  13. Saito, R., Grueneis, A., Cancado, L.G., Pimenta, M.A., Jorio, A., Dresselhaus, G., Dresselhaus, M.S., and Souza, A.G.: Molecular Crystals and Liquid Crystals 387, 287, (2002)

    Google Scholar 

  14. Saito, R., Jorio, A., Hafner, J.H., Lieber, C.M., Hunter, M., McClure, T., Dresselhaus, G., and Dresselhaus, M.S.: Physical Review B 6408, art. no.085312, (2001)

    Google Scholar 

  15. Jorio, A., Fantini, C., Dantas, M.S.S., Pimenta, M.A., Souza, A.G., Samsonidze, G.G., Brar, V.W., Dresselhaus, G., Dresselhaus, M.S., Swan, A.K., Unlu, M.S., Goldberg, B.B., and Saito, R.: Physical Review B 66, art. no.115411, (2002)

    Google Scholar 

  16. Jorio, A., Matinaga, F.M., Righi, A., Dantas, M.S.S., Pimenta, M.A., Souza, A.G., Mendes, J., Hafner, J.H., Lieber, C.M., Saito, R., Dresselhaus, G., and Dresselhaus, M.S.: Brazilian Journal of Physics 32, 921, (2002)

    Article  Google Scholar 

  17. Jorio, A., Souza, A.G., Dresselhaus, G., Dresselhaus, M.S., Swan, A.K., Unlu, M.S., Goldberg, B.B., Pimenta, M.A., Hafner, J.H., Lieber, C.M., and Saito, R.: Physical Review B 65, art. no.155412,(2002)

    Google Scholar 

  18. Dresselhaus, M.S., Dresselhaus, G., Jorio, A., Souza, A.G., Pimenta, M.A., and Saito, R. (2002): Accounts of Chemical Research 35, 1070,(2002)

    Article  PubMed  Google Scholar 

  19. Dresselhaus, M.S., Dresselhaus, G., Jorio, A., Souza, A.G., and Saito, R.: Carbon 40, 2043,(2002)

    Article  Google Scholar 

  20. Yu, Z.H., and Brus, L.E.: Journal of Physical Chemistry B 105, 6831,(2001)

    Article  Google Scholar 

  21. Yu, Z.H., and Brus, L.E.: J. Phys. Chem. A. 104, 10995, (2000)

    Article  Google Scholar 

  22. Saito, R., Dresselhaus, G., and Dresselhaus, M.S.: Physical Review B 61, 2981,(2000)

    Article  Google Scholar 

  23. Reich, S., Maultzsch, J., Thomsen, C., and Ordejon, P.: Physical Review B 66, 035412,(2002)

    Article  Google Scholar 

  24. Reich, S., and Thomsen, C.: Physical Review B 62, 4273,(2000)

    Article  Google Scholar 

  25. O'Connell, M.J., Bachilo, S.M., Huffman, C.B., Moore, V.C., Strano, M.S., Haroz, E.H., Rialon, K.L., Boul, P.J., Noon, W.H., Kittrell, C., Ma, J.P., Hauge, R.H., Weisman, R.B., and Smalley, R.E.: Science 297, 593, (2002)

    Article  PubMed  Google Scholar 

  26. Sauvajol, J.L., Anglaret, E., Rols, S., and Alvarez, L.: Carbon 40, 1697,(2002)

    Article  Google Scholar 

  27. Liu, J., Rinzler, A.G., Dai, H.J., Hafner, J.H., Bradley, R.K., Boul, P.J., Lu, A., Iverson, T., Shelimov, K., Huffman, C.B., Rodriguez-Macias, F., Shon, Y.S., Lee, T.R., Colbert, D.T., and Smalley, R.E.: Science 280, 1253,(1998)

    Article  PubMed  MathSciNet  Google Scholar 

  28. A.G. Rinzler, J.L., H. Dai, P. Nikolaev, C.B. Huffman, F.J. Rodriguez-Macias, P.J. Boul, A.H. Lu, D. Heymann, D.T. Colbert, R.S. Lee, J.E. Fischer, A.M. Rao, P.C. Eklund and R.E. Smalley: Applied Physics A 67, 29,(1998)

    Article  Google Scholar 

  29. Mawhinney, D.B., Naumenko, V., Kuznetsova, A., Yates, J.T., Liu, J., and Smalley, R.E.: Chemical Physics Letters 324, 213, (2000)

    Article  Google Scholar 

  30. Mawhinney, D.B., Naumenko, V., Kuznetsova, A., Yates, J.T., Liu, J., and Smalley, R.E.: Journal of the American Chemical Society 122, 2383,(2000)

    Article  Google Scholar 

  31. Kuznetsova, A., Popova, I., Yates, J.T., Bronikowski, M.J., Huffman, C.B., Liu, J., Smalley, R.E., Hwu, H.H., and Chen, J.G.G.: Journal of the American Chemical Society 123, 10699,(2001)

