Abstract
Epoxy resins chemically modified with functionally terminated poly (dimethyl siloxane), poly(dimethyl-co-methyltrifluoropropyl siloxane), and poly(dimethyl-co-diphenyl siloxane) oligomers are described in terms of their synthesis, morphology, solid-state properties, and friction and wear properties. The compatibility between the epoxy resin and the siloxane modifiers can be enhanced by increasing the percentage of methyltrifluoropropyl (TFP) siloxane or diphenyl (DP) siloxane relative to dimethyl siloxane. The compatibility of the siloxane modifier with the epoxy resin subsequently controls the size and make-up of the phase-separated elastomeric domains. Fracture toughness of the epoxy resin can be improved by modification with siloxanes containing 40% or higher TFP content or 20 and 40% DP content. Both fracture toughness and modulus changes are given a morphological basis. Friction and wear properties in both fatigue and abrasive wear tests have been found to be related to changes in modulus, fracture toughness, and morphology in ways dependent on the particular modifier. The properties and morphology of epoxy resin modified with amine-terminated and carboxyl-terminated butadiene acrylonitrile elastomers prepared under similar curing conditions have been determined and compared to those of the siloxane-modified resins.
This is a preview of subscription content, log in via an institution.
Preview
Unable to display preview. Download preview PDF.
5 References
Potter, W. G.: Epoxide Resins. New York: Springer 1970
Epoxy Resin Chemistry and Technology. May, C. A., Tanaka, Y. (eds.). New York: Marcel Dekker 1973
Epoxy Resin Chemistry. Bauer, R. S. (ed.). Am. Chem. Soc. Adv. Chem. Ser. 114 (1979)
McGarry, F. J.: Proc. Roy. Soc. Lond. A. 319, 59 (1970)
McGarry, F. J., Sultan, J. N.: 24th Ann. Tech Conf., Reinf. Plast./Compos. Div., SPI, Sect. 11-B (1969)
Rowe, E. H., Siebert, A. R., Drake, R. S.: Mod. Plast. 47, 110 (1970)
Rowe, E. H.: 24th Ann. Tech Conf., Reinf. Plast./Compos. Div., SPI, Sect. 11-A (1969)
Riew, C. K., Rowe, E. H., Siebert, A. R.: Am. Chem. Soc. Adv. Chem. Ser. 154, 326 (1976)
Romanchik, W. A., Sohn, Geibel, J. F.: Am. Chem. Soc. Symp. Ser. 221, 85 (1982)
Kunz, S. C., Beaumont, P. W. R.: J. Mater. Sci. 16, 3141 (1981)
Kinloch, A. J., Shaw, S. J., Tod, D. A., Hunston, D. L.: Polymer 24, 1341 (1983)
Okamoto, Y.: Polym. Eng. Sci. 23, 222 (1983)
Warrick, E. L., Pierce, O. R., Polmanteer, K. E., Saam, J. C.: Rubber Chem. Tech. 52, 437 (1979)
Cush, R. J., Winnan, H. W., in: Developments in Rubber Technology — 2. Whelan, A., Lee, K. S. (eds.). London: Applied Science 1981
Riffle, J. S., Yilgor, I., Banthia, A. K., Tran, C., Wilkes, G. L., McGrath, J. E.: Am. Chem. Soc. Symp. Ser. 221, 21 (1982)
Yorkgitis, E. M., Tran, C., Eiss, N. S., Jr., Hu, T. Y., Yilgor, I., Wilkes, G. L., McGrath, J. E.: Am. Chem. Soc. Adv. Chem. Ser. 208, 137 (1984)
Tran, C.: Ph. D. Thesis, Virginia Polytechnic Inst. & State Univ., Blacksburg (1984)
Bascom, W. D., Cottington, R. L.: J. Adhesion, 7, 333 (1976)
Bascom, W. D., Cottington, R. L., Jones, R. L., Peyser, P.: J. Appl. Polym. Sci., 19, 2545 (1975)
