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Abbreviations
- 15-Na:
-
Naphthoxazine
- APCI:
-
Atmospheric pressure chemical ionization
- ASAP:
-
Atmospheric solids analysis probe
- BPAEP:
-
Poly(bisphenyl acryloxyethyl phosphate)
- CD:
-
Cyclodextrin
- DATE:
-
Decanedioic acid bis-(2-thiophen-3-yl-ethyl)ester
- DESI:
-
Desorption electrospray ionization
- DIP-MS:
-
Direct insertion probe mass spectrometry
- DP-MS:
-
Direct pyrolysis mass spectrometry
- ESI:
-
Electrospray ionization
- FR:
-
Flame retardant
- IC:
-
Inclusion compound
- MALDI:
-
Matrix assisted laser desorption ionization
- OTE:
-
2-(Thiophen-3-yl-)ethyl octanoate
- P2VP:
-
Poly(2-vinylpyridine)
- P4VP:
-
Poly(4-vinylpyridine)
- PANI:
-
Polyaniline
- PC:
-
Poly(carbonate)
- PCL:
-
Poly(ε-caprolactone)
- PEO:
-
Poly(ethylene oxide)
- PET:
-
Polyethylene terephthalate
- PMMA:
-
Poly(methyl methacrylate)
- PMTh:
-
Poly(methyl thiophene)
- PPE:
-
Polyphenylene
- PPh:
-
Phenolphthalein
- PPP:
-
Poly(p-phenylene)
- PPy:
-
Polypyrrole
- PS:
-
Polystyrene
- PTh:
-
Polythiophene
- PVAc:
-
Poly(vinyl acetate)
- PVP:
-
Poly(vinylene phenylene)
- TATE:
-
Terephthalic acid bis-(2-thiophen-3-yl-ethyl)ester
- T di :
-
Initial decomposition temperature
- TIC:
-
Total ion current
References
Statheropoulos M, Georgakopoulos K, Montaudo G (1991) The interpretation of pyrolysis mass-spectra of polymers using a hybrid software system based on library searching with heuristics. J Anal Appl Pyrol 20:65
Statheropoulos M, Georgakopoulos K, Montaudo G (1991) A method for the interpretation of pyrolysis mass-spectra of polyamides. J Anal Appl Pyrol 23:15
Qian K, Killinger WE, Casey M (1996) Rapid polymer identification by in-source direct pyrolysis mass spectrometry and library searching techniques. Anal Chem 68:1019
Zhang S, Shin YS, Mayer R, Basile F (2007) On-probe pyrolysis desorption electrospray ionization (DESI) mass spectrometry for the analysis of non-volatile pyrolysis products. J Anal Appl Pyrol 80:353
Whitson SE, Erdodi G, Kennedy JP, Lattimer RP, Wesdemiotis C (2008) Direct probe-atmospheric pressure chemical ionization mass spectrometry of cross-linked copolymers and copolymer blends. Anal Chem 80:7778
Huang Z, Shi W (2006) Thermal behavior and degradation mechanism of poly(bisphenyl acryloxyethyl phosphate) as a UV curable flame-retardant oligomer. Polym Degrad Stab 91:1674
Huang NH, Zhang Q, Fan C, Wang JQ (2008) A mechanistic study of flame retardance of novel copolyester phosphorus containing linked pendant groups by TG/XPS/direct Py-MS. Chinese Chem Lett 19:350
Yurteri S, Cianga I, Degirmenci M, Yagci Y (2004) Synthesis and characterization of poly(p-phenylene)-graft-poly(epsilon-caprolactone) copolymers by combined ring-opening polymerization and cross-coupling processes. Polym Int 53:1219
Yurteri S, Cianga I, Demirel AL, Yagci Y (2005) New polyphenylene-g-polystyrene and polyphenylene-g-polystyrene/poly(epsilon-caprolactone) copolymers by combined controlled polymerization and cross-coupling processes. J Polym Sci A Polym Chem 43:879
Nur Y, Yurteri Y, Cianga I, Yagci Y, Hacaloglu J (2007) Thermal degradation of poly(p-phenylene-graft-epsilon-caprolactone) copolymer. Polym Degrad Stab 92:838
Nur Y, Yurteri Y, Cianga I, Yagci Y, Hacaloglu J (2007) Pyrolysis of polyphenylenes with PCL or/and PSt side chains. J Anal Appl Pyrol 80:453
Colak DG, Cianga I, Yagci Y, Cirpan A, Karasz FE (2007) Novel poly(phenylene vinylenes) with well-defined poly(epsilon-caprolactone) or polystyrene as lateral substituents: synthesis and characterization. Macromolecules 40:5301
Nur Y, Colak DE, Chianga I, Yagci Y, Hacaloglu J (2008) Pyrolysis of poly(phenylene vinylene)s with polycaprolactone side chains. Polym Degrad Stab 93:904
Nur Y, Colak DE, Chianga I, Yagci Y, Hacaloglu J (2008) Direct pyrolysis mass spectrometry studies on thermal degradation characteristics of poly(phenylene vinylene) with well-defined PSt side chains. J Therm Anal Calorim 94:157
Nur Y, Colak DE, Chianga I, Yagci Y, Hacaloglu J (2009) High temperature pyrolysis of poly(phenylene vinylene)s with poly(epsilon-caprolactone) or polystyrene side chains. J Therm Anal Calorim 98:527
Bullions TA, Wei M, Porbeni FE, Gerber MJ, Peet J, Balik M, White JL, Tonelli AE (2002) Reorganization of the structures, morphologies, and conformations of bulk polymers via coalescence from polymer-cyclodextrin inclusion compounds. J Polym Sci B Polym Phys 40(10):992
Rusa CC, Uyar T, Rusa M, Wang X, Hunt MA, Tonelli AE (2004) An intimate polycarbonate/poly(methyl methacrylate)/poly(vinyl acetate) ternary blend via coalescence from their common inclusion compound with gamma-cyclodextrin. J Polym Sci B Polym Phys 42(22):4182
Uyar T, Aslan E, Tonelli AE, Hacaloglu J (2006) Pyrolysis mass spectrometry analysis of poly(vinyl acetate), poly(methyl methacrylate) and their blend coalesced from inclusion compounds formed with gamma-cyclodextrin. Polym Degrad Stab 91:1
Uyar T, Oguz G, Tonelli AE, Hacaloglu J (2006) Thermal degradation processes of poly(carbonate) and poly(methyl methacrylate) in blends coalesced either from their common inclusion compound formed with gamma-cyclodextrin or precipitated from their common solution. Polym Degrad Stab 91:2471
Uyar T, Tonelli AE, Hacaloglu J (2006) Thermal degradation of polycarbonate, poly(vinyl acetate) and their blends. Polym Degrad Stab 91:2960
Uyar T, Rusa CC, Tonelli AE, Hacaloglu J (2007) Pyrolysis mass spectrometry analysis of polycarbonate/poly(methyl methacrylate)/poly(vinyl acetate) ternary blends. Polym Degrad Stab 92:32
Uyar T, El-Shafei A, Wang X, Hacaloglu J, Tonelli AE (2006) The solid channel structure inclusion complex formed between guest styrene and host gamma-cyclodextrin. Incl Phenom Macrocycl Chem 55:109
Elmaci A, Hacaloglu J (2009) Thermal degradation of poly(vinylpyridine)s. Polym Degrad Stab 94(4):738
Elmaci A, Hacaloglu J, Kayran C, Sakellariou G, Hadjichristidis N (2009) Thermal decomposition of polystyrene-b-poly(2-vinylpyridine) coordinated to co nanoparticles. Polym Degrad Stab 94:2023
Sundarrajan S, Srinivasan KSV (2006) Influence of structural factors on degradation product formation: primary pyrolysis products of poly(acyl sulfides) investigated by direct pyrolysis mass spectrometry. Polym Degrad Stab 91:975
Samperi F, Puglisi C, Ferreri T, Messina R, Cicala G, Recca A, Restuccia CL, Scamporrino A (2007) Thermal decomposition products of copoly(arylene ether sulfone)s characterized by direct pyrolysis mass spectrometry. Polym Degrad Stab 92:1304
Ramakrishnan L, Sivaprakasam K (2009) Synthesis, characterization, thermal degradation, and comparative chain dynamics studies of weak-link polysulfide polymers. J Polym Res 16:623
Whitson SE, Wesdemiotis C, Lattimer RP (2010) Characterization of polyurethane formulations by direct probe atmospheric pressure chemical ionization mass spectrometry. Rub Chem Tech 83:35
Patil AO, Heeger AJ, Wudl F (1988) Optical properties of conducting polymers. Chem Rev 88:183
Hughes M, Shaffer MSP, Renouf AC, Singh C, Chen GZ, Fray DJ, Windle AH (2002) Electrochemical capacitance of nanocomposite films formed by coating aligned arrays of carbon nanotubes with polypyrrole. Adv Mater 14:382
Jin S, Liu X, Zhang W, Lu Y, Xue G (2000) Electrochemical copolymerization of pyrrole and styrene. Macromolecules 33:4805
Gozet T, Onal AM, Hacaloglu J (2007) Investigation of the effect of dopant on characteristics of poly(3-methyl thiophene) via pyrolysis mass spectrometry. J Macromol Sci Pure Appl Chem 44:259
Hacaloglu J, Argin E, Kucukyavuz Z (2008) Characterization of polyaniline via pyrolysis mass spectrometry. J Appl Polym Sci 108:400
Papila O, Toppare L, Hacaloglu J (2006) Investigation of copolymers of thiophene-functionalized polystyrene with pyrrole by pyrolysis mass spectrometry. J Macromol Sci Pure Appl Chem 43:655
Levent A, Hacaloglu J, Toppare L (2008) Characterization of conducting copolymer of pyrrole via pyrolysis mass spectrometry. J Macromol Sci Pure Appl Chem 45:201
Aslan E, Hacaloglu J, Toppare L (2007) A pyrolysis mass spectrometry study of polythiophene copolymers. Polym Degrad Stab 92:822
