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Polymer Networks pp 1–26Cite as

The use of model polymer networks to elucidate molecular aspects of rubberlike elasticity

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Part of the book series: Advances in Polymer Science ((POLYMER,volume 44))

Abstract

Establishing quantitative structure-property relationships for elastomeric materials requires independent information characterizing the network structure crucial to their rubberlike behavior. Such information can be obtained by using highly selective cross-linking reactions instead of the usual indiscriminate joining of chain segments (such as occurs in sulfur or peroxide cures or in high energy irradiations). The present review shows how such selectively prepared “model” elastomers can be used to elucidate the dependence of a variety of elastomeric properties on network structure.

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X. References

  1. Flory, P. J.: Principles of Polymer Chemistry, Cornell University, Ithaca, New York 1953

    Google Scholar 

  2. Treloar, L. R. G.: The Physics of Rubber Elasticity, 3rd ed., Clarendon, Oxford 1975

    Google Scholar 

  3. Dušek, K., Prins, W.: Adv. Polym. Sci. 6, 1 (1969)

    Google Scholar 

  4. Mark, J. E.: Makromol. Chem., Suppl. 2, 87 (1979)

    Article  Google Scholar 

  5. Mark, J. E., Sullivan, J. L.: J. Chem. Phys. 66, 1006 (1977)

    Article  CAS  Google Scholar 

  6. Smith, T. L., Magnusson, A. B.: J. Polym. Sci. 42, 391 (1960)

    Article  CAS  Google Scholar 

  7. Smith, T. L., Magnusson, A. B.: J. Appl. Polym. Sci. 14, 218 (1961)

    Article  Google Scholar 

  8. Kraus, G., Moczygemba, G. A.: J. Polym. Sci. Part A 2, 277 (1964)

    Article  Google Scholar 

  9. Edwards, D. C.: Rubber Chem. Technol. 48, 202 (1975)

    CAS  Google Scholar 

  10. Rempp, P., Herz, J. E.: Angew. Makromol. Chemie 76/77, 373 (1979)

    Article  CAS  Google Scholar 

  11. Valles, E. M., Macosko, C. W.: Rubber Chem. Technol. 49, 1232 (1976)

    CAS  Google Scholar 

  12. Valles, E. M., Macosko, C. W.: in Chemistry and Properties of Cross-Linked Polymers, ed. by Labana, S. S.: Academic Press: New York, 1977

    Google Scholar 

  13. Valles, E. M., Macosko, C. W.: Macromolecules 12, 673 (1979)

    Article  CAS  Google Scholar 

  14. Dossin, L. M., Graessley, W. W.: Macromolecules 12, 123 (1979)

    Article  CAS  Google Scholar 

  15. Pearson, D. S., Graessley, W. W.: Macromolecules 13, 1001 (1980)

    Article  CAS  Google Scholar 

  16. Meyers, K. O., Bye, M. L., Merrill, E. W.: Macromolecules 13, 1045 (1980)

    Article  CAS  Google Scholar 

  17. Gottlieb, M. et al.: Macromolecules 14, 1039 (1981)

    Article  CAS  Google Scholar 

  18. Erman, B., Wagner, W., Flory, P. J.: Macromolecules 13, 1554 (1980)

    Article  CAS  Google Scholar 

  19. Falender, J. R., Yeh, G. S. Y., Mark, J. E.: J. Chem. Phys. 70, 5324 (1979)

    Article  CAS  Google Scholar 

  20. Falender, J. R., Yeh, G. S. Y., Mark, J. E.: J. Am. Chem. Soc. 101, 7353 (1979)

    Article  CAS  Google Scholar 

  21. Falender, J. R., Yeh, G. S. Y., Mark, J. E.: Macromolecules 12, 1207 (1979)

    Article  CAS  Google Scholar 

  22. Mark, J. E., Rahalkar, R. R., Sullivan, J. L.: J. Chem. Phys. 70, 1794 (1979)

    Article  CAS  Google Scholar 

  23. Llorente, M. A., Mark, J. E.: J. Chem. Phys. 71, 682 (1979)

    Article  CAS  Google Scholar 

  24. Llorente, M. A., Andrady, A. L., Mark, J. E.: J. Polym. Sci., Polym. Phys. Ed. 18, 2263 (1980)

    Article  CAS  Google Scholar 

  25. Andrady, A. L., Llorente, M. A., Mark, J. E.: J. Chem. Phys. 72, 2282 (1980)

    Article  CAS  Google Scholar 

  26. Andrady, A. L., Llorente, M. A., Mark, J. E.: J. Chem. Phys. 73, 1439 (1980)

    Article  CAS  Google Scholar 

  27. Mark, J. E., Llorente, M. A.: J. Am. Chem. Soc. 102, 632 (1980)

    Article  CAS  Google Scholar 

  28. Llorente, M. A., Mark, J. E.: Macromolecules 13, 681 (1980)

    Article  CAS  Google Scholar 

  29. Llorente, M. A., Mark, J. E.: J. Polym. Sci., Polym. Phys. Ed. 18, 181 (1980)

    Article  CAS  Google Scholar 

  30. Llorente, M. A., Mark, J. E.: Rubber Chem. Technol. 53, 988 (1980)

    CAS  Google Scholar 

  31. Mark, J. E., Sung, P.-H.: Eur. Polym. J. 16, 1223 (1980)

    Article  CAS  Google Scholar 

  32. Sung, P.-H., Mark, J. E.: Polym. J. 12, 835 (1980)

    Article  CAS  Google Scholar 

  33. Sung, P.-H., Mark, J. E.: J. Polym. Sci., Polym. Phys. Ed., 19, 507 (1981)

    Article  CAS  Google Scholar 

  34. Andrady, A. L. et al.: J. Appl. Polym. Sci. 26, 1829 (1981)

    Article  CAS  Google Scholar 

  35. Llorente, M. A., Andrady, A. L., Mark, J. E.: J. Polym. Sci., Polym. Phys. Ed. 19, 621 (1981)

    Article  CAS  Google Scholar 

  36. Mark, J. E.: Pure Appl. Chem. 53, 1495 (1981)

    CAS  Google Scholar 

  37. Llorente, M. A., Andrady, A. L., Mark, J. E.: Colloid Polym. Sci. 259, 000 (1981)

    Google Scholar 

  38. Mark, J. E.: Rubber Chem. Technol. 54, 000 (1981)

    Google Scholar 

  39. Riande, E., Guzmań, J., Llorente, M. A.: in press

    Google Scholar 

  40. Kennedy, J. P.: private communications

    Google Scholar 

  41. Ronca, G., Allegra, G.: J. Chem. Phys. 63, 4990 (1975)

    Article  CAS  Google Scholar 

  42. Graessley, W. W.: Macromolecules 8, 186, 865 (1975)

    Article  CAS  Google Scholar 

  43. Flory, P. J.: Proc. R. Soc. London, Ser. A. 351, 351 (1976)

    Article  CAS  Google Scholar 

  44. Flory, P. J.: in Contemporary Topics in Polymer Science, Vol. II, ed. by Pearce, E. M., Schaefgen, J. R., Plenum Press: New York, 1977

    Google Scholar 

  45. Flory, P. J.: J. Chem. Phys. 66, 5730 (1977); Erman, B., Flory, P. J.: J. Chem. Phys. 68, 5363 (1978)

    Article  Google Scholar 

  46. Flory, P. J.: Polymer 20, 1317 (1979)

    Article  CAS  Google Scholar 

  47. Flory, P. J.: Macromolecules 12, 119 (1979)

    Article  CAS  Google Scholar 

  48. Kästner, S.: Colloid Polym. Sci. 259, 499, 508 (1981)

    Article  Google Scholar 

  49. Mark, J. E., Flory, P. J.: J. Appl. Phys. 37, 4635 (1966)

    Article  CAS  Google Scholar 

  50. Mark, J. E.: J. Am. Chem. Soc. 92, 7252 (1970)

    Article  CAS  Google Scholar 

  51. Mark, J. E.: Rubber Chem. Technol. 48, 495 (1975)

    CAS  Google Scholar 

  52. Mark, J. E.: J. Chem. Educ. 58, 000 (1981)

    Google Scholar 

  53. Mark, J. E.: Polym. Eng. Sci. 19, 409 (1979)

    Article  CAS  Google Scholar 

  54. Mooney, M.: J. Appl. Phys. 19, 434 (1948); Rivlin, R. S.: Phil. Trans. R. Soc. London, Ser. A. 241, 379 (1948)

    Article  CAS  Google Scholar 

  55. Neidlinger, H. H., Hsu, Y. H.: paper presented at IUPAC Meeting, Strasbourg, 1981

    Google Scholar 

  56. Rehage, G., Opperman, W.: Polymer Preprints 22(2), 157 (1981)

    CAS  Google Scholar 

  57. Ferry, J. D.: Viscoelastic Properties of Polymers, 2nd Ed.: Wiley, New York, 1970

    Google Scholar 

  58. Graessley, W. W.: Adv. Polym. Sci. 16, 1 (1974)

    Article  Google Scholar 

  59. Macosko, C. W.: Polymer Preprints 22(2), 155 (1981)

    CAS  Google Scholar 

  60. Meyers, K. O., Merrill, E. W.: Polymer Preprints 22(2), 159 (1981)

    Google Scholar 

  61. Smith, T. L.: Polymer Preprints 22(2), 169 (1981)

    Google Scholar 

  62. Kramer, O. et al.: Macromolecules 7, 79 (1974)

    Article  CAS  Google Scholar 

  63. Batsberg, W., Kramer, O.: Polymer Preprints 22(2), 171 (1981)

    Google Scholar 

  64. Llorente, M. A., Mark, J. E.: J. Polym. Sci., Polym. Phys. Ed. 19, 1107 (1981)

    Article  CAS  Google Scholar 

  65. Mark, J. E., Llorente, M. A.: Polym. J. 13, 543 (1981)

    Article  CAS  Google Scholar 

  66. Zhang, Z.-M., Mark, J. E.: work in progress

    Google Scholar 

  67. Sung, P.-H., Mark, J. E.: work in progress

    Google Scholar 

  68. Flory, P. J., Tatara, Y.: J. Polym. Sci., Polym. Phys. Ed. 13, 683 (1975)

    Article  CAS  Google Scholar 

  69. Mark, J. E.: Polym. Eng. Sci. 19, 254 (1979)

    Article  CAS  Google Scholar 

  70. Su, T.-K., Mark, J. E.: Macromolecules 10, 120 (1977)

    Article  CAS  Google Scholar 

  71. Mark, J. E., Andrady, A. L.: Rubber Chem. Technol. 54, 366 (1981)

    CAS  Google Scholar 

  72. Zhang, Z.-M., Mark, J. E.: J. Polym. Sci., Polym. Phys. Ed. 19, 000 (1981)

    Google Scholar 

  73. Bueche, F.: Physical Properties of Polymers. New York: Interscience, 1962, ch. 10

    Google Scholar 

  74. Smith, T. L.: Polym. Eng. Sci. 17, 129 (1977)

    Article  CAS  Google Scholar 

  75. Gent, A. N.: in Science and Technology of Rubber, ed. by F. R. Eirich, New York: Academic Press, 1978, ch. 10

    Google Scholar 

  76. Pan, S.-J., Mark, J. E.: work in progress

    Google Scholar 

  77. Thiele, J. L., Mark, J. E.: work in progress

    Google Scholar 

  78. Smith, T. L.: J. Polym. Sci. A 1, 3597 (1963)

    Google Scholar 

  79. Alliger, G., Sjothun, I. J., ed.: Vulcanization of Elastomers, New York: Reinhold, 1964

    Google Scholar 

  80. Coran, A. Y.: in Science and Technology of Rubber, ed. by F. R. Eirich, New York: Academic Press, 1978, ch. 7

    Google Scholar 

  81. Dunham, M. L., Bailey, D. L., Mixer, Y.: Ind. Eng. Chem. 49, 1373 (1957)

    Article  CAS  Google Scholar 

  82. Bork, P. G., Roush, C. W.: in Vulcanization of Elastomers, ed. by G. Alliger and I. J. Sjothum, New York: Rheinhold, 1964, ch. 11

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry and the Polymer Research Center, The University of Cincinnati, 45221, Cincinnati, Ohio, USA

    J. E. Mark

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  1. J. E. Mark
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Editor information

Karel Dušek

Additional information

It is a pleasure to dedicate this paper to Prof. Manfred Gordon on the occasion of his 65th birthday.

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© 1982 Springer-Verlag

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Mark, J.E. (1982). The use of model polymer networks to elucidate molecular aspects of rubberlike elasticity. In: Dušek, K. (eds) Polymer Networks. Advances in Polymer Science, vol 44. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-11471-8_1

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  • DOI: https://doi.org/10.1007/3-540-11471-8_1

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-11471-0

  • Online ISBN: 978-3-540-39086-2

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