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Electroinitiated polymerization on electrodes

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Electric Phenomena in Polymer Science

Part of the book series: Advances in Polymer Science ((POLYMER,volume 33))

Abstract

Electroinitiated polymerization reactions leading to the formation of polymer on electrode surfaces — as distinguished from that in the bulk of the electrolytic solution — are discussed here. The structure and morphology of the polymer, and its bonding and adhesion to the electrode surface are examined in addition to the mechanisms of polymerization. The formation of adherent coatings on electrodes discussed in this manner is that of polymers from not only vinyl monomers, but also from phenols, acrolein, benzonitrile, polyimide intermediates and phenylacetylene. The novel use of carbon fiber electrodes in electroinitiated polymerization is introduced and its significance to interphase modification in carbon fiber composites is brought out. With continuing advances in techniques for the study of the formation, control, and properties of polymer films on electrodes, concurrent progress in investigation of surface coatings and graphite composites is indicated.

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  1. Department of Materials Science and Engineering, Washington State University, 99164, Pullman, WA

    R. V. Subramanian

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  1. R. V. Subramanian
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© 1979 Springer-Verlag

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Subramanian, R.V. (1979). Electroinitiated polymerization on electrodes. In: Electric Phenomena in Polymer Science. Advances in Polymer Science, vol 33. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-09456-3_2

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  • DOI: https://doi.org/10.1007/3-540-09456-3_2

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-09456-2

  • Online ISBN: 978-3-540-35229-7

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