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Synthesis, characterization and morphology of poly(butadiene-g-styrene)

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Polymerization Processes

Part of the book series: Advances in Polymer Science ((POLYMER,volume 38))

Abstract

This paper concerns the synthesis of poly(butadiene-g-styrene) by cationic grafting of polystyrene cations onto polybutadiene using alkyl halide /alkylaluminum initiating systems and an investigation into the effect of reaction conditions on grafting and mechanism studies with model reactions. Graft characterization by selective oxidative backbone destruction followed by surviving polystyrene branch analysis and morphology studies are also described.

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References

  1. “Cationic Graft Copolymerizations” J. P. Kennedy (ed.): J. Appl. Polymer Symp. 30 (1977)

    Google Scholar 

  2. Reibel, L., Kennedy, J. P., Chung, Y. L.: J. Org. Chem. 42 (1977)

    Google Scholar 

  3. Kennedy, J. P.: J. Polym. Sci., A-1, 6, 3139 (1968)

    CAS  Google Scholar 

  4. Kennedy, J. P.: J. Macromol. Sci. Chem., A3 (5), 861 (1969)

    Google Scholar 

  5. Kennedy, J. P.: J. Org. Chem. 35, 532 (1970)

    Article  CAS  Google Scholar 

  6. Kennedy, J. P., Desai, N. V., Sivaram, S.: J. Am. Chem. Soc. 95, 6386 (1973)

    Article  CAS  Google Scholar 

  7. Kennedy, J. P., Sivaram, S.: J. Org. Chem. 38, 2262 (1973)

    Article  CAS  Google Scholar 

  8. Kennedy, J. P.: J. Macromol. Sci. Chem., A7 (4), 969 (1973)

    Google Scholar 

  9. Kennedy, J. P., Ichikawa, M.: Polym. Eng. Sci. 14, 322 (1974)

    Article  CAS  Google Scholar 

  10. Hass, H. C., Kamath, P. M., Schuler, N. W.: J. Polym. Sci. 24, 85 (1957)

    Article  Google Scholar 

  11. Overberger, C. G., Burns, C. M.: J. Polym. Sci. A-1, 7, 333 (1969)

    Article  CAS  Google Scholar 

  12. Ueno, Y. et al.: J. Polym. Sci., A-1, 5, 339 (1967)

    Article  Google Scholar 

  13. Monoura, Y. et al.: J. Polym. Sci., A-1, 4, 1665 (1966)

    Article  Google Scholar 

  14. Jaacks, V., Kern, W.: Makromol. Chem. 83, 71 (1965)

    Article  CAS  Google Scholar 

  15. Sigwalt, P., Polton, A., Miskovic, M.: J. Polym. Sci., Part C. Polym. Symp. 56, 13 (1976)

    CAS  Google Scholar 

  16. Kennedy, J. P.: J. Macromol. Sci., A-6 2, 339 (1972)

    Google Scholar 

  17. Delvaux, M. J.: Ph. D. thesis, The University of Akron, 1980

    Google Scholar 

  18. Kennedy, J. P., Metzler, D. K.: “Cationic Graft Copolymerization,” J. P. Kennedy (Ed.) J. Appl. Polymer Symp. 30, 141 (1977)

    CAS  Google Scholar 

  19. Kato, K.: J. Polym. Sci., B-4, 35 (1966)

    Google Scholar 

  20. Matsuo, M., Sagae, S., Asai, H.: Polymer 10, 79 (1969)

    Article  CAS  Google Scholar 

  21. Pedemonte, E. et al.: Polymer 14, 145 (1973)

    Article  CAS  Google Scholar 

  22. Lewis, P. R., Price, C.: Polymer 13, 20 (1972)

    Article  CAS  Google Scholar 

  23. Price, C., Watson, A. G., Chow, M. T.: Polymer 13, 333 (1972)

    Article  CAS  Google Scholar 

  24. Lewis, P. R., Price, C.: Nature 223, 494 (1969)

    Article  Google Scholar 

  25. Lewis, P. R., Price, C.: Polymer 12, 258 (1971)

    Article  CAS  Google Scholar 

  26. Nakamura, S., Sato, H., Matsuzaki, K.: J. Appl. Polym. Sci., B 11, 221 (1973); ibid., J. Appl. Polym. Sci. 22, 2011 (1978)

    Google Scholar 

  27. Overberger, C. G., Kamath, P. M., Endres, G. F.: J. Am. Chem. Soc. 84, 4813 (1962)

    Article  Google Scholar 

  28. Muller, K.: “Functional Group Determination of Olefinic and Acetylenic Unsaturation,” Academic Press, London, 1974

    Google Scholar 

  29. Barnard, D.: J. Polym. Sci. 22, 213 (1956)

    Article  CAS  Google Scholar 

  30. Boer, H., Kooyman, E. C.: Anal. Chim. Acta 5, 550 (1951)

    Article  CAS  Google Scholar 

  31. Kolthoff, I. M., Lee, T. S., Carr, C. W.: J. Polymer Sci. 1, 429 (1946)

    Article  CAS  Google Scholar 

  32. Blanchette, J., Nielsen, L. E.: J. Polym. Sci. 20, 317 (1956)

    Article  CAS  Google Scholar 

  33. Mori, V., Minoura, Y., Imoto, M.: Angew. Makromol. Chem. 25, 1 (1958)

    Google Scholar 

  34. Duke, F. R.: J. Am. Chem. Soc. 69, 3054 (1947)

    Article  CAS  Google Scholar 

  35. Price, C. C., Knell, M.: J. Am. Chem. Soc. 64, 552 (1942)

    Article  CAS  Google Scholar 

  36. Buist, J. D., Bunton, C. A., Miles, J. H.: J. Am. Chem. Soc., 743 (1959)

    Google Scholar 

  37. Thame, N. G., Lundberg, R. D., Kennedy, J. P.: Polymer Sci., A-1 10, 2507 (1972)

    CAS  Google Scholar 

  38. Kennedy, J. P., Davidson, D. L.: “Cationic Graft Copolymerization,” J. P. Kennedy (Ed.) J. Appl. Polymer Symp. 30, 13; ibid., 51

    Google Scholar 

  39. Kennedy, J. P., Vidal, A.: J. Polym. Sci., A-1 13, 1765 (1975)

    CAS  Google Scholar 

  40. Oziomek, J., Kennedy, J. P.: J. Appl. Polymer Symp. 30, 91 (1977)

    CAS  Google Scholar 

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Author information

Author notes

  1. J. M. Delvaux

    Present address: Union Carbide Co., Bound Brook, N. J.

Authors and Affiliations

  1. Institute of Polymer Science, The University of Akron USA, 44325, Akron, OH

    Joseph P. Kennedy & J. M. Delvaux

Authors
  1. Joseph P. Kennedy
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  2. J. M. Delvaux
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© 1981 Springer-Verlag

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Kennedy, J.P., Delvaux, J.M. (1981). Synthesis, characterization and morphology of poly(butadiene-g-styrene). In: Polymerization Processes. Advances in Polymer Science, vol 38. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-10217-5_5

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  • DOI: https://doi.org/10.1007/3-540-10217-5_5

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-10217-5

  • Online ISBN: 978-3-540-38279-9

  • eBook Packages: Springer Book Archive

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