Abstract
The methods available for the preparation of star-branched polymers are described. After presentation of theoretical predictions of the effect of this type of branching on the properties of polymers, available experimental data are compared and critically discussed. Thermodynamic and visco-elastic properties at infinite dilution are first presented followed by visco-elastic properties in concentrated solution and the melt. Finally the effect of star-branching on T g of low molecular weight polymers is described.
Preview
Unable to display preview. Download preview PDF.
6 References
Schaefgren, J. R., Flory, P. J.: J. Am. Chem. Soc. 70, 2709 (1948)
Pfannemüller, B., Burchard, W.: Makromol. Chem. 121, 1 (1969)
Burchard, W., Eschwey, A., Franken, I., Pfannemüller, B.: Structure of fibrous biopolymers. Colston Papers 26, 365 (1974)
Pfannenmüller, B. Burchard, W., Franken, I.: Stärke 28, 1 (1976)
Swarc, M.: Carbanions, living polymers and electron transfer processes. New York: Interscience 1968
Bywater, S.: Progr. Polym. Sci. 4, 27 (1974)
Bywater, S.: Comprehensive chemical kinetics. Amsterdam: Elsevier 15, 1 (1976)
Morton, M., Helminiak, T. E., Gadkary, S. D., Bueche, F.: J. Polym. Sci. 57, 471 (1962)
Wenger, F., Yen, S.-P. S.: Polymer Reprints A.C.S. 3 (1) 162 (1962)
Altares, T., Wyman, D. P., Allen, V. R., Meyerson, K.: J. Polym. Sci. (Part A) 3, 4131 (1965)
Meunier, J.-C., van Leemput, R.: Makromol. Chem. 142, 1 (1971)
Gervasi, J. A., Gosnell, A. B.: J. Polym. Sci. (Part A1) 4, 1391 (1966)
Zelinsky, R. P., Wofford, C. F.: J. Polym. Sci. (Part A) 3, 93 (1965)
Hsieh, H. L.: Rubber Chem. Tech. 49, 1307 (1976)
Roovers, J. E. L., Bywater, S.: Macromolecules 5, 384 (1972)
Herz, J., Strazielle, C.: C. R. Acad. Sci. 272, 747 (1971)
Herz, J., Hert, M., Strazielle, C.: Makromol. Chem. 160, 213 (1972)
Hert, M., Strazielle, C., Herz, J.: C. R. Acad. Sci. C276, 395 (1973)
Bryce, W. A. J., McGibbon, G., Meldrum, J. G.: Polymer 11, 394 (1970)
Decker, D., Rempp, P.: C. R. Acad. Sci. 261, 1977 (1965)
Zilliox, J.-G., Decker, D., Rempp, P.: C. R. Acad. Sci. 262, 726 (1966)
Zilliox, J.-G., Rempp, P., Parrod, J.: J. Polym. Sci. (Part C) 22, 145 (1968)
Worsfold, D. J., Zilliox, J.-G., Rempp, P.: Can. J. Chem. 47, 3379 (1969)
Worsfold, D. J.: Macromolecules 3, 514 (1970)
Eschwey, H., Burchard, W.: Polymer 16, 180 (1975)
Kohler, A., Zilliox, J.-G., Rempp, P.: Eur. Polym. J. 8, 627 (1972)
Eschwey, H., Hallensleben, M. L., Burchard, W.: Makromol. Chem. 173, 235 (1973)
Bi, L.-K., Fetters, L. J.: Macromolecules 9, 732 (1976)
Flory, P. J.: Principles of polymer chemistry. Ithaca: Cornell U. Press, 1953.
