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Linear polymers containing transition metals in the main chain

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Speciality Polymers

Part of the book series: Advances in Polymer Science ((POLYMER,volume 41))

Abstract

In recent years linear polymers containing transition metals have attracted much interest. There are two types of organometallic polymers in which the metal-containing portion is either a part of the polymer main chain or bound to the polymer as a pendant group. In this article the recent studies on the former type of linear polymers are reviewed on the basis of the following three parts: 1 metallocene-containing polymers; 2 linear “Werner-type” coordination polymers; 3 polymers containing sigma-bonded transition metals in the main chain. The main part of this review is devoted to a new class of soluble metal-poly-yne polymers in which transition metal atoms are joined in the main chain by a metal-carbon σ-bond.

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4 References

  1. Carraher, Jr. et al. (eds.): Organometallic Polymers, New York, Academic Press 1978

    Google Scholar 

  2. Katon, J. E. (ed.): Organic semiconducting polymers, New York, Marcel Dekker 1970

    Google Scholar 

  3. Stone, F. G. A., Graham, G. (eds.): Inorganic polymers, New York, Academic Press 1962

    Google Scholar 

  4. Miller, J. S., Epstein, A. J., in: Progress in Inorganic Chemistry. Lippard, S. J. (ed.), vol. 20, p. 1, New York, Wiley Intersci. Publ., 1976

    Google Scholar 

  5. Neuse, E. W., Rosenberg, H.: Metallocene polymer, New York, Marcel Dekker 1970

    Google Scholar 

  6. Neuse, E. W., in: Advance in Macromolecular Chemistry (Paska, M. W. (ed.)), vol. 1, p. 1, New York, Academic Press 1968

    Google Scholar 

  7. Pittman, Jr. C. U., in: Organometallic Reactions. Becker, E., Tsutsui, M. (eds.), vol. 6, New York, Marcel Dekker 1977

    Google Scholar 

  8. Carraher (Eds) (1978) Organometallic Polymers Academic Press New York

    Google Scholar 

  9. Korshak, V. V., Sosin, S. L., Alekseeva, V. A.: Dokl. Akad. Nauk. SSSR 132, 360 (1960); Vysokomol. Soed. 2, 1332 (1961)

    Google Scholar 

  10. Nesmeyanov, A. N. et al.: Dokl. Akad. Nauk. SSSR 137, 1370 (1961)

    Google Scholar 

  11. Rosenberg, H., Neuse, E. W.: J. Organomet. Chem. 6, 76 (1966)

    Google Scholar 

  12. Neuse, E. W., Bednarik, L.: Macromolecules 12, 187 (1979)

    Google Scholar 

  13. Neuse, E. W., Bednarik, L.: Transition Met. Chem. 4, 87 (1979); ibid. 4, 104 (1979)

    Google Scholar 

  14. Izumi, T., Kasahara, A.: Bull. Chem. Soc. Japan 48, 1955 (1975)

    Google Scholar 

  15. Carraher, Jr., E. C., cf. Ref. 1 (a) p. 79

    Google Scholar 

  16. Carraher, Jr., E. C., Christensen, M. J.: Angew. Makromol. Chem. 69, 61 (1978)

    Google Scholar 

  17. Neuse, E. W., cf. Ref. 1 (a), p. 95

    Google Scholar 

  18. Salzer, A., Werner, H.: Angew. Chem., Int. Ed. Engl. 11, 930 (1972)

    Google Scholar 

  19. Kolesnikov, S. P., Dobson, J. E., Skell, P. S.: J. Am. Chem. Soc. 100, 999 (1978)

    Google Scholar 

  20. Katz, T. J., Schulman, J.: J. Am. Chem. Soc. 86, 3169 (1964); ibid. 90, 734 (1968)

    Google Scholar 

  21. Davison, A., Smart, J. C.: J. Organomet. Chem. 49, C43 (1973); Smart, J. C., Pinsky, B. L.: J. Am. Chem. Soc. 99, 956 (1977); Smart, J. C., Curtis, C. J.: Inorg. Chem. 16, 1788 (1977)

