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Sequential Post-modifications of Polybutadiene for Industrial Applications

  • Jan-Philipp Dilcher
  • Hannes Jürgens
  • Gerrit A. LuinstraEmail author
Chapter
Part of the Advances in Polymer Science book series (POLYMER, volume 269)

Abstract

Polybutadiene is a versatile starting material for polymer-analogous reactions because of the high content of easily accessed double bonds. It is a large scale polymeric product with relatively low costs. Polybutadiene may be tuned in its properties by consecutive chemical functionalizations to expand its range of applications. The polarity decreases content double bond hydrogenation and may be increased by the addition of heteroatoms to the olefinic entities. The functionalized of double bonds (e.g. to epoxides, aldehydes, carboxylates, hydroxyls or amines) opens the option of subsequent reactions in particular with nucleophilic reagents. This article focuses on post-modifications of polybutadiene homo-polymers by such sequential reactions and shows their relevance to applications.

Keywords

Epoxide Hydrogenation Multi-step functionalization Oxidation Polybutadiene Polymer-analogous reactions Post-modification Subsequent reactions 

Notes

Acknowledgments

Research on polybutadiene functionalization at the University of Hamburg was supported by LEXI “Key Technologies for Sustainable Energy Systems in Smart Grids”.

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Copyright information

© Springer International Publishing Switzerland 2015

Authors and Affiliations

  • Jan-Philipp Dilcher
    • 1
  • Hannes Jürgens
    • 1
  • Gerrit A. Luinstra
    • 1
    Email author
  1. 1.Institute for Technical and Macromolecular ChemistryUniversity of HamburgHamburgGermany

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