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Interpolymer complexes

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Speciality Polymers

Part of the book series: Advances in Polymer Science ((POLYMER,volume 41))

Abstract

In this review, the problems of complex formation in different systems of interacting macromolecules namely in polymer-polymer, polymer-alternating or statistical copolymer systems are discussed. The influence of solvent nature, the critical phenomena, equilibrium, selectivity and co-operativity in reactions are considered. The perspectives of development of this field of polymer science and the potential practical applications of interpolymer complexes are pointed out.

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Abbreviations

c:

concentrations of polymer (g/dl)

H:

enthalpy

K:

constant of complex stability

Mv :

viscosity average molecular weight

Mw :

weight average molecular weight

M :

Hydrodynamic average molecular weight

\(\bar n\) :

degree of polymerization

ncr :

critical degree of polymerization

I/P:

depolarization of luminescence

Q:

heat of reaction (kcal/mol)

S0 :

constant of sedimentation

S:

entropy

T:

temperature

α:

degree of neutralization

β:

average degree of packing of matrix with oligomer β=[oligomer]/[polyacid]

μ:

standard chemical potential

[η]:

intrinsic viscosity (dl/g)

ηsp/c:

reduced viscosity

ϑ:

degree of conversion at complex formation or degree of the complex formation

σ:

parameter of helix-coil transition cooperativity

τ:

relaxation time (ns)

X:

degree of completion of exchange reaction

DMF:

dimethyl formamide

DMSO:

dimethyl sulfoxide

DTMLG:

3-o-methacrylic ester of 2,4-di-o-tosylevoglucosan

figure 1
ionen:

polycation carrying the charge in the main chain

ionen 2 X:
figure 2
ionen 5,6:
figure 3
PAA:

poly(acrylic acid)

PAA*:

luminescence-labelled poly(acrylic acid)

PAAm:

poly(acrylamide)

PDMAEM:

poly(2-N,N-dimethylaminoethyl methacrylate)

PEG:

poly(ethylene glycol)

PEI:

poly(ethylenimine)

PEO:

poly(ethylene oxide)

PMAA:

poly(methacrylic acid)

PMAA*:

luminescence-labelled poly(methacrylic acid)

PMMA:

poly(methyl methacrylate)

PMMI:

poly(monomethyl itaconate)

POE:

(polyoxyethylene)

PVA:

poly(vinyl alcohol)

PVA-S:

poly(vinyl alcohol) sulfurated

PVA-AAc:

aminoacetylated poly(vinyl alcohol)

PVBTACl:

poly(vinylbenzyltrimethyl-ammonium chloride)

PVME:

poly(vinyl methyl ether)

PVPy:

polyvinylpyridine

PVPyEtBr:

poly(2-vinylethylpyridinium bromide)

PVP:

polyvinylpyrrolidone

PSSNa:

poly(sodium styrene sulfonate)

AA/AAm:

copolymer of acrylic acid and acrylamide

AA/PVP:

copolymer of acrylic acid and vinylpyrrolidone

DMAEM/DTMLG:

copolymer of 2-N,N-dimethylaminoethyl methacrylate and 3-o-methacrylic ester of 2,4-di-o-tosylevoglucosan

MA/St:

copolymer of maleic acid and styrene

MA/VBE:

copolymer of maleic acid and butyl vinyl ether

MAA/BA:

copolymer of methacrylic acid and butyl acrylate

MAA/BMA:

copolymer of methacrylic acid and butyl methacrylate

MAA/MMA:

copolymer of methacrylic acid and methyl methacrylate

MAA/St:

copolymer of methacrylic acid and styrene

MAn/AA:

copolymer of maleic anhydride and acrylic acid

MAn/MAA:

copolymer of maleic anhydride and methycrylic acid

MAn/MMI:

copolymer of maleic anhydride and monomethyl ether of itaconic acid

VP/AAm:

copolymer of N-vinylpyrrolidone and acrylamide

VP/MAcrCl:

copolymer of N-vinylpyrrolidone and methacrylic chloride

VP/St:

copolymer of N-vinylpyrrolidone and styrene

VP/VGEEG:

copolymer of N-vinylpyrrolidone and glycidyl vinyl ether of ethylene glycol

SSNa/DTMLG:

copolymer of sodium styrene sulfonate and 3-o-methacrylic ester of 2,4-di-o-tosylevoglucosan

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Bekturov, E.A., Bimendina, L.A. (1981). Interpolymer complexes. In: Speciality Polymers. Advances in Polymer Science, vol 41. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-10554-9_11

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