Aslan E, Hacaloglu J, Toppare L (2008) Thermal analysis of a new thiophene derivative and its copolymer. J Therm Anal Calorim 92:839
Hacaloglu J, Tezal F, Kücükyavuz Z (2009) The characterization of polyaniline and polypyrrole composites bypyrolysis mass spectrometry. J Appl Polym Sci 133:3130
Allen DJ, Ishida H (2006) Physical and mechanical properties of flexible polybenzoxazine resins: effect of aliphatic diamine chain length. J Appl Polym Sci 101(5):2798
TakeichiT KT, Agag T (2008) High performance polybenzoxazines as a novel type of phenolic resin. Polym J 40:1121
Ghosh NN, Kiskan B, Yagci Y (2007) Polybenzoxazines – new high performance thermosetting resins: synthesis and properties. Prog Polym Sci 32:1344
Agag T (2006) Preparation and properties of some thermosets derived from allyl-functional naphthoxazines. J Appl Polym Sci 100:3769
Uyar T, Koyuncu Z, Ishida H, Hacaloglu J (2008) Polymerisation and degradation of an aromatic amine-based naphthoxazine. Polym Degrad Stab 93:2096
Fam SB, Uyar T, Ishida H, Hacaloglu J (2010) The use of pyrolysis mass spectrometry to investigate polymerization and degradation processes of methyl amine-based benzoxazine. Polym Test 29:520
Fam SB, Kiskan B, Aydogan B, Hacaloglu J, Yagcı Y (2011) Thermal degradation of polysiloxane and polyetherester containing benzoxazine moieties in the main chain. J Anal Appl Pyrol 90:155
Trimpin S, Wijerathne K, Mc Ewen CN (2009) Rapid methods of polymer and polymer additives identification: multi-sample solvent-free MALDI, pyrolysis at atmospheric pressure, and atmospheric solids analysis probe mass spectrometry. Anal Chim Acta 654:20
Greiner A, Wendorff JH (2007) Electrospinning: a fascinating method for the preparation of ultrathin fibres. Angew Chem Int Ed 46:5670
Li D, Xia Y (2004) Electrospinning of nanofibers: reinventing the wheel? Adv Mater 16:1151
Ren GL, Xu XH, Liu Q, Cheng J, Yuan XY, Wu LL, Wan YZ (2006) Electrospun poly(vinyl alcohol)/glucose oxidase biocomposite membranes for biosensor applications. React Funct Polym 66:1559
Teo WE, Ramakrishna S (2006) A review on electrospinning design and nanofibre assemblies. Nanotechnology 17:R89
Hedges AR (1998) Industrial applications of cyclodextrins. Chem Rev 98:2035
Uyar T, Hacaloglu J, Besenbacher F (2009) Electrospun polystyrene fibers containing high temperature stable volatile fragrance/flavor facilitated by cyclodextrin inclusion complexes. React Funct Polym 69:145
Uyar T, Havelund R, Hacaloglu J, Zhou X, Besenbacher F, Kingshott P (2009) The formation and characterization of cyclodextrin functionalized polystyrene nanofibers produced by electrospinning. Nanotechnology 20:125605
Uyar T, Nur Y, Hacaloglu J, Besenbacher F (2009) Electrospinning of functional poly(methyl methacrylate) nanofibers containing cyclodextrin-menthol inclusion complexes. Nanotechnology 20:125703
Uyar T, Hacaloglu J, Besenbacher F (2011) Electrospun polyethylene oxide (PEO) nanofibers containing cyclodextrin inclusion complex. J Nanosci Nanotechnol 11:3949–3958
Uyar T, Havelund R, Nur Y, Hacaloglu J, Besenbacher F, Kingshott P (2009) Molecular filters based on cyclodextrin functionalized electrospun fibers. J Membr Sci 333:129
Uyar T, Havelund R, Hacaloglu J, Besenbacher F, Kingshott P (2010) Functional electrospun polystyrene nanofibers incorporating alpha-, beta-, and gamma-cyclodextrins: comparison of molecular filter performance. ACS Nano 4:5121
Uyar T, Havelund R, Nur Y, Balan A, Hacaloglu J, Toppare L, Besenbacher F, Kingshott P (2010) Cyclodextrin functionalized poly(methyl methacrylate) (PMMA) electrospun nanofibers for organic vapors waste treatment. J Membr Sci 365:409
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Hacaloglu, J. (2011). Direct Insertion Probe Mass Spectrometry of Polymers. In: Hakkarainen, M. (eds) Mass Spectrometry of Polymers – New Techniques. Advances in Polymer Science, vol 248. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_2011_133
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DOI: https://doi.org/10.1007/12_2011_133
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