    Article  PubMed  Google Scholar 

  32. Deng, J.P., Mou, C.Y., and Han, C.C.: Fullerene Science and Technology 5, 1033,(1997)

    Google Scholar 

  33. Mickelson, E.T., Huffman, C.B., Rinzler, A.G., Smalley, R.E., Hauge, R.H., and Margrave, J.L.: Chemical Physics Letters 296, 188,(1998)

    Article  Google Scholar 

  34. Bahr, J.L., Yang, J.P., Kosynkin, D.V., Bronikowski, M.J., Smalley, R.E., and Tour, J.M.: Journal of the American Chemical Society 123, 6536, (2001)

    Article  PubMed  Google Scholar 

  35. Bahr, J.L., and Tour, J.M.: Chemistry of Materials 13, 3823, (2001)

    Article  Google Scholar 

  36. Chen, Y., Haddon, R.C., Fang, S., Rao, A.M., Lee, W.H., Dickey, E.C., Grulke, E.A., Pendergrass, J.C., Chavan, A., Haley, B.E., and Smalley, R.E.: Journal of Materials Research 13, 2423, (1998)

    Google Scholar 

  37. Wong, S.S., Woolley, A.T., Joselevich, E., Cheung, C.L., and Lieber, C.M.: Journal of the American Chemical Society 120, 8557,(1998)

    Article  Google Scholar 

  38. Hu, H., Zhao, B., Hamon, M.A., Kamaras, K., Itkis, M.E., and Haddon, R.C.: Journal of the American Chemical Society 125, 14893,(2003)

    Article  PubMed  Google Scholar 

  39. Chen, J., Hamon, M.A., Hu, H., Chen, Y.S., Rao, A.M., Eklund, P.C., and Haddon, R.C.: Science 282, 95, (1998)

    Article  PubMed  MathSciNet  Google Scholar 

  40. Holzinger, M., Vostrowsky, O., Hirsch, A., Hennrich, F., Kappes, M., Weiss, R., and Jellen, F.: Angewandte Chemie-International Edition 40, 4002,(2001)

    Article  Google Scholar 

  41. Holzinger, M., Abraha, J., Whelan, P., Graupner, R., Ley, L., Hennrich, F., Kappes, M., and Hirsch, A.: Journal of the American Chemical Society 125, 8566,(2003)

    Article  PubMed  Google Scholar 

  42. Hirsch, A.: Angewandte Chemie-International Edition 41, 1853,(2002)

    Article  Google Scholar 

  43. Chen, Z.F., Thiel, W., and Hirsch, A.: Chemphyschem 4, 93,(2003)

    Article  PubMed  Google Scholar 

  44. S. Niyogi, M.A.H., H. Hu, B. Zhao, P. Bhowmik, R. Sen, M.E. Itkis, and R.C. Haddon: Accounts of Chemical Research 35, 1105,(2002)

    Article  PubMed  Google Scholar 

  45. Hamon, M.A., Itkis, M.E., Niyogi, S., Alvaraez, T., Kuper, C., Menon, M., and Haddon, R.C.: Journal of the American Chemical Society 123, 11292,(2001)

    Article  PubMed  Google Scholar 

  46. Haddon, R.C.: Journal of the American Chemical Society 112, 3385,(1990)

    Article  Google Scholar 

  47. Haddon, R.C.: Science 261, 1545,(1993)

    Google Scholar 

  48. Haddon, R.C.: Journal of Physical Chemistry A 105, 4164,(2001)

    Google Scholar 

  49. Taylor, R., and Walton, D.R.M.: Nature 363, 685,(1993)

    Article  Google Scholar 

  50. Hirsch, A.: The Chemistry of the Fullerenes (Stuttgart: Thieme,1994)

    Google Scholar 

  51. M.S. Dresselhaus, G.D., P.C. Eklund: Science of Fullerenes and Carbon Nanotubes (San Diego, CA: Academic Press,1996)

    Google Scholar 

  52. Bronikowski, M.J., Willis, P.A., Colbert, D.T., Smith, K.A., and Smalley, R.E.: Journal of Vacuum Science & Technology a-Vacuum Surfaces and Films 19, 1800,(2001)

    Google Scholar 

  53. R. Saito, G.D., M.S. Dresselhaus: Physical Properties of Carbon Nanotubes (London: Imperial College Press,1998)

    Google Scholar 

  54. Bravo-Diaz, C., Soengas-Fernandez, M., Rodriguez-Sarabia, M.J., and Gonzalez-Romero, E.: Langmuir 14, 5098,(1998)

    Article  Google Scholar 

  55. Bahr, J.L., and Tour, J.M.: Journal of Materials Chemistry 12, 1952,(2002)

    Article  Google Scholar 

  56. Dyke, C.A., and Tour, J.M.: Journal of the American Chemical Society 125, 1156,(2003)

    Article  PubMed  Google Scholar 

  57. Strano, M.S., Dyke, C.A., Usrey, M.L., Barone, P.W., Allen, M.J., Shan, H.W., Kittrell, C., Hauge, R.H., Tour, J.M., and Smalley, R.E.: Science 301, 1519,(2003)

