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Structural and chemical modifications of cellulose by graft copolymerization

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New Polymerization Reactions

Part of the book series: Advances in Polymer Science ((POLYMER,volume 42))

Abstract

Studies concerning the following problems are reviewed;

  1. 1.

    Influence of the cellulose structure and of the chemical structure of the grafted polymer on the kinetics of graft copolymerization of cellulose, on the composition, and the structure of the cellulose products.

  2. 2.

    Kinetics of chemically initiated graft polymerization onto cellulose and its peculiarities connected with the heterogeneity of the process.

  3. 3.

    Specificities of grafting in the heterogenious medium and use of some effects in technology.

  4. 4.

    Basic trends in the development of the commercial process of graft polymerization on cellulose.

  5. 5.

    Polymer-analoguous conversion of polymer chains grafted to cellulose.

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Abbreviations

[c]:

effective concentration of cellulose proportional to its mass

D:

coefficient of monomer diffusion into the film

l:

film width

kg :

constant of chain growth

kct :

constant of chain termination

kt :

constant of transfer to monomer

krf :

rate constant of the formation of cellulose radicals

k′o :

rate constant of the decomposition of cellulose radicals

M:

monomer concentration in the film

\(\bar P\) :

average degree of polymerization

\(\bar R\) :

averge grafting rate over the entire width of the film

Ri :

initiations rate

t:

reaction time

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Authors and Affiliations

  1. Moscow Textile Institute, M. Kaluskaja I, B-419, Moscow, USSR

    B. P. Morin, I. P. Breusova & Z. A. Rogovin

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  1. B. P. Morin
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  2. I. P. Breusova
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  3. Z. A. Rogovin
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Morin, B.P., Breusova, I.P., Rogovin, Z.A. (1982). Structural and chemical modifications of cellulose by graft copolymerization. In: New Polymerization Reactions. Advances in Polymer Science, vol 42. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-10958-7_4

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  • DOI: https://doi.org/10.1007/3-540-10958-7_4

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