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Molecular aspects of multiple dielectric relaxation processes in solid polymers

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Electric Phenomena in Polymer Science

Part of the book series: Advances in Polymer Science ((POLYMER,volume 33))

Abstract

The article outlines our current understanding of the multiple relaxations observed in crystalline and amorphous solid polymers, as studied using dielectric techniques. An attempt is made to interpret the relaxations of amorphous polymers in a unified way, independent of the details of chemical structure, by use of the time-correlation function approach to partial and total relaxations. In addition, the recent studies of polymers of medium and high degrees of crystallinity are reviewed.

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V References

  • Abragam, A.: Principles of nuclear magnetism, London: Oxford U.P. 1961

    Google Scholar 

  • Adachi, K., Fujihara, I., Ishida, Y.: J. Polym. Sci., Polym. Phys. Ed. 13, 2155 (1975)

    Article  CAS  Google Scholar 

  • Adachi, K., Ishida, Y.: J. Polym. Sci., Polym. Phys. Ed. 15, 693 (1977)

    Article  CAS  Google Scholar 

  • Adachi, K., Hattori, M., Ishida, Y.: J. Polym. Sci., Polym. Phys. Ed. 15, 693 (1977)

    Article  CAS  Google Scholar 

  • Adam, G.: J. Chem. Phys. 43, 662 (1965)

    Article  CAS  Google Scholar 

  • Allen, G., Higgins, J. S.: Rep. Progr. Phys. 36, 1073 (1973)

    Article  CAS  Google Scholar 

  • Anderson, J. E., Ullman, R.: J. Chem. Phys. 47, 2178 (1967)

    Article  CAS  Google Scholar 

  • Anderson, J. E., cited In: J. Chem. Soc., Faraday Symp., 6, 1972, p. 90 of Discussion

    Google Scholar 

  • Ashcraft, C. R., Boyd, R. H.: J. Polym. Sci., Polym. Phys. Ed. 14, 2153 (1976)

    Article  CAS  Google Scholar 

  • Baird, M. E.: Electrical properties of polymeric materials. London: The Plastics Institute 1973

    Google Scholar 

  • Beevers, M. S., Williams, G.: Adv. Mol. Relax. Proc. 7, 237 (1975)

    Article  CAS  Google Scholar 

  • Beevers, M. S., Crossley, J., Garrington, D. C., Williams, G.: J. Chem. Soc., Faraday Trans. II, 72, 1482 (1976)

    Article  CAS  Google Scholar 

  • Beevers, M. S., Crossley, J., Garrington, D. C., Williams, G.: J. Chem. Soc., Faraday Trans. II, 73, 458 (1977a)

    Article  CAS  Google Scholar 

  • Beevers, M. S., Crossley, J., Garrington, D. C., Williams, G.: J. Chem. Soc., Faraday Symp. 11, 38 (1977b)

    Article  CAS  Google Scholar 

  • Berne, B. J., Harp, G. D.: Adv. Chem. Phys. 17, 63 (1970)

    Article  CAS  Google Scholar 

  • Berne, B. J.: In: Physical chemistry, an advanced treatise, Vol. VIII B, The liquid state, ed. Eyring, H., Jost, W., Henderson, D., New York: Academic Press 1971

    Google Scholar 

  • Berne, B. J., Pecora, R.: Dynamic light scattering, New York: Wiley-Interscience 1976

    Google Scholar 

  • Billmeyer, F. W.: Textbook of polymer science, Second Ed., New York: Wiley 1971

    Google Scholar 

  • Birshtein, T. M., Ptitsyn, O. B.: Conformations of macromolecules, (Transl. from 1964 edition by S. M. Timasheff and M. J. Timasheff), New York: Wiley-Interscience 1966

    Google Scholar 

  • Böttcher, C. J. F.: Theory of electric polarization, Second Ed., Vol. I, 1973, Amsterdam: Elsevier

    Google Scholar 

  • Böttcher, C. J. F.: Theory of electric polarization, Second Ed., Vol. II, 1978, Amsterdam: Elsevier

    Google Scholar 

  • Brereton, M. G., Davies, G. R.: Polymer 18, 1764 (1977)