    Article  PubMed  Google Scholar 

  58. Itkis, M.E., Niyogi, S., Meng, M.E., Hamon, M.A., Hu, H., and Haddon, R.C.: Nano Letters 2, 155,(2002)

    Article  Google Scholar 

  59. Kataura, H., Kumazawa, Y., Maniwa, Y., Umezu, I., Suzuki, S., Ohtsuka, Y., and Achiba, Y.: Synthetic Metals 103, 2555,(1999)

    Article  Google Scholar 

  60. Mintmire, J.W., and White, C.T.: Physical Review Letters 81, 2506,(1998)

    Article  Google Scholar 

  61. Ando, T.: Journal of the Physical Society of Japan 66, 1066,(1997)

    Article  Google Scholar 

  62. Kane, C.L., and Mele, E.J.: Physical Review Letters 90,(2003)

    Google Scholar 

  63. Strano, M.S.: Journal of the American Chemical Society 125, 16148,(2003)

    Article  PubMed  Google Scholar 

  64. Krupke, R., Hennrich, F., von Lohneysen, H., and Kappes, M.M.: Science 301, 344,(2003)

    Article  PubMed  Google Scholar 

  65. Zheng, M., Jagota, A., Strano, M.S., Santos, A.P., Barone, P., Chou, S.G., Diner, B.A., Dresselhaus, M.S., McLean, R.S., Onoa, G.B., Samsonidze, G.G., Semke, E.D., Usrey, M., and Walls, D.J.: Science 302, 1545,(2003)

    Article  PubMed  Google Scholar 

  66. Chattopadhyay, D., Galeska, L., and Papadimitrakopoulos, F.: Journal of the American Chemical Society 125, 3370,(2003)

    Article  PubMed  Google Scholar 

  67. Zhou, W., Ooi, Y.H., Russo, R., Papanek, P., Luzzi, D.E., Fischer, J.E., Bronikowski, M.J., Willis, P.A., and Smalley, R.E.: Chemical Physics Letters 350, 6,(2001)

    Article  Google Scholar 

  68. Kavan, L., Rapta, P., and Dunsch, L.: Chemical Physics Letters 328, 363,(2000)

    Article  Google Scholar 

  69. Kavan, L., and Dunsch, L.: Chemphyschem 4, 944,(2003)

    Article  PubMed  Google Scholar 

  70. Kavan, L., Rapta, P., Dunsch, L., Bronikowski, M.J., Willis, P., and Smalley, R.E.: Journal of Physical Chemistry B 105, 10764,(2001)

    Article  Google Scholar 

  71. Collins, P.G., Bradley, K., Ishigami, M., and Zettl, A.: Science 287, 1801,(2000)

    Article  PubMed  Google Scholar 

  72. Heinze, S., Tersoff, J., Martel, R., Derycke, V., Appenzeller, J., and Avouris, P.: Physical Review Letters 89,(2002)

    Google Scholar 

  73. Shim, M., and Siddons, G.P.: Applied Physics Letters 83, 3564,(2003)

    Article  Google Scholar 

  74. Zheng, M., Jagota, A., Semke, E.D., Diner, B.A., McLean, R.S., Lustig, S.R., Richardson, R.E., and Tassi, N.G.: Nature Materials 2, 338,(2003)

    Article  PubMed  Google Scholar 

  75. Nakashima, N., Tomonari, Y., and Murakami, H.: Chemistry Letters, 638,(2002)

    Google Scholar 

  76. Djuve, J., Grant, L.M., Sjoblom, J., Goloub, T.P., and Pugh, R.J.: Langmuir 18, 2673,(2002)

    Article  Google Scholar 

  77. Brown, S.D.M., Jorio, A., Corio, P., Dresselhaus, M.S., Dresselhaus, G., Saito, R., and Kneipp, K.: Physical Review B 6315, art. no.155414,(2001)

    Google Scholar 

  78. Reich, S., Thomsen, C., and Ordejon, P.: Physical Review B 65, art. no.155411,(2002)

    Google Scholar 

Download references

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2005 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Strano, M., Usrey, M., Barone, P., Heller, D., Baik, S. (2005). The Selective Chemistry of Single Walled Carbon Nanotubes. In: Rotkin, S.V., Subramoney, S. (eds) Applied Physics of Carbon Nanotubes. NanoScience and Technology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-28075-8_6

Download citation

Publish with us

Policies and ethics