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Preparation and properties of star-branched polymers

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Physical Chemistry

Part of the book series: Advances in Polymer Science ((POLYMER,volume 30))

Abstract

The methods available for the preparation of star-branched polymers are described. After presentation of theoretical predictions of the effect of this type of branching on the properties of polymers, available experimental data are compared and critically discussed. Thermodynamic and visco-elastic properties at infinite dilution are first presented followed by visco-elastic properties in concentrated solution and the melt. Finally the effect of star-branching on T g of low molecular weight polymers is described.

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6 References

  1. Schaefgren, J. R., Flory, P. J.: J. Am. Chem. Soc. 70, 2709 (1948)

    Article  Google Scholar 

  2. Pfannemüller, B., Burchard, W.: Makromol. Chem. 121, 1 (1969)

    Article  Google Scholar 

  3. Burchard, W., Eschwey, A., Franken, I., Pfannemüller, B.: Structure of fibrous biopolymers. Colston Papers 26, 365 (1974)

    Google Scholar 

  4. Pfannenmüller, B. Burchard, W., Franken, I.: Stärke 28, 1 (1976)

    Article  Google Scholar 

  5. Swarc, M.: Carbanions, living polymers and electron transfer processes. New York: Interscience 1968

    Google Scholar 

  6. Bywater, S.: Progr. Polym. Sci. 4, 27 (1974)

    Article  Google Scholar 

  7. Bywater, S.: Comprehensive chemical kinetics. Amsterdam: Elsevier 15, 1 (1976)

    CAS  Google Scholar 

  8. Morton, M., Helminiak, T. E., Gadkary, S. D., Bueche, F.: J. Polym. Sci. 57, 471 (1962)

    Article  CAS  Google Scholar 

  9. Wenger, F., Yen, S.-P. S.: Polymer Reprints A.C.S. 3 (1) 162 (1962)

    CAS  Google Scholar 

  10. Altares, T., Wyman, D. P., Allen, V. R., Meyerson, K.: J. Polym. Sci. (Part A) 3, 4131 (1965)

    CAS  Google Scholar 

  11. Meunier, J.-C., van Leemput, R.: Makromol. Chem. 142, 1 (1971)

    Article  CAS  Google Scholar 

  12. Gervasi, J. A., Gosnell, A. B.: J. Polym. Sci. (Part A1) 4, 1391 (1966)

    CAS  Google Scholar 

  13. Zelinsky, R. P., Wofford, C. F.: J. Polym. Sci. (Part A) 3, 93 (1965)

    Google Scholar 

  14. Hsieh, H. L.: Rubber Chem. Tech. 49, 1307 (1976)

    Google Scholar 

  15. Roovers, J. E. L., Bywater, S.: Macromolecules 5, 384 (1972)

    Article  CAS  Google Scholar 

  16. Herz, J., Strazielle, C.: C. R. Acad. Sci. 272, 747 (1971)

    CAS  Google Scholar 

  17. Herz, J., Hert, M., Strazielle, C.: Makromol. Chem. 160, 213 (1972)

    Article  CAS  Google Scholar 

  18. Hert, M., Strazielle, C., Herz, J.: C. R. Acad. Sci. C276, 395 (1973)

    Google Scholar 

  19. Bryce, W. A. J., McGibbon, G., Meldrum, J. G.: Polymer 11, 394 (1970)

    Article  CAS  Google Scholar 

  20. Decker, D., Rempp, P.: C. R. Acad. Sci. 261, 1977 (1965)

    Google Scholar 

  21. Zilliox, J.-G., Decker, D., Rempp, P.: C. R. Acad. Sci. 262, 726 (1966)

    CAS  Google Scholar 

  22. Zilliox, J.-G., Rempp, P., Parrod, J.: J. Polym. Sci. (Part C) 22, 145 (1968)

    Google Scholar 

  23. Worsfold, D. J., Zilliox, J.-G., Rempp, P.: Can. J. Chem. 47, 3379 (1969)

    Article  CAS  Google Scholar 

  24. Worsfold, D. J.: Macromolecules 3, 514 (1970)

    Article  CAS  Google Scholar 

  25. Eschwey, H., Burchard, W.: Polymer 16, 180 (1975)

    Article  CAS  Google Scholar 

  26. Kohler, A., Zilliox, J.-G., Rempp, P.: Eur. Polym. J. 8, 627 (1972)

    Article  CAS  Google Scholar 

  27. Eschwey, H., Hallensleben, M. L., Burchard, W.: Makromol. Chem. 173, 235 (1973)

    Article  CAS  Google Scholar 

  28. Bi, L.-K., Fetters, L. J.: Macromolecules 9, 732 (1976)

    Article  Google Scholar 

  29. Flory, P. J.: Principles of polymer chemistry. Ithaca: Cornell U. Press, 1953.

    Google Scholar 

  30. Zimm, B. H., Stockmayer, W. H.: J. Chem. Phys. 17, 1301 (1949)

    Article  CAS  Google Scholar 

  31. Burchard, W.: Macromolecules 7, 835, 840 (1974)

    Article  CAS  Google Scholar 

  32. Burchard, W.: Macromolecules 10, 919 (1977)

    Article  CAS  Google Scholar 

  33. Burchard, W.: British Polym. J. 9, 103 (1977)

    Article  Google Scholar 

  34. Benoit, H.: J. Polym. Sci. 11, 507 (1953)

    Article  CAS  Google Scholar 

  35. Stockmayer, W. H., Fixman, M.: Ann. N. Y. Acad. Sci. 57, 334 (1953)

    Article  CAS  Google Scholar 

  36. Å olc, K.: Macromolecules 6, 378 (1973)

