Skip to main content
SpringerLink
Log in

Molecular interactions and macroscopic properties of polyacrylonitrile and model substances

  • Conference paper
  • First Online:
Chemistry

Part of the book series: Advances in Polymer Science ((POLYMER,volume 32))

Abstract

The relationships between intra- and intermolecular forces in polyacrylonitrile on the one hand, and the macroscopic behavior of the polymer and fibers thereof on the other, are reviewed. Characteristic properties such as the very high polymerization rate constant in water, the dissolution of the polymer in concentrated inorganic salt solutions, the high melting point, the strong depression of melting point and glass transition temperature by water, the plasticization by polar additives, etc., are traced back to their molecular origins, in particular to the strong intra- and intermolecular noncovalent bonding caused by the highly polar nitrile group. The effects of dipole-dipole interaction, hydrogen bonding and electron-donor-acceptor complex formation are discussed separately.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

6 References

  1. Hinrichsen, G.: Melliand Textilber. 58, 7 (1977)

    Google Scholar 

  2. Handbook of Chemistry and Physics, CRC Press, 57 th Edition 1976

    Google Scholar 

  3. Saum, A. M.: J. Polymer Sci. 42, 57 (1960)

    Google Scholar 

  4. Buckingham, A. D., Raab, R. E.: J. Chem. Soc. 1961, 5511

    Google Scholar 

  5. Zhukova, E. L.: Opt. Spektroscop. 4, 750 (1958)

    Google Scholar 

  6. Freedman, T. B., Nixon, E. R.: Spectrochim. Acta 28 A, 1375 (1972)

    Google Scholar 

  7. Paoloni, L., Hauser, S.: Bull. Soc. Chim. Belg. 84, 219 (1975)

    Google Scholar 

  8. Dagnino, M. R., La Manna, G., Paoloni, L.: Chem. Phys. Letters 39, 552 (1976), and references therein

    Google Scholar 

  9. Rowlinson, J. S.: Trans. Faraday Soc. 45, 974 (1949)

    Google Scholar 

  10. Lambert, J. D., Roberts, A. H., Rowlinson, J. S., Wilkinson, V. J.: Proc. Royal Soc., A, 196, 113 (1949)

    Google Scholar 

  11. Thomas, B. H., Orville-Thomas, W. J.: J. Mol. Structure 3, 191 (1969)

    Google Scholar 

  12. Krigbaum, W. R., Takita, N.: J. Polymer Sci. 43, 467 (1960)

    Google Scholar 

  13. Bohn, C. R., Schaefgen, J. R., Statton, W. O.: J. Polym. Sci. 55, 531 (1961)

    Google Scholar 

  14. Rosenbaum, S.: J. Appl. Polymer Sci. 9, 2071 (1965)

    Google Scholar 

  15. See, e. g., Stuart, H. A. (ed.): Die Physik der Hochpolymeren, Vol. 1. Berlin, Heidelberg, New York: Springer 1952

    Google Scholar 

  16. Dart, S. L.: Textile Res. J. 30, 372 (1960)

    Google Scholar 

  17. Knudsen, J. P., Fitzgerald, W.: The Influence of Gel-Network Mechanics on the Tensile Properties of Wet Spun Fibers, Presented at Gordon Conference on Textiles, 1965

    Google Scholar 

  18. Bell, J. P., Dumbleton, J. H.: Textile Res. J. 41, 196 (1971)

    Google Scholar 

  19. Hinrichsen, G., Orth, H.: Kolloid Z. 247, 844 (1971)

    Google Scholar 

  20. Hinrichsen, G.: J. Appl. Polymer Sci. 17, 3305 (1973)

    Google Scholar 

  21. Colvin, B. G., Storr, P.: Europ. Polymer J. 10, 337 (1974)

    Google Scholar 

  22. Huang, Y. S., Koenig, J. L.: Appl. Spectrosc. 25, 620 (1971)

    Google Scholar 

  23. See, e. g., Grassie, N., Hay, J. N.: J. Polymer Sci. 56, 189 (1962); Friedlander, H. N., Peebles, L. H., Brandrup, J., Kirby, J. R.: Macromolecules 1, 79 (1968); Ulbrich, J., Makschin, W.: Faserforsch. Textiltech. 22, 381 (1971)