    Article  Google Scholar 

  • Brereton, M. G., Davies, G. R., Rushworth, A., Spence, J.: J. Polym. Sci., Polym. Phys. Ed. 15, 583 (1977)

    Article  CAS  Google Scholar 

  • Cook, M., Watts, D. C., Williams, G.: Trans. Faraday Soc. 66, 2503 (1970)

    Article  CAS  Google Scholar 

  • Cook, M., Ph. D. Thesis, Univ. of Wales 1971

    Google Scholar 

  • Crossley, J., Williams, G.: J. Chem. Soc., Faraday Trans. II 73, 1906 (1978)

    Article  Google Scholar 

  • Davies, G. R., Ward., I. M.: J. Polym. Sci., Part B 7, 353 (1969)

    Article  CAS  Google Scholar 

  • Debye, P., Polar molecules, New York: Chemical Catalog 1929

    Google Scholar 

  • DiMarzio, E. A., Bishop, H.: J. Chem. Phys. 60, 3802 (1974)

    Article  CAS  Google Scholar 

  • Dubois-Violette, E., Geny, F., Monnerie, L., Parodi, O.: J. Chim. Phys. 66, 1865 (1969)

    CAS  Google Scholar 

  • Ferry, J. D.: Viscoelastic properties of polymers, New York: Wiley 1961

    Google Scholar 

  • Flory, P. J.: Statistical mechanics of chain molecules, New York: Wiley-Interscience 1969

    Google Scholar 

  • Fröhlich, H.: Theory of dielectrics, London: Oxford U.P. 1958

    Google Scholar 

  • Fuoss, R. M., Kirkwood, J. G.: J. Am. Chem. Soc. 63, 385 (1941)

    Article  CAS  Google Scholar 

  • Furukawa, T., Fukada, E.: Nature 221, 1235 (1969)

    Article  CAS  Google Scholar 

  • Furukawa, T., Fukada, E.: J. Polym. Sci. 14, 1979 (1976)

    CAS  Google Scholar 

  • Geny, F., Monnerie, L.: J. Polym. Sci., Polym. Phys. Ed. 15, 1 (1977)

    Article  CAS  Google Scholar 

  • Glarum, S. H.: J. Chem. Phys. 33, 639 (1960)

    Article  CAS  Google Scholar 

  • Hayakawa, R., Wada, Y.: Adv. Polym. Sci. 11, 1 (1973)

    CAS  Google Scholar 

  • Hayakawa, R., Wada, Y.: J. Polym. Sci., Polym. Phys. Ed. 12, 2119 (1974)

    Article  CAS  Google Scholar 

  • Hedvig, P.: Dielectric spectroscopy of polymers. Bristol: Adam Hilger 1977

    Google Scholar 

  • Heijboer, J.: Mechanical properties and molecular structure of organic polymers. Proc. Int. Conf. Non Cryst. Solids (Delft 1964), Amsterdam: North Holland p. 231, 1965

    Google Scholar 

  • Heijboer, J.: Mechanical Properties of Glassy Polymers Containing Saturated Rings. Central Lab., TNO, Communic. No. 435, The Netherlands, Delft 1972

    Google Scholar 

  • Hill, N., Vaughan, W., Price, A. H., Davies, M.: Dielectric properties and molecular behaviour. New York: Van Nostrand 1969

    Google Scholar 

  • Hoffman, J. D., Pfeiffer, H. G.: J. Chem. Phys. 22, 132 (1954)

    Article  CAS  Google Scholar 

  • Hoffman, J. D.: J. Chem. Phys. 23, 1331 (1955)

    Article  CAS  Google Scholar 

  • Hoffman, J. D., Williams, G., Passaglia, E.: J. Polym. Sci. Part C, 14, 173 (1966)

    Google Scholar 

  • Ishida, Y., Yamafuji, K.: Kolloid Z. 177, 97 (1961)

    Article  CAS  Google Scholar 

  • Ishida, Y., Matsuo, M., Yamafuji, K.: Kolloid Z. 180, 108 (1962)

