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Multi-Component and Sequential Reactions in Polymer Synthesis pp 1–15Cite as

Metal-Catalyzed Multicomponent Reactions for the Synthesis of Polymers

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Part of the book series: Advances in Polymer Science ((POLYMER,volume 269))

Abstract

Despite the chemical complexity of multicomponent reactions (MCRs), the dawn of MCRs was fairly early in the history of organic chemistry. After lagging behind successful utilization of MCRs in combinatorial chemistry, the integration of MCRs with polymer chemistry has very recently started, which offers new possibilities in polymer synthesis. In spite of a large number of MCRs available for organic transformation reactions, this chapter describes metal-catalyzed MCRs in the area of polymer chemistry.

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Abbreviations

A3-coupling:

Metal-catalyzed three-component reactions between alkynes, amines, and aldehydes

CuAAC:

Cu(I)-catalyzed cycloaddition reaction between terminal alkynes and azides

CuMCR:

Cu(I)-catalyzed multicomponent reaction between terminal alkynes, sulfonyl azides, and nucleophiles

CuSeq:

Sequential Cu(I)-catalyzed cycloaddition reaction between alkynes and azides and metal-catalyzed cross-coupling reaction of triazole derivatives

IMCR:

Isocyanide-based multicomponent reaction

MC-MCR:

Metal-catalyzed multicomponent reaction

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Authors and Affiliations

  1. Faculty of Natural System, Institute of Science and Engineering, Kanazawa University, Kakuma-machi, Kanazawa, 920-1192, Japan

    Ryohei Kakuchi

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  1. Ryohei Kakuchi
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Correspondence to Ryohei Kakuchi .

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Editors and Affiliations

  1. Institute for Technical and Macromolecular Chemistry, University of Hamburg, Hamburg, Germany

    Patrick Theato

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Kakuchi, R. (2014). Metal-Catalyzed Multicomponent Reactions for the Synthesis of Polymers. In: Theato, P. (eds) Multi-Component and Sequential Reactions in Polymer Synthesis. Advances in Polymer Science, vol 269. Springer, Cham. https://doi.org/10.1007/12_2014_300

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