    Google Scholar 

  22. cf. Ref. 12

    Google Scholar 

  23. Katz, T. J., Slusarek, W.: J. Am. Chem. Soc. 101, 4259 (1979)

    Google Scholar 

  24. Patel, M. N., Patel, J. B.: Angew. Makromol. 80, 171 (1979)

    Google Scholar 

  25. McGregor, K. T., Soos, Z. G.: Inorg. Chem. 15, 2159 (1976)

    Google Scholar 

  26. Wrobleski, J. T., Brown, D. B.: Inorg. Chem. 18, 498 (1979); ibid. 18, 2738 (1979)

    Google Scholar 

  27. Götzfried, F. et al.: Angew. Chem. 91, 499 (1979)

    Google Scholar 

  28. Teo, B.-K. et al.: J. Am. Chem. Soc. 99, 4862 (1977)

    Google Scholar 

  29. Rivera, N. M., Engler, E. M.: J. Chem. Soc. Chem. Commun. 1979, 184

    Google Scholar 

  30. Kanda, S., Suzuki, A., Ohkawa, K.: Ind. Eng. Chem. Dev. 12, 88 (1973)

    Google Scholar 

  31. Son, S., Kanamaru, F., Koizumi, M.: Inorg. Chem. 18, 400 (1979)

    Google Scholar 

  32. Amon, W. F., Jr., Kane, M. W.: US Patent 2, 505, 085 (April 25, 1950)

    Google Scholar 

  33. Spiro, T. G. et al.: J. Am. Chem. Soc. 88, 2721 (1966)

    Google Scholar 

  34. Allerton, S. E. et al.: ibid. 88, 3148 (1966)

    Google Scholar 

  35. Spiro, T. G., Bates, G., Saltman, P.: ibid. 89, 5559 (1967)

    Google Scholar 

  36. Dahl, G. H. et al.: US Clearing House Fed. Sci. Tech. Inform., 1968, A. D. 671, 882 from US Gov. Res. Develop. Rep. 68, (17) 103 (1968)

    Google Scholar 

  37. Block, B. P., Dahl, G.: US Pat. 3, 415, 781 (December 10, 1968)

    Google Scholar 

  38. Richard, L., Bow, S. N.: Inorg. Chim. Acta 25, L113 (1977)

    Google Scholar 

  39. Shirai, H. et al.: J. Polym. Sci., Polym. Lett. Ed. 17, 343 (1979)

    Google Scholar 

  40. Shirai, H. et al.: Makromol. Chem. 180, 2073 (1979)

    Google Scholar 

  41. Hartel, M. et al.: Angew. Makromol. 29, 30, 307 (1973)

    Google Scholar 

  42. Sawodny, W., Riederer, M.: Angew. Chem. 89, 897 (1977)

    Google Scholar 

  43. Riederer, M., Urban, E., Sawodny, W.: ibid. 89, 898 (1977)

    Google Scholar 

  44. Riederer, M., Sawodny, W., J. Chem. Res. (S), 1978, 450; (M), 5373

    Google Scholar 

  45. Donaruma, L. G. et al.: Macromolecules 12, 435 (1979)

    Google Scholar 

  46. Green, M. L. H., in: Organometallic Compounds, 3rd edit., Coat, G. E., Green, M. L. H., Wade, K. (eds.), vol. 2, p. 203, London, Muthuen 1968