    Article  CAS  Google Scholar 

  • Ishida, Y.: J. Polym. Sci., Part A-2, 7, 1835 (1969)

    CAS  Google Scholar 

  • Ivanov, E. N.: Sov. Phys., J.E.T.P. 18, 1041 (1964)

    Google Scholar 

  • Jernigan, R. L., in: Dielectric properties of polymers, ed. Karasz, F. E., New York: Plenum 1972, p. 99

    Google Scholar 

  • Johari, G. P., Smyth, C. P.: J. Am. Chem. Soc. 91, 5168 (1969)

    Article  CAS  Google Scholar 

  • Johari, G. P., Goldstein, M.: J. Phys. Chem. 74, 2034 (1970a)

    Article  CAS  Google Scholar 

  • Johari, G. P., Goldstein, M.: J. Chem. Phys. 53, 2372 (1970b)

    Article  CAS  Google Scholar 

  • Johari, G. P., Smyth, C. P.: J. Chem. Phys. 56, 4411 (1972)

    Article  CAS  Google Scholar 

  • Johari, G. P., in: J. Chem. Soc., Faraday Symp. 6, 1972, p. 42 of Discussion

    Article  Google Scholar 

  • Johari, G. P.: J. Chem. Phys. 58, 1766 (1973)

    Article  CAS  Google Scholar 

  • Johari, G. P.: Ann. New York Acad. Sci. 279, 117 (1976)

    Article  CAS  Google Scholar 

  • Jonscher, A. K.: Nature 253, 717 (1975a)

    Article  CAS  Google Scholar 

  • Jonscher, A. K.: Kolloid Z. 253, 231 (1975b)

    CAS  Google Scholar 

  • Jonscher, A. K.: Nature 267, 673 (1977)

    Article  CAS  Google Scholar 

  • Kakizaki, M., Hideshima, T.: J. Macromol. Sci., Phys. B-8, 367 (1973)

    Google Scholar 

  • Kakutani, H.: J. Polym. Sci., Part A-2, 8, 1177 (1970)

    CAS  Google Scholar 

  • Karasz, F. E., (ed).: Dielectric properties of polymers. New York: Plenum 1972

    Google Scholar 

  • Kielich, S., in: Dielectric and related molecular processes, ed. M. Davies, (Spec. Period. Rep.), London, The Chem. Soc. 1, 293 (1972)

    Google Scholar 

  • Kirkwood, J. G.: J. Chem. Phys. 7, 911 (1939)

    Article  CAS  Google Scholar 

  • Kirkwood, J. G., Fuoss, R. M.: J. Chem. Phys. 9, 329 (1941)

    Article  CAS  Google Scholar 

  • Koizumi, N., Yano, S., Tsunashima, K.: J. Polym. Sci., Part B, 7, 59 (1969)

    Article  CAS  Google Scholar 

  • Koppelmann, J., Gielessen, J.: Z. Elektrochem. 65, 689 (1961)

    CAS  Google Scholar 

  • McCall, D. W., in: Molecular dynamics and structure of solids, ed. Carter, R. J., Rush, J. J., Washington, Nat. Bur. Stand., Spec. Public. No. 301, 1969

    Google Scholar 

  • McCrum, N. G., Read, B. E., Williams, G.: Anelastic and dielectric effects in polymeric solids, New York: Wiley 1967

    Google Scholar 

  • Mansfield, M., Boyd, R. H.: J. Polym. Sci., Polym. Phys. 16, 1227 (1978)

    Article  CAS  Google Scholar 

  • Matsuoka, S., Roe, R. J., Cole, H. F., in: Dielectric properties of polymers, Karasz, F. E., ed., New York: Plenum 1972, p. 255

    Google Scholar 

  • Mopsik, F. I., Broadhurst, M. G.: J. Appl. Phys. 46, 4204 (1975)

    Article  Google Scholar 

  • Murayama, N.: J. Polym. Sci. Polym. Phys. Ed., 13, 929 (1975)

    Article  CAS  Google Scholar 

  • Murayama, N., Oikawa, T., Katto, T., Nakamura, K.: J. Polym. Sci., Polym. Phys. Ed., 13, 1033 (1975)

    Article  CAS  Google Scholar 

  • Murayama, N., Hashizume, H.: J. Polym. Sci., Polym. Phys. Ed. 14, 989 (1976)

    Article  CAS  Google Scholar 

  • Nagai, K., Ishikawa, T.: J. Chem. Phys. 43, 4508 (1965)

    Article  CAS  Google Scholar 

  • Nakagawa, K., Ishida, Y.: J. Polym. Sci., Polym. Phys. Ed. 11, 1503 (1973)

    CAS  Google Scholar 

  • Nakagawa, K., Tsuru, S.: J. Polym. Sci., Polym. Phys. Ed. 14, 1755 (1976)

    Article  CAS  Google Scholar 

  • Nakamura, K., Wada, Y.: J. Polym. Sci., Part A-2, 9, 161 (1971)

    Article  CAS  Google Scholar 

  • O'Reilly, J. M.: J. Polym. Sci. 47, 429 (1962)

    Article  Google Scholar 

  • Osaki, S., Uemura, S., Ishida, Y.: J. Polym. Sci., Part A-2, 9, 585 (1971)

    Article  CAS  Google Scholar 

  • Osaki, S., Ishida, Y.: J. Polym. Sci., Polym. Phys. Ed. 12, 1727 (1974)

    Article  CAS  Google Scholar 

  • Phillips, M. C., Barlow, A. J., Lamb, J.: Proc. Roy. Soc., A, 329, 193 (1972a)

    Article  CAS  Google Scholar 

  • Phillips, P. J., Kleinheis, G., Stein, R. S.: J. Polym. Sci. Polym. Phys. Ed. 10, 1593 (1972b)

    CAS  Google Scholar 

  • Phillips, P. J., Wilkes, G. L., Delf, B. W., Stein, R. S.: J. Polym. Sci., Polym. Phys. Ed. 9, 499 (1971)

    Google Scholar 

  • Pohl, H. A., Bacskai, R., Purcell, W. P.: J. Phys. Chem. 64, 1701 (1960)

    Article  CAS  Google Scholar 

  • Rahman, A.: Phys. Rev. A, 136, 405 (1964)

    CAS  Google Scholar 

  • Rahman, A., Stillinger, F. H.: J. Chem. Phys. 55, 3336 (1971)

    Article  CAS  Google Scholar 

  • Read, B. E.: Trans. Faraday Soc. 61, 2140 (1965)

    Article  CAS  Google Scholar 

  • Rothschild, W. G., Rosasco, G. J., Livingston, R. C.: J. Chem. Phys. 62, 1253 (1975)

    Article  CAS  Google Scholar 

  • Saito, N., Okano, K., Iwayanagi, S., Hideshima, T., in: Solid state physics. Seitz, F., Turnbull, D., eds., New York: Academic Press, 1963, Vol. XIV, p. 343

    Google Scholar 

  • Saito, S.: Study of molecular motions in solid polymers by the dielectric measurements. Res. of the Electrotechn. Lab., Tokyo, Japan, Publ. No. 648, 1964

    Google Scholar 

  • Saito, S., Sasabe, H., Nakajima, T., Yada, K.: J. Polym. Sci., Part A-2, 6, 1297 (1968)

    Article  CAS  Google Scholar 

  • Sasabe, H., Saito, S.: J. Polym. Sci., Part A-2, 6, 1401 (1968)

    Article  CAS  Google Scholar 

  • Sasabe, H., Saito, S., Asahina, M., Kakutani, H.: J. Polym. Sci., Part A-2, 7, 1405 (1969)

    Article  CAS  Google Scholar 

  • Sasabe, H.: Res. of the Electrotech. Lab., Tokyo, Japan, Publ. No. 721, 1971

    Google Scholar 

  • Sawada, K., Ishida, Y.: J. Polym. Sci., Polym. Phys. Ed., 13, 2247 (1975)

    Article  CAS  Google Scholar 

  • Schaefer, J., Stejskal, E. O., Buchdahl, R.: Macromolecules 10, 384 (1977)

