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Reversible Addition-Fragmentation Chain Transfer Polymerization from Surfaces

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Controlled Radical Polymerization at and from Solid Surfaces

Part of the book series: Advances in Polymer Science ((POLYMER,volume 270))

Abstract

Reversible addition–fragmentation chain transfer (RAFT) polymerization-based surface modification has emerged as a powerful tool for preparation of well-defined polymers grafted solid substrates. Combination of the RAFT process with highly efficient ligation reactions involving click chemistry can further extend its application in controlled synthesis of functional hybrid and composite materials. This review highlights some basic features of this method and describes synthesis of polymer-grafted solid surfaces such as silica particles, metal oxide, gold nanoparticles, cellulose, and graphene oxide. Applications of such functional materials, including their use in functional additives, bioactive surfaces and biomaterials, stationary phases for chromatographic applications, and preparation of hollow capsules and molecularly imprinted polymer films, are also summarized.

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Acknowledgment

Y.Z. acknowledges the financial support from the National Natural Science Foundation of China (Grants 20844001, 20874067 and 21074081) and the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions. S.P. acknowledges the Royal Society Wolfson Merit Award (WM130055) and the Monash-Warwick Alliance for financial support.

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Authors and Affiliations

  1. Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, China

    Youliang Zhao

  2. Department of Chemistry, The University of Warwick, Gibbet Hill, Coventry, CV4 7AL, UK

    Sébastien Perrier

  3. Faculty of Pharmacy and Pharmaceutical Sciences, Monash University, 381 Royal Parade, Parkville, VIC, 3052, Australia

    Sébastien Perrier

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  1. Youliang Zhao
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  2. Sébastien Perrier
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Correspondence to Youliang Zhao .

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Editors and Affiliations

  1. Makromolekulare Chemie, Georg-August-Universität Institut für Physikalische Chemie, Göttingen, Germany

    Philipp Vana

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Zhao, Y., Perrier, S. (2015). Reversible Addition-Fragmentation Chain Transfer Polymerization from Surfaces. In: Vana, P. (eds) Controlled Radical Polymerization at and from Solid Surfaces. Advances in Polymer Science, vol 270. Springer, Cham. https://doi.org/10.1007/12_2015_316

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