    Google Scholar 

  24. Dunn, P., Ennis, B. C.: J. Appl. Polymer Sci. 14, 1795 (1970)

    Google Scholar 

  25. Hinrichsen, G.: Angew. Makromol. Chem. 20, 121 (1974)

    Google Scholar 

  26. Schatzki, T. F.: J. Appl. Polymer Sci. 5, S1 (1961)

    Google Scholar 

  27. Loshaek, S., Fox, T. G.: Bull. Am. Phys. Soc. 1, 123 (1956)

    Google Scholar 

  28. Kimmel, R. M., Andrews, R. D.: J. Appl. Phys. 36, 3063 (1965)

    Google Scholar 

  29. Ogura, K., Kawamura, S., Sobue, H.: Macromolecules 4, 79 (1971)

    Google Scholar 

  30. Hinrichsen, G.: J. Polymer Sci. C, 38, 303 (1972)

    Google Scholar 

  31. Cotton, G. R., Schneider, W. C.: Kolloid Z. 192, 16 (1963)

    Google Scholar 

  32. Andrews, R. D., Kimmel, R. M.: Polymer Letters 3, 167 (1965)

    Google Scholar 

  33. See, e. g., Murayama, T., Bell, J. P.: J. Polymer Sci. A-2 8, 437 (1970)

    Google Scholar 

  34. Rosenbaum, S.: J. Appl. Polymer, Sci. 9, 2085 (1965)

    Google Scholar 

  35. Umeyama, H., Morokuma, K.: J. Amer. Chem. Soc. 99, 1316 (1977) and references therein; Morokuma, K.: J. Chem. Phys. 55, 1236 (1971)

    Google Scholar 

  36. Kollman, P. A., Allen, L. C.: J. Amer. Chem. Soc. 93, 4997 (1971)

    Google Scholar 

  37. Al-Jabury, M., Turner, D. W.: J. Chem. Soc. 1964, 4434

    Google Scholar 

  38. Field, F. H., Franklin, J. R.: Electron impact phenomena, New York: Academic Press 1957

    Google Scholar 

  39. Allred, A., Rochow, E.: J. Inorg. Nucl. Chem. 5, 264, 269 (1958)

    Google Scholar 

  40. Pimentel, G., McClellan, A.: The hydrogen bond. Freeman, W. H., San Francisco, Calif. 1960

    Google Scholar 

  41. Kollman, P.: J. Amer. Chem. Soc. 99, 4875 (1977)

    Google Scholar 

  42. 100, 2974 (1978)