    Google Scholar 

  47. See for example, (a) Davidson, P. J., Lappert, M. F., Pearce, R.: Chem. Rev. 2, 219 (1976)

    Google Scholar 

  48. Schrock, R. R., Parshall, G. W.: ibid. 2, 243 (1976)

    Google Scholar 

  49. Korshak, V. V., Sladkov, A. W., Kurdryavtsev, Y. P.: Vysokomol. Soedin. 2, 1824 (1960)

    Google Scholar 

  50. Hay, A. S.: J. Polym. Sci. A1, 7, 1625 (1976)

    Google Scholar 

  51. Sonogashira, K. et al.: J. Chem. Soc., Chem. Commun. 1977, 291

    Google Scholar 

  52. Sonogashira, K. et al.: J. Organometal. Chem. 145, 101 (1978)

    Google Scholar 

  53. Bruce, M. I. et al.: J. Organometal. Chem. 42, C107 (1972)

    Google Scholar 

  54. Abu Salah, O. M., Bruce, M. I., J. Chem. Soc. 1974, 2302

    Google Scholar 

  55. Sonogashira, K., Takahashi, S., Hagihara, N.: Macromolecules 10, 879 (1977)

    Google Scholar 

  56. Takahashi, S. et al.: ibid. 11, 1064 (1978)

    Google Scholar 

  57. Rutledge, T. F.: Acetylenes and allenes, p. 403, New York, Reinhold Publ. Co. 1969

    Google Scholar 

  58. Takahashi, S. et al.: J. Polym. Sci., Polym. Chem. Ed. 18, 661 (1980)

    Google Scholar 

  59. Sonogashira, K. et al.: J. Organometal. Chem. 188, 237 (1980)

    Google Scholar 

  60. Yamazaki, H., Aoki, K.: private communication

    Google Scholar 

  61. Takahashi, S. et al.: in preparation

    Google Scholar 

  62. Sonogashira, K. et al.: J. Organomet. Chem. 160, 319 (1978)

    Google Scholar 

  63. Takahashi, S. et al.: J. Polym. Sci., Polym. Chem. Ed. 18, 349 (1980)

    Google Scholar 

  64. Hartley, F. R.: The chemistry of platinum and palladium, p. 332, London, Applied Science 1973

    Google Scholar 

  65. Alfrey, T., Bartovics, A., Mark, H.: J. Am. Chem. Soc. 64, 1557 (1942)

    Google Scholar 

  66. Spurlin, H. M., Martin, A. F., Tennent, H. G.: J. Polym. Sci. 1, 63 (1946)

    Google Scholar 

  67. Mangaraj, D., Bhatnagar, S. K., Rath, S. B.: Makromol. Chem. 67, 75 (1963)

    Google Scholar 

  68. Doty, P., Bradbury, J. H., Holtzer, A. M.: J. Am. Chem. Soc. 78, 947 (1956)

    Google Scholar 

  69. Simha, R.: J. Phys. Chem. 44, 25 (1940)

    Google Scholar 

  70. Tranford, C.: Physical chemistry of macromolecules, p. 333, New York, John Wiley and Sons 1961

    Google Scholar 

  71. Motowoka, M. et al.: Polymer J. 11, 665 (1979)

    Google Scholar 

  72. Ikeda, K., Tomiyama, T.: Private communication

    Google Scholar 

  73. Eigner, J., Doty, P.: J. Mol. Biol. 12, 549 (1965)

    Google Scholar 

  74. Samulski, E. T.: Liquid crystalline order in polymers, Blumstain, A. (ed.), New York, Academic Press 1978

    Google Scholar 

  75. Pearce, E. M., Schaefgen, J. R. (ed.): Contemporary topics in polymer science, Vol. 2, New York, Plenum Press 1977

    Google Scholar 

  76. Knowlek, S. L. et al.: Macromolecules 10, 1390 (1977)

    Google Scholar 

  77. Bair, T. I., Morgan, P. W., Killian, F. L.: ibid. 10, 1396 (1977)

    Google Scholar 

  78. Panar, M., Beste, L. F.: ibid. 10, 1401 (1977)

    Google Scholar 

  79. Aharoni, S. M.: Macromolecules 12, 94 (1979)

    Google Scholar 

  80. Takahashi, S.: Macromolecules, 12, 1016 (1979)

    Google Scholar 

  81. Flory, P. J.: Proc. R. Soc. London, Ser. A, 234, 73 (1956)

    Google Scholar 

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© 1981 Springer-Verlag

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Hagihara, N., Sonogashira, K., Takahashi, S. (1981). Linear polymers containing transition metals in the main chain. In: Speciality Polymers. Advances in Polymer Science, vol 41. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-10554-9_12

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  • DOI: https://doi.org/10.1007/3-540-10554-9_12

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-10554-1

  • Online ISBN: 978-3-540-38525-7

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