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Fabrication of Metal Oxide–Polymer Hybrid Nanocomposites

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Organic-Inorganic Hybrid Nanomaterials

Part of the book series: Advances in Polymer Science ((POLYMER,volume 267))

Abstract

The synthesis of polymer/metal oxide hybrid nanocomposites has attracted increasing attention because of their potential applications. The advances in polymer science have provided the ability to prepare a wide range of materials with controllable mechanical, thermal, and electroactive properties. As part of this renewed interest in nanocomposites, many researchers have begun seeking new strategies for engineering nanocomposite materials that combine the desirable properties of nanoparticles (NPs) with those of polymers. Previous research has revealed a number of key challenges in producing nanocomposites with the desired behavior. The greatest hindrance to the large-scale production and commercialization of nanocomposites is the lack of cost-effective methods for controlling the dispersion of NPs in their polymeric hosts. Nanoscale particles typically aggregate, which negates any benefit associated with their small dimensions. The particles must be integrated in such a way that isolated, well-dispersed primary NPs are found inside the matrix. Processing techniques are needed that are effective on the nanoscale yet applicable to macroscopic processing. Synthetic strategies for nanocomposites with high homogeneity are a challenge. Several attempts have been made to synthesize nanocomposites and they can be classified under two major categories: ex-situ and in-situ processes. This review discusses both ex-situ and in-situ methods with appropriate examples.

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Acknowledgement

This study was supported by DG Economic Circle Leading Industry R&D Program of the Ministry of Knowledge and Economy (MOKE) (R0001657)

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Authors and Affiliations

  1. School of Chemical Engineering, Yeungnam University, Gyeongsan, Gyeoungbuk, 712-749, Republic of Korea

    Yuvaraj Haldorai & Jae-Jin Shim

  2. Department of Energy and Materials Engineering, Dongguk University-Seoul, Seoul, Republic of Korea

    Yuvaraj Haldorai

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  1. Yuvaraj Haldorai
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  2. Jae-Jin Shim
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Correspondence to Yuvaraj Haldorai .

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Editors and Affiliations

  1. Department of Chemistry, Bahra University, Waknaghat, Himachal Pradesh, India

    Susheel Kalia

  2. School of Chemical Engineering, Yeungnam University, Gyeongbuk, Korea, Republic of (South Korea)

    Yuvaraj Haldorai

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Haldorai, Y., Shim, JJ. (2014). Fabrication of Metal Oxide–Polymer Hybrid Nanocomposites. In: Kalia, S., Haldorai, Y. (eds) Organic-Inorganic Hybrid Nanomaterials. Advances in Polymer Science, vol 267. Springer, Cham. https://doi.org/10.1007/12_2014_285

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