Bascom, W. D., Hunston, D. L., in: Adhesion 6. Allen, K. W. (ed.). London: Applied Science 1982
Bascom, W. D., Hunston, D. L., Timmons, C. O.: Org. Coat. Plast. Chem. 38, 179 (1978)
Bascom, W. D., Mostovoy, S.: Org. Coat. Plast. Chem. 38, 152 (1978)
Sayre, J. A., Assink, R. A., Lagasse, R. R.: Polymer 22, 87 (1981)
Kunz, S. C., Sayre, J. A., Assink, R. A.: Polymer, 23, 1897 (1982)
Manzione, L. T., Gillham, J. K., McPherson, C. A.: J. Appl. Polym. Sci., 26, 907 (1981)
Manzione, L. T., Gillham, J. K., McPherson, C. A.: J. Appl. Polym. Sci., 26, 889 (1981)
Bucknall, C. B., Yoshii, T.: Br. Polym. J. 10, 53 (1978)
Bucknall, C. B.: Toughened Plastics. London: Applied Science 1977
Yee, A. F., Pearson, R. A.: General Electric Co. NASA Contractor Report 3718. 1983
Kunz-Douglass, S. C., Beaumont, P. W. R., Ashby, M. F.: J. Mater. Sci. 15, 1109 (1980)
Sultan, J. N., McGarry, F. J.: Polym. Eng. Sci. 13, 29 (1973)
Kinloch, A. J., Shaw, S. J., Hunston, D. L.: Polymer 24, 1355 (1983)
Meeks, S. C.: Polymer 15, 675 (1974)
Johnson, K. L. in: Friction and Traction. Dowson, D. et al. (eds.). Guildford, England: Westbury House (1981)
Yilgor, I., Yilgor, E., Banthia, A. K., Wilkes, G. L., McGrath, J. E.: Polym. Bull. 4, 323 (1981)
Hu, T. Y., Eiss, N. S., Jr., Yorkgitis, E. M., Wilkes, G. L., Tran, C., Yilgor, I., McGrath, J. E.: Polym. Mater. Sci. Eng. 49, 508 (1983)
Eiss, N. S., Jr., Czichos, H., in: Wear of Materials 1985. New York: ASME 1985, in press
Tran, C., McGrath, J. E.: in preparation
Ochi, M., Ozazaki, M., Shimbo, M.: J. Polym. Sci.: Polym. Phys. Ed. 20, 689 (1982)
Pogany, G. A.: Polymer 1, 66 (1970)
Enns, J. B., Gillham, J. K.: J. Appl. Polym. Sci. 28, 2567 (1983)
Chang, T. D., Carr, S. H., Brittain, J. O.: Polym. Eng. Sci. 22, 1205 (1982)
Yorkgitis, E. M.: Ph. D. Thesis, Virginia Polytechnic Inst. & State Univ., Blacksburg (1985)
Knott, J. F.: Fundamentals of Fracture Mechanics. New York: Wiley 1973
Gent, A. N., Tobias, R. H.: Am. Chem. Soc. Symp. Ser. 193, 367 (1982)
Gent, A. N., Pulford, C. T. R. in: Developments in Polymer Fracture — 1. Andrews, E. H. (ed.). London: Applied Science 1979
Lancaster, J. K. in: Polymer Science, a Materials Science Handbook. Jenkins, A. D. (ed.). North Holland Publishing 1972
Jain, V. K., Bahadur, S.: Wear 60, 187 (1973)
Eiss, N. S., Jr.: Polym. Mater. Sci. Eng. 50, 78 (1984)
Eiss, N. S., Jr., Bayraktaroglu, M.: ASLE Trans. 23, 269 (1980)
Briscoe, B. J., Tabor, D. in: Polymer Surfaces. Clark, D. T., Feast, W. J. (eds.). New York: Wiley 1978
Timoshenko, S., Goodier, J. N.: Theory of Elasticity. 2nd edit. New York: McGraw-Hill 1951
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 1985 Springer-Verlag
About this paper
Cite this paper
Yorkgitis, E.M., Eiss, N.S., Tran, C., Wilkes, G.L., McGrath, J.E. (1985). Siloxane-modified epoxy resins. In: Epoxy Resins and Composites I. Advances in Polymer Science, vol 72. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-15546-5_4
Download citation
DOI: https://doi.org/10.1007/3-540-15546-5_4
Received:
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-15546-1
Online ISBN: 978-3-540-39457-0
eBook Packages: Springer Book Archive