    Article  Google Scholar 

  37. Thurmond, C. D., Zimm, B. H.: J. Polym. Sci. 8, 477 (1952)

    Article  CAS  Google Scholar 

  38. Rouse, P. E.: J. Chem. Phys. 21, 1272 (1953)

    Article  CAS  Google Scholar 

  39. Zimm, B. H.: J. Chem. Phys. 24, 269 (1956)

    Article  CAS  Google Scholar 

  40. Zimm, B. H., Kilb, R. W.: J. Polym. Sci. 37, 19 (1959)

    Article  CAS  Google Scholar 

  41. Ham, J. S.: J. Chem. Phys. 26, 625 (1957)

    Article  CAS  Google Scholar 

  42. Osaki, K., Schrag, J. L.: J. Polym. Sci. (Phys. Ed.) 11, 549 (1973)

    CAS  Google Scholar 

  43. Osaki, K.: Adv. Polymer Sci. 12, 1 (1973)

    CAS  Google Scholar 

  44. Bueche, F.: J. Chem. Phys. 20, 1959 (1952)

    Article  CAS  Google Scholar 

  45. Bueche, F.: J. Chem. Phys. 20, 599 (1952)

    Google Scholar 

  46. Berry, G. C., Fox, T. G.: Adv. Polymer Sci. 5, 261 (1968)

    Article  Google Scholar 

  47. Bueche, F.: J. Chem. Phys. 40, 484 (1964)

    Article  CAS  Google Scholar 

  48. Orofino, T. A., Wenger, F.: J. Phys. Chem. 67, 566 (1963)

    Article  CAS  Google Scholar 

  49. Roovers, J. E. L., Bywater, S.: Macromolecules 7, 443 (1974)

    Article  CAS  Google Scholar 

  50. Berry, G. C.: J. Polym. Sci. (Part A2) 9, 687 (1971)

    CAS  Google Scholar 

  51. Strazielle, C., Herz, J.: Eur. Polym. J. 13, 223 (1977)

    Article  CAS  Google Scholar 

  52. Meunier, J.-C., van Leemput, R.: Makromol. Chem. 147, 191 (1971)

    Article  CAS  Google Scholar 

  53. Zilliox, J.-G.: Makromol. Chem. 156, 121 (1972)

    Article  CAS  Google Scholar 

  54. Hadjichristidis, N., Roovers, J. E. L.: J. Polym. Sci. (Phys. Ed.) 12, 2521 (1974)

    Article  CAS  Google Scholar 

  55. Candau, F., Rempp, P., Benoit, H.: Macromolecules 5, 627 (1972)

    Article  CAS  Google Scholar 

  56. Mazur, J., McCrackin, F.: Macromolecules 10, 326 (1977)

    Article  CAS  Google Scholar 

  57. Toporowski, P. M., Roovers, J. E. L.: Macromolecules 11, 365 (1978)

    Article  CAS  Google Scholar 

  58. Orofino, T. A., Flory, P. J.: J. Chem. Phys. 26, 1067 (1957)

    Article  Google Scholar 

  59. Candau, F., Strazielle, C., Benoit, H.: Makromol. Chem. 170, 165 (1973)

    Article  CAS  Google Scholar 

  60. Stockmayer, W. H.: J. Polym. Sci. 15, 595 (1955)

    Article  CAS  Google Scholar 

  61. Berry, C. G., Orofino, T. A.: J. Chem. Phys. 40, 1614 (1964)

    Article  CAS  Google Scholar 

  62. Kurata, M., Fukatsu, M.: J. Chem. Phys. 41, 2934 (1964)

    Article  CAS  Google Scholar 

  63. Osaki, K., Mitsuda, Y., Johnson, R. M., Schrag, J. L., Ferry, J. D.: Macromolecules 5, 17 (1972)

    Article  CAS  Google Scholar 

  64. Mitsuda, Y., Osaki, K., Schrag, J. L., Ferry, J. D.: Polym. J. 4, 24 (1973)

