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Gas–Polymer Interactions: Key Thermodynamic Data and Thermophysical Properties

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Polymer Thermodynamics

Part of the book series: Advances in Polymer Science ((POLYMER,volume 238))

Abstract

Gas–polymer interactions play a pivotal role in the formation of different molecular organizations/reorganizations of polymeric structures. Such structural modifications can have a negative impact on the material properties and should be understood in order to prevent them or these modifications are of engineering interest and they should be purposely tailored and properly controlled. Two newly developed techniques, gas-sorption/solubility and scanning transitiometry, are shown to be well adapted to provide the necessary (key) data to better understand and monitor the polymeric modifications observed under the triple constraints of temperature, elevated pressure, and gas sorption. This article illustrates the major contribution of gas–polymer interactions in different interconnected applied and engineering fields of the petroleum industry, polymer science, and microelectronics.

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References

  1. Grolier JPE (2000) Polym Mater 1:7

    Google Scholar 

  2. Yamada T, Boyer SAE, Iyoda T, Yoshida H, Grolier JPE (2007) J Therm Anal Calorim 89:9

    Article  CAS  Google Scholar 

  3. Yamada T, Boyer SAE, Iyoda T, Yoshida H, Grolier JPE (2007) J Therm Anal Calorim 89:717

    Article  CAS  Google Scholar 

  4. Boyer SAE, Klopffer MH, Martin J, Grolier JPE (2007) J Appl Polym Sci 103:1706

    Article  CAS  Google Scholar 

  5. Kamiya Y, Hirose T, Mizogushi K, Naito Y (1986) J Polym Sci B Polym Phys 24:1525

    Article  CAS  Google Scholar 

  6. Wong B, Zhang Z, Handa YP (1998) J Polym Sci B Polym Phys 36:2025

    Article  CAS  Google Scholar 

  7. Chaudary BI, Johns AI (1998) J Cell Plast 34:312

    Google Scholar 

  8. Schnitzler JV, Eggers R (1998) In: Proceedings of the 5th meeting on supercritical fluids, Nice, France, vol 1, p 93

    Google Scholar 

  9. Miura KI, Otake K, Kurosawa S, Sako T, Sugeta T, Nakane T, Sato M, Tsuji T, Hiaki T, Hongo M (1988) Fluid Phase Equilib 144:181

    Article  Google Scholar 

  10. Wang NH, Takishima S, Matsuoka H (1994) Int Chem Eng 34:255

    Google Scholar 

  11. Briscoe BJ, Lo O, Wajs A, Dang P (1998) J Polym Sci B Polym Phys 36:243

    Article  Google Scholar 

  12. Koros WJ, Paul DR (1976) J Polym Sci Polym Phys 14:1903

    CAS  Google Scholar 

  13. Stern SA, Meringo AHD (1978) J Polym Sci Polym Phys 16:735

    CAS  Google Scholar 

  14. Sato Y, Iketani T, Takishima S, Masuoka H (2000) Polym Eng Sci 40:1369

    Article  CAS  Google Scholar 

  15. Sanchez IC, Rodgers PA (1990) Pure Appl Chem 62:2107

    Article  CAS  Google Scholar 

  16. Wissinger RG, Paulaitis ME (1987) J Polym Sci B Polym Phys 25:2497

    Article  CAS  Google Scholar 

  17. Sanchez IC, Lacombe RH (1976) J Phys Chem 80:2352

    Article  CAS  Google Scholar 

  18. Hilic S, Padua AAH, Grolier JPE (2000) Rev Sci Instrum 71:4236

    Article  CAS  Google Scholar 

  19. Hilic S, Boyer SAE, Padua AAH, Grolier JPE (2001) J Polym Sci B Polym Phys 39:2063

    Article  CAS  Google Scholar 

  20. Randzio SL (1985) Thermochim Acta 89:215

    Article  CAS  Google Scholar 

  21. Randzio SL, Eatough DJ, Lewis EA, Hansen LD (1988) J Chem Thermodyn 20:937

    Article  CAS  Google Scholar 

  22. Randzio SL (1991) Pure Appl Chem 63:1409

    Article  CAS  Google Scholar 

  23. Randzio SL, Grolier JPE, Quint JR (1994) Rev Sci Instrum 65:960

    Article  CAS  Google Scholar 

  24. Randzio SL, Grolier JPE, Zaslona J, Quint JR (1991) French Patent 91–09227, Polish Patent P-295285

    Google Scholar 

  25. Randzio SL, Grolier JPE (1997) French Patent 97–15521. http://www.transitiometry.com. Accessed 4 May 2010

  26. Randzio SL, Stachowiak Ch, Grolier JPE (2003) J Chem Thermodyn 35:639

    Article  CAS  Google Scholar 

  27. Dan F, Grolier JPE (2002) Setaram News 7:13

    Google Scholar 

  28. Dan F, Grolier JPE (2004) Spectrocalorimetric screening for complex process optimization. In: Letcher T (ed) Chemical thermodynamics for industry. Royal Society of Chemistry, Cambridge, p 88