Zimm, B. H., Stockmayer, W. H.: J. Chem. Phys. 17, 1301 (1949)
Burchard, W.: Macromolecules 7, 835, 840 (1974)
Burchard, W.: Macromolecules 10, 919 (1977)
Burchard, W.: British Polym. J. 9, 103 (1977)
Benoit, H.: J. Polym. Sci. 11, 507 (1953)
Stockmayer, W. H., Fixman, M.: Ann. N. Y. Acad. Sci. 57, 334 (1953)
Å olc, K.: Macromolecules 6, 378 (1973)
Thurmond, C. D., Zimm, B. H.: J. Polym. Sci. 8, 477 (1952)
Rouse, P. E.: J. Chem. Phys. 21, 1272 (1953)
Zimm, B. H.: J. Chem. Phys. 24, 269 (1956)
Zimm, B. H., Kilb, R. W.: J. Polym. Sci. 37, 19 (1959)
Ham, J. S.: J. Chem. Phys. 26, 625 (1957)
Osaki, K., Schrag, J. L.: J. Polym. Sci. (Phys. Ed.) 11, 549 (1973)
Osaki, K.: Adv. Polymer Sci. 12, 1 (1973)
Bueche, F.: J. Chem. Phys. 20, 1959 (1952)
Bueche, F.: J. Chem. Phys. 20, 599 (1952)
Berry, G. C., Fox, T. G.: Adv. Polymer Sci. 5, 261 (1968)
Bueche, F.: J. Chem. Phys. 40, 484 (1964)
Orofino, T. A., Wenger, F.: J. Phys. Chem. 67, 566 (1963)
Roovers, J. E. L., Bywater, S.: Macromolecules 7, 443 (1974)
Berry, G. C.: J. Polym. Sci. (Part A2) 9, 687 (1971)
Strazielle, C., Herz, J.: Eur. Polym. J. 13, 223 (1977)
Meunier, J.-C., van Leemput, R.: Makromol. Chem. 147, 191 (1971)
Zilliox, J.-G.: Makromol. Chem. 156, 121 (1972)
Hadjichristidis, N., Roovers, J. E. L.: J. Polym. Sci. (Phys. Ed.) 12, 2521 (1974)
Candau, F., Rempp, P., Benoit, H.: Macromolecules 5, 627 (1972)
Mazur, J., McCrackin, F.: Macromolecules 10, 326 (1977)
Toporowski, P. M., Roovers, J. E. L.: Macromolecules 11, 365 (1978)
Orofino, T. A., Flory, P. J.: J. Chem. Phys. 26, 1067 (1957)
Candau, F., Strazielle, C., Benoit, H.: Makromol. Chem. 170, 165 (1973)
Stockmayer, W. H.: J. Polym. Sci. 15, 595 (1955)
Berry, C. G., Orofino, T. A.: J. Chem. Phys. 40, 1614 (1964)
Kurata, M., Fukatsu, M.: J. Chem. Phys. 41, 2934 (1964)
Osaki, K., Mitsuda, Y., Johnson, R. M., Schrag, J. L., Ferry, J. D.: Macromolecules 5, 17 (1972)
Mitsuda, Y., Osaki, K., Schrag, J. L., Ferry, J. D.: Polym. J. 4, 24 (1973)
Roovers, J. E. L.: unpublished
Berry, G. C.: J. Chem. Phys. 44, 4550 (1966)
Yamakawa, H.: Modern theory of polymer solutions. New York: Harper and Row 1971
Grubisic, Z., Rempp, P., Benoit, H.: J. Polym. Sci. (Part B) 5, 753 (1967)
Benoit, H., Grubisic, Z., Rempp, P., Decker, D., Zilliox, J.-G.: J. Chim. Phys. 63, 1507 (1966)
Casassa, E. F., Tagami, Y.: Macromolecules 2, 14 (1969)
Roovers, J. E. L., Hadjichristidis, N.: unpublished
Pannell, J.: Polymer 13, 277 (1972)
Kato, T., Itsubo, A., Yamamoto, Y., Fujimoto, T., Nagasawa, M.: Polym. J. 7, 123 (1975)
Utracki, L. A., Roovers, J. E. L.: Macromolecules 6, 366 (1973)
Graessley, W. W., Masuda, T., Roovers, J. E. L., Hadjichristidis, N.: Macromolecules 9, 127 (1976)
Kraus, G., Gruver, J. T.: J. Polym. Sci. (Part A) 3, 105 (1965)
Kraus, G., Gruver, J. T.: J. Polym. Sci. (Part A 2) 8, 305 (1970)
Graessley, W. W.: Adv. Polymer Sci. 16, 1 (1974)
de Gennes, P.: J. Chem. Phys. 55, 572 (1971)
Masuda, T., Ohta, Y., Onogi, S.: Macromolecules 4, 763 (1971)
Graessley, W. W.: Accounts Chem. Res. 10, 332 (1977)
Ferry, J. D.: Viscoelastic properties of polymers. (2nd edit.). New York: Wiley 1970
Utracki, L. A., Roovers, J. E. L.: Macromolecules 6, 373 (1973)
Roovers, J. E. L., Toporowski, P. M.: J. Appl. Polym. Sci. 18, 1685 (1974)
Meares, P.: Trans. Faraday Soc. 53, 31 (1957)
Fox, T. G., Flory, P. J.: J. Appl. Phys. 21, 581 (1950)
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 1979 Springer-Verlag
About this paper
Cite this paper
Bywater, S. (1979). Preparation and properties of star-branched polymers. In: Physical Chemistry. Advances in Polymer Science, vol 30. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-09199-8_2
Download citation
DOI: https://doi.org/10.1007/3-540-09199-8_2
Received:
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-09199-8
Online ISBN: 978-3-540-35395-9
eBook Packages: Springer Book Archive