    Article  CAS  Google Scholar 

  65. Roovers, J. E. L.: unpublished

    Google Scholar 

  66. Berry, G. C.: J. Chem. Phys. 44, 4550 (1966)

    Article  CAS  Google Scholar 

  67. Yamakawa, H.: Modern theory of polymer solutions. New York: Harper and Row 1971

    Google Scholar 

  68. Grubisic, Z., Rempp, P., Benoit, H.: J. Polym. Sci. (Part B) 5, 753 (1967)

    Article  Google Scholar 

  69. Benoit, H., Grubisic, Z., Rempp, P., Decker, D., Zilliox, J.-G.: J. Chim. Phys. 63, 1507 (1966)

    CAS  Google Scholar 

  70. Casassa, E. F., Tagami, Y.: Macromolecules 2, 14 (1969)

    Article  CAS  Google Scholar 

  71. Roovers, J. E. L., Hadjichristidis, N.: unpublished

    Google Scholar 

  72. Pannell, J.: Polymer 13, 277 (1972)

    Article  CAS  Google Scholar 

  73. Kato, T., Itsubo, A., Yamamoto, Y., Fujimoto, T., Nagasawa, M.: Polym. J. 7, 123 (1975)

    Article  CAS  Google Scholar 

  74. Utracki, L. A., Roovers, J. E. L.: Macromolecules 6, 366 (1973)

    Article  CAS  Google Scholar 

  75. Graessley, W. W., Masuda, T., Roovers, J. E. L., Hadjichristidis, N.: Macromolecules 9, 127 (1976)

    Article  CAS  Google Scholar 

  76. Kraus, G., Gruver, J. T.: J. Polym. Sci. (Part A) 3, 105 (1965)

    CAS  Google Scholar 

  77. Kraus, G., Gruver, J. T.: J. Polym. Sci. (Part A 2) 8, 305 (1970)

    Article  CAS  Google Scholar 

  78. Graessley, W. W.: Adv. Polymer Sci. 16, 1 (1974)

    Google Scholar 

  79. de Gennes, P.: J. Chem. Phys. 55, 572 (1971)

    Article  Google Scholar 

  80. Masuda, T., Ohta, Y., Onogi, S.: Macromolecules 4, 763 (1971)

    Article  CAS  Google Scholar 

  81. Graessley, W. W.: Accounts Chem. Res. 10, 332 (1977)

    Article  CAS  Google Scholar 

  82. Ferry, J. D.: Viscoelastic properties of polymers. (2nd edit.). New York: Wiley 1970

    Google Scholar 

  83. Utracki, L. A., Roovers, J. E. L.: Macromolecules 6, 373 (1973)

    Article  CAS  Google Scholar 

  84. Roovers, J. E. L., Toporowski, P. M.: J. Appl. Polym. Sci. 18, 1685 (1974)

    Article  CAS  Google Scholar 

  85. Meares, P.: Trans. Faraday Soc. 53, 31 (1957)

    Article  CAS  Google Scholar 

  86. Fox, T. G., Flory, P. J.: J. Appl. Phys. 21, 581 (1950)

    Article  CAS  Google Scholar 

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Bywater, S. (1979). Preparation and properties of star-branched polymers. In: Physical Chemistry. Advances in Polymer Science, vol 30. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-09199-8_2

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  • DOI: https://doi.org/10.1007/3-540-09199-8_2

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-09199-8

  • Online ISBN: 978-3-540-35395-9

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