    Google Scholar 

  43. Luck, W. A. P.: Topics Curr. Chem. 64, 113 (1976)

    Google Scholar 

  44. Owicki, J. C., Scheraga, H. A.: J. Amer. Chem. Soc. 99, 7403 (1977)

    Google Scholar 

  45. Swaminathan, S., Beveridge, D. L.: J. Amer. Chem. Soc. 99, 8392 (1977)

    Google Scholar 

  46. Rahman, A., Stillinger, F. H.: J. Chem. Phys. 55, 336 (1971); J. Amer. Chem. Soc. 95, 7943 (1973)

    Google Scholar 

  47. Stillinger, F. H.: Adv. Chem. Phys. 31, 1 (1975)

    Google Scholar 

  48. Hankins, D., Moskowitz, J., Stillinger, F.: J. Chem. Phys. 53, 4544 (1970)

    Google Scholar 

  49. Del Bene, J. E.: J. Chem. Phys. 57, 1899 (1972)

    Google Scholar 

  50. Popkie, H., Kistenmacher, H., Clementi, E.: J. Chem. Phys. 59, 1325 (1973)

    Google Scholar 

  51. Stillinger, F., Rahman, A.: J. Chem. Phys. 60, 1545 (1974)

    Google Scholar 

  52. Diercksen, G. H. F., Kraemer, W. P., Roos, B. O.: Theoret. Chim. Acta 36, 249 (1975)

    Google Scholar 

  53. Kollman, P., McKelvey, J., Johansson, A., Rothenberg, S.: J. Amer. Chem. Soc. 97, 955 (1975)

    Google Scholar 

  54. Matsuoka, O., Clementi, E., Yoshimine, M.: J. Chem. Phys. 64, 1351 (1976)

    Google Scholar 

  55. Swietoslowsky, W.: Acad. Polon. 1931, Nr. 2,6.7

    Google Scholar 

  56. Bernal, J. D., Fowler, R. H.: J. Chem. Phys. 1, 515 (1933)

    Google Scholar 

  57. Dyke, T. R., Muenter, J. S.: J. Chem. Phys. 60, 2929 (1974)

    Google Scholar 

  58. Perelygin, I. S., Shaikhova, A. B.: Opt. Spectrosk. 31, 205 (1971)

    Google Scholar 

  59. LeNarvor, A., Gentric, E., Saumagne, P.: Can. J. Chem. 49, 1933 (1971)

    Google Scholar 

  60. Kobayashi, H.: Kagaku (Kyoto) 23, 315 (1953)

    Google Scholar 

  61. Del Bene, J. E.: Chem. Phys. Letters. 24, 203 (1974)

    Google Scholar 

  62. Murthy, A. S. N., Saini, G. R., Devi, K., Shah, S. B.: Adv. Mol. Relax. Proc. 7, 255 (1975)

    Google Scholar 

  63. Turner, D. W., Baker, A. D., Baker, C., Brundle, C. R.: Molecular photoelectron spectroscopy, p. 346. New York: Wiley 1970

    Google Scholar 

  64. Siderova, A. I., Narziev, B. N.: Ukr. Fiz. Zh. 12, 317 (1967)

    Google Scholar 

  65. Brandrup, J., Immergut, E. H. (eds.): Polymer Handbook, New York: Wiley 1975

    Google Scholar 

  66. See, e. g. Schulz, G. V.: Adv. Polymer Sci. 9, 1 (1972)

    Google Scholar 

  67. Dainton, F. S., Sisley, W. D.: Trans. Faraday Soc. 59, 1369 (1963)

    Google Scholar 

  68. White, S. C., Thompson, H. W.: Proc. Roy. Soc. London, A-291, 460 (1966)

    Google Scholar 

  69. Henrici-Olivé, G., Olivé, S.: unpublished

    Google Scholar 

  70. Henrici-Olivé, G., Olivé, S.: Polymer Bulletin, 1, 47 (1978)

    Google Scholar 

  71. See, e.g., Henrici-Olivé, G., Olivé, S.: Coordination and catalysis, Weinheim and New York: Verlag Chemie 1977

    Google Scholar 

  72. Bamford, C. H., Jenkins, A. D., Johnston, R.: Proc. Roy. Soc., London, A-241, 364 (1957)

    Google Scholar 

  73. Costain, C. C., Stoicheff, B. P.: J. Chem. Phys. 30, 777 (1959)

    Google Scholar 

  74. Ger. Offen. 2,343,571, 1972 (Du Pont)

    Google Scholar 

  75. Bell, J. P., Murayama, T.: J. Appl. Polymer Sci. 12, 1795 (1968)

    Google Scholar 

  76. Rosenbaum, S.: Textile Res. J. 34, 291 (1964)

    Google Scholar 

  77. Sotton, M., Vialard, A. M., Rabourdin, Ch.: Bull. Scient. ITF (France) 2, 173 (1973)

    Google Scholar 

  78. Sotton, M., Jaquemart, J., Monrocq, R.: Bull. Scient. ITF (France), 2, 247 (1973)

    Google Scholar 

  79. Stewart, J. C., Whewell, C. S.: Text. Res. J. 30, 903, 912 (1960)

    Google Scholar 

  80. Friedlander, H. N., Menikheim, V.: Chemical reactions on polymeric fiber surfaces, in Ledwith, A., North, A. M. (eds.): Molecular behavior and the development of polymeric materials. London: Chapman and Hall 1975

    Google Scholar 

  81. Miller, B.: The wetting of fibers, in Schick, M. J. (ed.): Surface characteristics of fibers and textiles, Part. II. New York: Marcel Dekker 1977

    Google Scholar 

  82. Pontrelli, G. J.: Partial analysis of comfort's gestalt, in Hollies, N. R. S., Goldman, R. F. (eds.): Clothing comfort. Ann Arbor Sci. Publ. Inc. 1977

    Google Scholar 

  83. B. P. 851, 829; 852,521, 1977, (Bayer A. G.); see also Melliand Textilber. 58, 11 (1977)

    Google Scholar 

  84. Gur-Arieh, Z., Ingamells, W., Peters, R. H.: J. Appl. Polymer Sci. 20, 41 (1976); GurArieh, Z., Ingamells, W.: J. S. D. C. 90, 8 (1974)

