Abstract
The energy bands of RbAu and KAu are calculated by the self-consistent local-density pseudopotential method using hard-core potentials. RbAu is an indirect gap semiconductor whereas KAu is a metal. A study of KxRb1−xAu in the virtual crystal approximation shows that the metal-semiconductor transition occurs at xc=0.45 where the alloy is an indirect zero-gap material. The chemical bonding in KxRb1−xAu is ionic with Au playing the role of anion.
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W.E.Spicer, A.H.Sommer, and J.G.White: Phys. Rev. 115 (1959) 57.
H.Overhof, J.Knecht, R.Fischer, and F.Hensel: J. Phys. F: Metal Phys. 8 (1978) 1607.
C.Norris and L.Wallden: Phys. Stat. Sol. a 2 (1970) 381.
G.A.Tinelli and D.F.Holcomb: Materials Science Center, Cornell University, Report N. 2935 (1977).
N.Nikoloso, R.W.Schmutzler, and F.Hensel: Ber. Bunsenges. phys. Chem. 82 (1978) 621; see also the review paper by F.Hensel: Adv. Phys. 28 (1979) 555.
F.Meloni and A.Baldereschi: Recent Development in Condensed Matter Physics, J.T.Devreese ed. (Plenum, New York, 1981) vol. 3, p. 281.
C.E.Moore: Atomic Energy Levels (US Govt. Publishing Office, Washington, 1949).
C.Froese-Fisher Atomic Data 4 (1972) 301 for the alkali atoms and J.P.Desclaux: Atomic Data 12 (1973) 311 for gold.
L.Pauling: The Nature of the Chemical Bond (Cornell Univ. Press, Ithaca, 1960).
G.Kienast and J.Verma: Z. anorg. allg. Chem. 310 (1961) 143.
H.M.Huang and T.L.Liu: Phys. Lett. 46A (1973) 295.
A.Baldereschi: Phys. Rev. B7 (1973) 5212.
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© 1982 Springer-Verlag
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Meloni, F., Baldereschi, A. (1982). Electronic properties of KxRb1−xAu , an indirect small gap semiconductor. In: Gornik, E., Heinrich, H., Palmetshofer, L. (eds) Physics of Narrow Gap Semiconductors. Lecture Notes in Physics, vol 152. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-11191-3_5
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DOI: https://doi.org/10.1007/3-540-11191-3_5
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