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Linear amino polymers: Synthesis, protonation and complex formation

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Polymerization Reactions

Part of the book series: Advances in Polymer Science ((POLYMER,volume 58))

Abstract

Linear amino polymers containing basic nitrogen atoms are critically reviewed with regard to their synthesis, protonation and complex formation in solution with metal ions. Cross linked resins having essentially the same structure as linear polymers, are also mentioned. As far as the protonation is concerned, special care has been given to thermodynamic aspects, and to the most probable protonation mechanism. Complexing abilities of these polymers have been evaluated through stability constants and spectroscopic parameters. Practical implications of the properties have been considered.

β, δ, ε are taken from references 69 and 70

Please note: some of the symbols and abbreviations have been modified with respect to the original papers in order to avoid superposition of significance.

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Abbreviations

pK:

−log [H+] [L]/[HL+]

pKa :

pK referred to coordinated acid dissociation

pK0 :

pK of ionizing groups in the absence of electrostatic interactions with other ionizing groups

pKapp :

pH+logα/1−α

pKav :

average pK

pHp :

pH at beginning polymer precipitation

α:

degree of ionization; degree of neutralization

log β′:

logarithm of the overall stability constant of complexes

γ:

fraction of ionizable groups present in the form of charged neighbour pairs

β:

degree of protonation of residual tertiary amino groups

δ:

overall degree of neutralization

ε:

degree of neutralization of quaternary ammonium hydroxide sites

M:

Mol, molar

c:

concentration; cM = molar concentration; cMppt = molar concentration at the precipitation point

\(\bar M\);n:

number average molecular weight

〈P〉:

average polymerization degree

[η]:

viscosity number; intrinsic viscosity

ηsp :

specific viscosity

ηinh :

inherent viscosity at a given concentration

ΔH0, ΔG0, ΔS0 :

enthalpy, free energy, and entropy of formation, respectively

DMF:

dimethyl formamide

ORD:

optical rotatory dispersion

CD:

circular dichroism

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Authors and Affiliations

  1. Istituto di Chimica degli Intermedi dell' Università, Viale Risorgimento 4, 40136, Bologna, Italy

    Paolo Ferruti

  2. Istituto di Chimica Generale dell' Università, Piano dei Mantellini 44, 53100, Siena, Italy

    Rolando Barbucci

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  1. Paolo Ferruti
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  2. Rolando Barbucci
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Ferruti, P., Barbucci, R. (1984). Linear amino polymers: Synthesis, protonation and complex formation. In: Polymerization Reactions. Advances in Polymer Science, vol 58. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-12793-3_7

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  • DOI: https://doi.org/10.1007/3-540-12793-3_7

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