    Google Scholar 

  85. U. S. P. 3,147,322 (1964)

    Google Scholar 

  86. Walton, R. A.: Quart. Rev. (London) 19, 126 (1965)

    Google Scholar 

  87. Ha, T. K.: J. Mol. Structure 11, 185 (1972)

    Google Scholar 

  88. Hoard, J. L., Owen, T. B., Buzzell, A., Salmon, O. N.: Acta, Cryst., 3, 130 (1950)

    Google Scholar 

  89. Howard, J. A. K., Smart, L. E., Gilmore, C. J.: J. C. S. Chem. Comm. 1976, 477

    Google Scholar 

  90. Purcell, K. F., Drago, R. S.: J. Amer. Chem. Soc. 88, 919 (1966)

    Google Scholar 

  91. Matsubara, I.: Bull. Chem. Soc., Japan 34, 1710, 1719 (1961): 35, 27 (1962)

    Google Scholar 

  92. See, e. g., Cotton, F. A., Wilkinson, G.: Advanced inorganic chemistry, 3rd ed. New York: Interscience Publ. 1972

    Google Scholar 

  93. Kinoshita, Y. K., Matsubara, I., Saito, U.: Bull. Chem. Soc., Japan 32, 741, 1216 (1959)

    Google Scholar 

  94. Kinoshita, Y. K., Matsubara, I., Higuchi, T., Saito, Y.: Bull. Chem. Soc., Japan 32, 1221 (1959)

    Google Scholar 

  95. Brown, T. L., Kubota, H.: J. Amer. Chem. Soc. 83, 4175 (1961)

    Google Scholar 

  96. Walton, R. A.: Progress Inorg. Chem. 16, 1 (1972)

    Google Scholar 

  97. Reedijk, J., Zuur, A. P., Groeneveld, W. L.: Rec. Trav. Chim. Pays Bas. 86, 1127 (1967)

    Google Scholar 

  98. Al-Janabi, M.: Thesis, University of Delaware 1968

    Google Scholar 

  99. Bock, H., tom Dieck, H.: Ber. 99, 213 (1966)

    Google Scholar 

  100. Farona, M. F., Bremer, N. J.: J. Amer. Chem. Soc. 88, 3735 (1966)

    Google Scholar 

  101. Mullen, P. A., Orloff, M. K., Theoret. Chim. Acta 23, 278 (1971)

    Google Scholar 

  102. Schrauzer, G. N.: J. Amer. Chem. Soc. 81, 5310 (1959)

    Google Scholar 

  103. Luxmore, A. R., Truter, M. R.: Acta Cryst. 15, 1117 (1962)

    Google Scholar 

  104. Guggenberger, L. J.: Inorg. Chem. 12, 499 (1973)

    Google Scholar 

  105. U. S. 3,346,685, 1967 (Dow Chemical Company)

    Google Scholar 

  106. Feild, T. A., Fremon, G. H.: Textile Research J. 21, 531 (1951)

    Google Scholar 

  107. Blaker, R. H., Katz, S. M., Laucius, J. F., Remington, W. R., Schroeder, H. E.: Discuss. Faraday Soc. 16, 210 (1954)

    Google Scholar 

  108. Rath, H., Rehm, H., Rummler, H., Specht, E.: Melliand Textilber. 38, 431 (1957)

    Google Scholar 

  109. Lathan, W. A., Morokuma, K.: J. Amer. Chem. Soc. 97, 3615 (1975)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Monsanto Triangle Park Development Center Inc., 27709, Research Triangle Park, North Carolina, USA

    Gisela Henrici-Olivé & Salvador Olivé

Authors
  1. Gisela Henrici-Olivé
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Salvador Olivé
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

Copyright information

© 1979 Springer-Verlag

About this paper

Cite this paper

Henrici-Olivé, G., Olivé, S. (1979). Molecular interactions and macroscopic properties of polyacrylonitrile and model substances. In: Chemistry. Advances in Polymer Science, vol 32. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-09442-3_6

Download citation

  • DOI: https://doi.org/10.1007/3-540-09442-3_6

  • Received:

  • Published:

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-09442-5

  • Online ISBN: 978-3-540-35233-4

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation