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Nitroxide-Mediated Polymerization from Surfaces

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Controlled Radical Polymerization at and from Solid Surfaces

Part of the book series: Advances in Polymer Science ((POLYMER,volume 270))

Abstract

The current chapter gives a general overview on surface-initiated nitroxide-mediated polymerization (SI-NMP). More particularly, the developed strategies to perform an SI-NMP process, the various type of substrates including inorganic and organic supports, and the potential of SI-NMP to prepared advanced materials are discussed. Based on a selected number of literature examples it appears that SI-NMP is a versatile and powerful approach to introduce polymer brushes on surfaces and/or tune polymer surface properties.

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Abbreviations

3-MPS:

3-Methacryloxyproyltrimethoxysilane

AFM:

Atomic force microscopy

AIBN:

Azobisisobutyronitrile

APTES:

3-Aminopropryl triethoxysilane

ATRP:

Atom transfer radical polymerization

BlocBuilder MA:

2-Methyl-2-[N-tert-butyl-N-(1-diethoxyphosphoryl-2,2-dimethylpropyl)aminoxy]propionic acid

BPO:

Benzoyl peroxide

CNT:

Carbon nanotube

DLS:

Dynamic light scattering

DMAc:

Dimethylacetamide

DMF:

N,N-Dimethylformamide

DPPC:

l-Adipalmytoyl-phosphatidylcholine

HEMA:

2-Hydroxyethyl methacrylate

LB:

Langmuir–Blodgett

MAMA-NHS:

2-Methyl-2-[N-tert-butyl-N-(1-diethoxyphosphoryl-2,2-dimethylpropyl)aminoxy]-N-propionyloxysuccinimide

MMA:

Methyl methacrylate

MMT:

Montmorillonite

MWNT:

Multiwalled carbon nanotube

NEXAFS:

Near-edge X-ray absorption fine structure

NMP:

Nitroxide-mediated polymerization

OMS:

Ordered mesoporous silica

P3VP:

Poly(3-vinylpyridine)

P4VP:

Poly(4-vinylpyridine)

PAA:

Poly(acrylic acid)

PBA:

Poly(n-butyl acrylate)

PtBA:

Poly(tert-butyl acrylate)

PDMAEA:

Poly(2-dimethylamino ethyl acrylate)

PHPMA:

Poly(2-hydroxypropyl methacrylamide)

PNIPAM:

Poly(N-isopropylacrylamide)

PPTEA:

Poly[2-phenyl-2-(2,2,6,6-tetramethylpiperidin-1-yloxy)ethyl acrylate]

PS:

Polystyrene

PS-b-PCL:

Polystyrene-block-polycaprolactone

PSMA:

Poly[styrene-co-(maleic anhydride)]

RAFT:

Reversible–addition fragmentation chain transfer

SANS:

Small-angle neutron scattering

SAXS:

Small-angle X-ray scattering

SG1:

N-tert-Butyl-N-[1-diethylphosphono-(2-2-dimethylpropyl) nitroxide]

SI-NMP:

Surface-initiated nitroxide-mediated polymerization

SWNT:

Single-walled carbon nanotube

TEM:

Transmission electron microscopy

TEMPO:

2,2,6,6-Tetramethylpiperidinyl-1-oxy

TEMPO-Br:

1-Oxo-2,2,6,6-tetramethylpiperidinium bromide

TIPNO:

2,2,5-Trimethyl-4-phenyl-3-azahexane-3-oxyl

TSPMA:

3-(Trimethoxysilyl)propyl methacrylate

VBC:

4-Vinylbenzyl chloride

XPS:

X-ray photoelectron spectroscopy

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Authors and Affiliations

  1. CNRS, Institut de Chimie Radicalaire, UMR7273, Aix-Marseille Université, 13397, Marseille cedex 20, France

    Trang N. T. Phan & Didier Gigmes

  2. Laboratoire Léon Brillouin, CEA Saclay, 91191, Gif-sur-Yvette Cedex, France

    Jacques Jestin

Authors
  1. Trang N. T. Phan
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  2. Jacques Jestin
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  3. Didier Gigmes
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Corresponding author

Correspondence to Didier Gigmes .

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Editors and Affiliations

  1. Makromolekulare Chemie, Georg-August-Universität Institut für Physikalische Chemie, Göttingen, Germany

    Philipp Vana

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Phan, T.N.T., Jestin, J., Gigmes, D. (2015). Nitroxide-Mediated Polymerization from Surfaces. In: Vana, P. (eds) Controlled Radical Polymerization at and from Solid Surfaces. Advances in Polymer Science, vol 270. Springer, Cham. https://doi.org/10.1007/12_2015_317

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