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Post-polymerization Modification of Surface-Bound Polymers

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Controlled Radical Polymerization at and from Solid Surfaces

Part of the book series: Advances in Polymer Science ((POLYMER,volume 270))

Abstract

Surfaces that have been intricately functionalized with reactive polymers have attracted scientific attention recently because of their potential use in a broad range of applications. Polymers containing chemically reactive functional groups can be utilized for subsequent modification of various surfaces. Reactive polymeric surfaces can be produced by surface-initiated polymerization, such as atom transfer radical polymerization, nitroxide-mediated polymerization, and ring-opening metathesis polymerization. Such surfaces can subsequently undergo post-polymerization modification to alter their physicochemical properties. Post-polymerization modification has a number of advantages, including the fact that diverse polymer structures are rapidly accessible without individual synthesis; polymerization of new functional monomers can produce a variety of surfaces and interfaces; and other materials can be easily modified, which would be difficult using conventional direct polymerization. In addition, the libraries of chemical reactions and materials that can be used in post-polymerization modifications are abundant. Therefore, post-polymerization modification opens up new platforms for the facile and versatile modification of various surfaces. This chapter focuses on a discussion of post-polymerization modification of various surface-bound polymers, from planar surfaces to three-dimensional objects, and on the extended applications of the reactive surfaces.

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  1. Institute for Technical and Macromolecular Chemistry, University of Hamburg, Bundesstrasse 45, 20146, Hamburg, Germany

    Hanju Jo & Patrick Theato

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    Philipp Vana

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Jo, H., Theato, P. (2015). Post-polymerization Modification of Surface-Bound Polymers. In: Vana, P. (eds) Controlled Radical Polymerization at and from Solid Surfaces. Advances in Polymer Science, vol 270. Springer, Cham. https://doi.org/10.1007/12_2015_315

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