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Abbreviations
- Me:
-
methyl
- Et:
-
ethyl
- Pr:
-
n-propyl
- iPr:
-
isopropyl
- Bu:
-
n-butyl
- Ph:
-
phenyl
- Cp:
-
η5-cyclopentadienyl
- M:
-
metal
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TiCl4 and Ti(OR)4 are cheap raw materials used in large quantities in industry. Zirconium analogs cost about 3–4 times as much
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For an excellent review concerning chiral tetrahedral organotransition metal compounds, see Brunner, H.: Adv. Organomet. Chem. 18, 151 (1980)
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Reetz, M.T. (1982). Organotitanium reagents in organic synthesis a simple means to adjust reactivity and selectivity of carbanions. In: Synthetic and Structural Problems. Topics in Current Chemistry, vol 106. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-11766-0_1
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