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Nanocomposites and Self-Assembled Structures via Controlled Radical Polymerization

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Controlled Radical Polymerization at and from Solid Surfaces

Part of the book series: Advances in Polymer Science ((POLYMER,volume 270))

Abstract

We report recent findings on the formation of nanocomposites and self-assembled hybrid nanoarchitectures, in which controlled radical polymerization plays a key role. Specifically, we address how macromolecular design via these controlled methods can be used to flexibly guide the formation of hybrid nanoarchitectures in a rational and predetermined fashion. To this end, the role of polymeric architecture in tuning polymer/inorganic nanocomposite structures is examined.

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Abbreviations

AFM:

Atomic force microscopy

AgNP:

Silver nanoparticle

ATRP:

Atom-transfer radical polymerization

AuNP:

Gold nanoparticle

CPB:

Concentrated polymer brush

DC:

Daoud−Cotton

DEGEMA:

Diethyleneglycol ethylmethacrylate

DEGMMA:

Diethylenegylcol methylmethacrylate

DLS:

Dynamic light scattering

DMAEMA:

N,N-Diemthylaminoethyl methacrylate

DMF:

N,N-Dimethylformamide

DMSO:

Dimethylsulfoxide

GMA:

Glycidyl methacrylate

HBP:

Hyperbranched polymer

IONP:

Iron oxide nanoparticle

LAMP:

Lipoic acid 2-hydroxy-3-(methacryloyloxy)-propyl ester

LCST:

Lower critical solution temperature

MPC:

2-(Methacryloyloxy)ethyl phosphorylcholine

NMR:

Nuclear magnetic resonance

NMRP:

Nitroxide-mediated radical polymerization

NP:

Nanoparticle

PDMAEMA:

Poly(N,N-diemthylaminoethyl methacrylate)

PdNP:

Palladium nanoparticle

PEG:

Poly(ethylene glycol)

PEO:

Poly(ethylene oxide)

PGMA:

Poly(glycidyl methacrylate)

PMAA:

Poly(methacrylic acid)

PMMA:

Poly(methyl methacrylate)

PMPC:

Poly(2-(methacryloyloxy)ethyl phosphorylcholine)

PNiPAAM:

Poly(N-isopropylacrylamide)

POEGMA:

Poly(oligo(ethylene glycol) methacrylate)

PS:

Polystyrene

PVP:

Poly(vinylpyridine)

RAFT:

Reversible addition−fragmentation chain transfer

RDRP:

Reversible-deactivation radical polymerization

SAXS:

Small-angle X-ray scattering

SDPB:

Semidilute polymer brush

SEC:

Size-exclusion chromatography

SI:

Surface-initiated

SiNP:

Silica nanoparticle

stat :

Statistical

TEM:

Transmission electron microscopy

THF:

Tetrahydrofuran

TTC:

Trithiocarbonate

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Authors and Affiliations

  1. Institut für Physikalische Chemie, Georg-August-Universität Göttingen, Tammannstrasse 6, 37077, Göttingen, Germany

    Christian Rossner & Philipp Vana

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  1. Christian Rossner
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  2. Philipp Vana
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Correspondence to Philipp Vana .

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  1. Makromolekulare Chemie, Georg-August-Universität Institut für Physikalische Chemie, Göttingen, Germany

    Philipp Vana

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Rossner, C., Vana, P. (2015). Nanocomposites and Self-Assembled Structures via Controlled Radical Polymerization. In: Vana, P. (eds) Controlled Radical Polymerization at and from Solid Surfaces. Advances in Polymer Science, vol 270. Springer, Cham. https://doi.org/10.1007/12_2015_314

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