    Article  CAS  Google Scholar 

  • Scott, A. H., Scheiber, D. J., Curtis, A. J., Lauritzen, J. I., Hoffman, J. D.: J. Res. Natl. Bur. Stds. 66A, 269 (1962)

    CAS  Google Scholar 

  • Shimizu, K., Yano, O., Wada, Y.: J. Polym. Sci., Polym. Phys. Ed. 13, 1959 (1975)

    Article  CAS  Google Scholar 

  • Shindo, H., Murakami, I., Yamamura, H.: J. Polym. Sci., Part A-1, 7, 297 (1969)

    Article  CAS  Google Scholar 

  • Starkweather, H. W.: J. Polym. Sci., Polym. Phys. Ed., 15, 247 (1977)

    Article  CAS  Google Scholar 

  • Stockmayer, W. H.: Pure Appl. Chem. 15, 539 (1967)

    Article  Google Scholar 

  • Stockmayer, W. H., in: Fluides moleculaires, Balian, R. and Weill, G., ed., New York: Gordon and Breach 1976, p. 101

    Google Scholar 

  • Tanaka, A., Uemura, S., Ishida, Y.: J. Polym. Sci., Part A-2, 8, 1585 (1970)

    Article  CAS  Google Scholar 

  • Tanaka, A., Ishida, Y.: Polym. Sci., Polym. Phys. Ed., 10, 1029 (1972)

    CAS  Google Scholar 

  • Tanaka, A., Uemura, S., Ishida, Y.: J. Polym. Sci., Polym. Phys. Ed. 10, 2093 (1972)

    CAS  Google Scholar 

  • Tanaka, A., Ishida, Y.: J. Polym. Sci., Polym. Phys. Ed. 12, 335 (1974)

    Article  CAS  Google Scholar 

  • Tidy, D., Williams, G., manuscript in preparation (1978)

    Google Scholar 

  • Uemura, S.: J. Polym. Sci., Polym. Phys. Ed. 10, 2155 (1972)

    CAS  Google Scholar 

  • Uemura, S.: J. Polym. Sci., Polym. Phys. Ed. 12, 1177 (1974)

    Article  CAS  Google Scholar 

  • Valeur, B., Monnerie, L.: J. Polym. Sci., Polym. Phys. Ed. 14, 11, 29 (1976)

    Article  CAS  Google Scholar 

  • Van Turnhout, J.: Thermally stimulated discharge of polymer electrets. Amsterdam: Elsevier 1975

    Google Scholar 

  • Van Turnhout, J.: Thermally stimulated discharge of electrets. To be publ. In: Electrets, ed. Sessler, G. M., Topics in Physics Series, Berlin, Heidelberg, New York: Springer 1978

    Google Scholar 

  • Volkenstein, M. V.: Configurational statistics of polymeric chains. New York: Wiley-Interscience 1963

    Google Scholar 

  • Wada, Y., Hayakawa, R.: Japan J. Appl. Phys. 15, 2041 (1976)

    Article  CAS  Google Scholar 

  • Wada, Y., in: Dielectric and related molecular Processes, ed. M. Davies (Spec. Period. Report), London, The Chem. Soc. 3, 143 (1977)

    Chapter  Google Scholar 

  • Williams, G.: Trans. Faraday Soc. 60, 1548 (1964a)

    Article  CAS  Google Scholar 

  • Williams, G.: Trans. Faraday Soc. 60, 1556 (1964b)

    Article  CAS  Google Scholar 

  • Williams, G.: Trans. Faraday Soc. 61, 1564 (1965)

    Article  CAS  Google Scholar 

  • Williams, G.: Trans. Faraday Soc. 62, 1321 (1966a)

    Article  CAS  Google Scholar 

  • Williams, G.: Trans. Faraday Soc. 62, 2091 (1966b)

    Article  CAS  Google Scholar 

  • Williams, G., In: Molecular relaxation processes. Chem. Soc. (London) Spec. Publ. No. 20, London: The Chem. Soc., and New York: Academic Press, p. 21, 1966c

    Google Scholar 

  • Williams, G., Edwards, D. A.: Trans. Faraday Soc. 62, 1329 (1966)

    Article  CAS  Google Scholar 

  • Williams, G., Lauritzen, J. I., Hoffman, J. D.: J. Appl. Phys. 38, 4203 (1967)

    Article  CAS  Google Scholar 

  • Williams, G., Watts, D. C.: Trans. Faraday Soc. 66, 80 (1970)

    Article  CAS  Google Scholar 

  • Williams, G., Watts, D. C., in: NMR, basic principles and progress, Vol. IV, NMR of Polymers, Berlin, Heidelberg, New York: Springer, p. 271 1971a

    Google Scholar 

  • Williams, G., Watts, D. C.: Trans. Faraday Soc. 67, 2793 (1971b)

    Article  CAS  Google Scholar 

  • Williams, G., Watts, D. C.: Trans. Faraday Soc. 67, 1971 (1971c)

    Article  CAS  Google Scholar 

  • Williams, G., Watts, D. C., Dev, S. B., North, A. M.: Trans. Faraday Soc. 67, 1323 (1971)

    Article  CAS  Google Scholar 

  • Williams, G., Hains, P. J.: Chem. Phys. Lett. 10, 585 (1971)

    Article  CAS  Google Scholar 

  • Williams, G., Cook, M., Hains, P. J.: J. Chem. Soc., Faraday Trans. II. 68, 1045 (1972a)

    Article  CAS  Google Scholar 

  • Williams, G.: Chem. Rev. 72, 55 (1972a)

    Article  CAS  Google Scholar 

  • Williams, G., In: J. Chem. Soc., Faraday Symp. No. 6, 1972, p. 44 of discussion (1972b)

    Google Scholar 

  • Williams, G., in: Dielectric properties of polymers, Karasz, F. E., ed., New York: Plenum 1972, p. 17 (1972c)

    Google Scholar 

  • Williams, G., Watts, D. C., Nottin, J. P.: J. Chem. Soc., Faraday Trans. II, 68, 16 (1972b)

    Article  CAS  Google Scholar 

  • Williams, G., Hains, P. J.: J. Chem. Soc. Faraday Symp. 6, 14 (1972)

    Article  Google Scholar 

  • Williams, G., in: Dielectric and related molecular processes, ed. M. Davies (Spec. Period. Report), London, The Chem. Soc. 2, 151 (1975)

    Chapter  Google Scholar 

  • Williams, G.: Chem. Soc. Rev. 7, 89 (1978)

    Article  CAS  Google Scholar 

  • Williams, G., Crossley, J.: Ann. Rep. A, London, The Chem. Soc. 11 (1978)

    Google Scholar 

  • Yamafuji, K.: J. Phys. Soc. (Japan) 15, 2295 (1960)

    Article  CAS  Google Scholar 

  • Yamafuji, K., Ishida, Y.: Kolloid Z. 183, 15 (1962)

    CAS  Google Scholar 

  • Yano, S.: J. Polym. Sci., Part A-2, 8, 1057 (1970)

    Article  CAS  Google Scholar 

  • Yano, S., Tadano, K., Aoki, K., Koizumi, N.: J. Polym. Sci., Polym. Phys. Ed. 12, 1875 (1974)

    Article  CAS  Google Scholar 

  • Yano, O., Saiki, K., Tarucha, T., Wada, Y.: J. Polym. Sci., Polym. Phys. Ed. 15, 43 (1977)

    Article  CAS  Google Scholar 

  • Yano, O., Kamoshida, T., Sekiyama, S., Wada, Y.: J. Polym. Sci., Polymer Phys. Ed. 16, 679 (1978)

    Article  CAS  Google Scholar 

  • Zwanzig, R.: Ann. Rev. Phys. Chem. 16, 67 (1965)

    Article  CAS  Google Scholar 

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  1. Edward Davies Chemical Laboratories, University College of Wales, SY23 1NE, Aberystwyth, Dyfed, U.K.

    Graham Williams

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Williams, G. (1979). Molecular aspects of multiple dielectric relaxation processes in solid polymers. In: Electric Phenomena in Polymer Science. Advances in Polymer Science, vol 33. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-09456-3_3

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