    Chapter  Google Scholar 

  29. Grolier JPE, Dan F, Boyer SAE, Orlowska M, Randzio SL (2004) Int J Thermophys 25:297

    Article  CAS  Google Scholar 

  30. Grolier JPE, Dan F (2006) Thermochim Acta 450:47

    Article  CAS  Google Scholar 

  31. Grolier JPE, Dan F (2007) Advanced calorimetric techniques in polymer engineering, vol 259. In: Moritz HU, Pauer W (eds) Polymer reaction engineering, macromolecular symposia, p 371

    Google Scholar 

  32. Boyer SAE (2003) Ph.D. Thesis, Université Blaise Pascal, Clermont-Ferrand, France

    Google Scholar 

  33. Sanchez IC, Lacombe RH (1978) Macromolecules 11:1145

    Article  CAS  Google Scholar 

  34. Boudouris D, Constantinou L, Panayiotou C (2000) Fluid Phase Equilib 167:1

    Article  CAS  Google Scholar 

  35. Hariharan R, Freeman BD, Carbonell RG, Sarti GC (1993) J Appl Polym Sci 50:1781

    Article  CAS  Google Scholar 

  36. DeAngelis MG, Merkel TC, Bondar VI, Freeman BD, Doghieri F, Sarti GC (1999) J Polym Sci B Polym Phys 37:3011

    Article  CAS  Google Scholar 

  37. Koros WJ (1980) J Polym Sci Polym Phys 18:981

    CAS  Google Scholar 

  38. Michaels AS, Parkers RB (1959) J Polym Sci 41:53

    Article  CAS  Google Scholar 

  39. Michaels AS, Bixler HJ (1961) J Polym Sci 50:393

    Article  CAS  Google Scholar 

  40. Puleo AC, Paul DR, Wonk PK (1989) Polymer 30:1357

    Article  CAS  Google Scholar 

  41. Manfredi C, Nobile MAD, Mensitieri G, Guerra G, Rapacciuolio M (1997) J Polym Sci Polym Phys 35:133

    Article  CAS  Google Scholar 

  42. Guadagno L, Baldi P, Vittoria V, Guerra G (1998) Macromol Chem Phys 199:2671

    Article  CAS  Google Scholar 

  43. Aletiev A, Drioli E, Gokzhaev M, Golemme G, Ilinich O, Lapkin A, Volkov V, Yampolskii Y (1998) J Memb Sci 138:99

    Article  Google Scholar 

  44. Mogri Z, Paul DR (2001) Polymer 42:7781

    Article  CAS  Google Scholar 

  45. Boyer SAE, Randzio SL, Grolier JPE (2006) J Polym Sci B Polym Phys 44:185

    Article  CAS  Google Scholar 

  46. Boyer SAE, Grolier JPE (2005) Pure Appl Chem 77:593

    Article  CAS  Google Scholar 

  47. Ismail AF, Lorna W (2002) Sep Purif Technol 27:173

    Article  CAS  Google Scholar 

  48. Boyer SAE, Grolier JPE (2005) Polymer 46:3737

    Article  CAS  Google Scholar 

  49. Sato Y, Fujiwara K, Takikawa T, Sumarno, Takishima S, Masuoka H (1999) Fluid Phase Equilib 162:261

    Article  CAS  Google Scholar 

  50. Lorge O, Briscoe BJ, Dang P (1999) Polymer 40:2981

    Article  CAS  Google Scholar 

  51. Flaconnèche B, Martin J, Klopffer MH (2001) Oil Gas Sci Techn Rev IFP 56:261

    Article  Google Scholar 

  52. Bos A, Pünt IGM, Wessling M, Strathmann H (1999) J Memb Sci 155:67

    Article  CAS  Google Scholar 

  53. Hansen AR, Eckert CA (1991) J Chem Eng Data 36:252

    Article  CAS  Google Scholar 

  54. Ghosal K, Chern RT, Freeman BD, Savariar RJ (1995) J Polym Sci B Polym Phys 33:657

    Article  CAS  Google Scholar 

  55. Grolier JPE, Dan F (2004) Calorimetric measurements of thermophysical properties for industry. In: Letcher T (ed) Chemical thermodynamics for industry. Royal Society of Chemistry, Cambridge, p 144

    Chapter  Google Scholar 

  56. Randzio SL, Grolier JPE (1998) Anal Chem 70:2327

    Article  CAS  Google Scholar 

  57. Ehrlich P, Kurpen JJ (1963) J Polym Sci A 1:3217

    CAS  Google Scholar 

  58. Yoshida H, Wanatabe K, Wanatabe R, Iyoda T (2004) Trans Mater Res Soc Jpn 29:861

    CAS  Google Scholar 

  59. Boyer SAE, Grolier JPE, Pison L, Iwamoto C, Yoshida H, Iyoda T (2006) J Therm Anal Calorim 85:699

    Article  CAS  Google Scholar 

  60. Boyer S.A.E, Grolier JPE, Yoshida H, Iyoda T (2007) J Polym Sci B Polym Phys 45:1354

    Article  CAS  Google Scholar 

  61. Watanabe K, Tian Y, Yoshida H, Asaoka S, Iyoda T (2003) Trans Mater Res Sci Jpn 28:553

    CAS  Google Scholar 

  62. Tian Y, Watanabe K, Kong X, Abe J, Iyoda T (2002) Macromolecules 35:3739

    Article  CAS  Google Scholar 

  63. Mukherjee PK, Rzoska SJ (2002) Phys Rev E 65:051705

    Article  CAS  Google Scholar 

  64. Maeda Y, Niori T, Yamamoto J, Yokokawa H (2005) Thermochim Acta 57:428

    Google Scholar 

  65. Triolo R, Triolo A, Triolo F, Steytler DC, Lewis CA, Heenan RK, Wignall GD, DeSimone JM (2000) Phys Rev E 61:4640

    Article  CAS  Google Scholar 

  66. Kawabata Y, Nagao M, Seto H, Komura S, Takeda T, Schwahn D, Yamada NL, Nobutou H (2004) Phys Rev Lett 92:056103

    Article  CAS  Google Scholar 

  67. Seeger A, Freitag D, Freidel F, Luft G (2004) Thermochim Acta 424:175

    Article  CAS  Google Scholar 

  68. Ryu DY, Lee JL, Kim JK, Lavery KA, Russell TP, Han YS, Seon BS, Lee CH, Thiyagarajan P (2003) Phys Rev Lett 90:235501

    Article  CAS  Google Scholar 

  69. Pollard M, Russel TP, Ruzette AV, Mayes AM, Gallot Y (1998) Macromolecules 31:6493

    Article  CAS  Google Scholar 

  70. Hamley IW (1998) The physics of block copolymers. Oxford University Press, Oxford

    Google Scholar 

  71. Masten MW, Bates FS (1996) Macromlecules 29:1091

    Article  Google Scholar 

  72. Lazzari M, López Quintela MA (2003) Adv Mater 15:1583

    Article  CAS  Google Scholar 

  73. Younglove B, Ely JF (1987) J Phys Chem Ref Data 16:577

    CAS  Google Scholar 

  74. Ribeiro M, Pison L, Grolier JPE (2001) Polymer 42:1653

    Article  CAS  Google Scholar 

  75. Chow TS (1980) Macromolecules 13:362

    Article  CAS  Google Scholar 

  76. Gibbs JH, Di Marzio EA (1958) J Chem Phys 28:373

    Article  CAS  Google Scholar 

  77. Di Marzio EA, Gibbs JH (1963) J Polym Sci A 1:1417

    CAS  Google Scholar 

  78. O’Neill ML, Handa YP (1994) Plasticization of polystyrene by high pressure gases: a calorimetric study. In: Seyler RJ (ed) Assignment of the glass transition. ASTM, Philadelphia, p 165

    Chapter  Google Scholar 

  79. Chiou JS, Barkow JW, Paul DR (1985) J Appl Polym Sci 30:263

    Article  Google Scholar 

  80. Zhang Z, Handa YP (1998) J Polym Sci B Polym Phys 36:977

    Article  CAS  Google Scholar 

  81. Condo PD, Sanchez IC, Panayiotou CG, Johnston KP (1992) Macromolecules 25:6119

    Article  CAS  Google Scholar 

  82. Condo PD, Paul DR, Johnston KP (1994) Macromolecules 27:365

    Article  CAS  Google Scholar 

  83. Handa YP, Zhang Z (2000) J Polym Sci B Polym Phys 38:716

    Article  CAS  Google Scholar 

  84. Nawabi AV, Handa YP, Liao X, Yoshitaka Y, Tomohiro M (2007) Polym Int 56:67

    Article  CAS  Google Scholar 

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Author information

Authors and Affiliations

  1. Laboratoire de Thermodynamique des Solutions et des Polymères, Université Blaise Pascal de Clermont-Ferrand, 63177, Aubière, France

    Jean-Pierre E. Grolier

  2. Centre de Mise en Forme des Matériaux (CEMEF), Mines ParisTech, 06904, Sophia Antipolis, Valbonne, France

    Séverine A. E. Boyer

Authors
  1. Jean-Pierre E. Grolier
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  2. Séverine A. E. Boyer
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Corresponding author

Correspondence to Jean-Pierre E. Grolier .

Editor information

Editors and Affiliations

  1. Inst. Physikalische Chemie, Universität Mainz, Jakob-Welder-Weg 13, Mainz, 55099, Germany

    Bernhard A. Wolf

  2. Sekr. TK7, TU Berlin, Straße des 17. Juni 135, Berlin, 10623, Germany

    Sabine Enders

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Grolier, JP.E., Boyer, S.A.E. (2010). Gas–Polymer Interactions: Key Thermodynamic Data and Thermophysical Properties. In: Wolf, B., Enders, S. (eds) Polymer Thermodynamics. Advances in Polymer Science, vol 238. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_2010_83

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