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Selective formation of organic compounds by photoelectrosynthesis at semiconductor particles

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Book cover Electrochemistry I

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 142))

Abstract

As the importance of electrosynthesis as a reliable synthetic tool is being increasing recognized, a parallel interest has developed in applying the techniques of photoelectrochemistry to problems of interest to the organic chemist. Although most photoelectrochemical investigations have been concerned with inducing redox reactivity in simple inorganic molecules (e.g., in water splitting or carbon dioxide or nitrogen reduction), the principles developed in these studies are equally applicable to organic transformations. This review will illustrate recent advances toward the objective of using the illuminated surfaces of semiconductors as sites for initiating and controlling organic reactivity. Because this area is inherently interdisciplinary, it is nearly impossible to provide a comprehensive compilation of all work relevant to the photoinduced reactions of concern. The illustrative examples cited here should serve, however, to introduce the interested reader to mechanistic features which must be dealt with in investigating photoelectrochemical transformations.

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  1. Department of Chemistry, University of Texas, 78712, Austin, TX, USA

    Marye Anne Fox

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E. Steckhan

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Fox, M.A. (1987). Selective formation of organic compounds by photoelectrosynthesis at semiconductor particles. In: Steckhan, E. (eds) Electrochemistry I. Topics in Current Chemistry, vol 142. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-17871-6_12

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  • DOI: https://doi.org/10.1007/3-540-17871-6_12

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