Skip to main content

Historical Overview of (Mini)emulsion Polymerizations and Preparation of Hybrid Latex Particles

  • Chapter
  • First Online:
Book cover Hybrid Latex Particles

Part of the book series: Advances in Polymer Science ((POLYMER,volume 233))

Abstract

In this introductory chapter, a brief overview of emulsion polymerization and miniemulsion polymerization principles is given in relation to preparation of hybrid latex particles. An account is presented of the early history of preparation of hybrid latex particles with an emphasis on the hybrid lattices containing organic and inorganic material phases. The two approaches for obtaining encapsulated inorganic particles are discussed: the chemical method in which polymerization takes place in the presence of inorganic particles, and the physical method whereby latex particles are deposited on the surface of inorganic particles by heterocoagulation. A new classification scheme for the preparation of hybrid latex particles and corresponding higher-order nanostructures is given in this paper. This classification is partially based on a discussion during the International Polymer Colloids Group meeting in Italy in 2009.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 259.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Slomkowski S et al (2003) IUPAC terminology of polymerization processes and polymers in dispersed systems http://www.students.itu.edu.tr/$\sim$ surgun/IUPAC_polym_coll_ terminology.pdf

    Google Scholar 

  2. Bourgeat-Lami E (2002) J Nanosci Nanotechnol 2:1–24

    Article  CAS  Google Scholar 

  3. Polymer Colloids Group (2009) Polymer colloids – quo vadis? 1st international polymer colloids group conference, Lucca, Italy, 6–11 July 2009

    Google Scholar 

  4. Corey EJ (1967) Pure Appl Chem 14:19–37

    Article  CAS  Google Scholar 

  5. Caruso F, Möhwald H (1999) Langmuir 15:8276–8281

    Article  CAS  Google Scholar 

  6. Cronin L, Beugholt C, Krickemeyer E, Schmidtmann M, Bögge H, Kögerler P, Luong K, Müller A (2002) Angew Chem Int Ed 41:2805–2808

    Article  CAS  Google Scholar 

  7. Teixeira RFA, Bon SAF (2010) Physical methods for the preparation of hybrid nanocomposite polymer latex particles. Adv Polym Sci. doi:10.1007/12_2010_65

    Google Scholar 

  8. Hubert DHW, Jung M, Frederik PM, Bomans PHH, Meuldijk J, German AL (2000) Adv Mater 12:1286–1289

    Article  CAS  Google Scholar 

  9. Rahman MM, Elaissari A (2010) Organic–inorganic hybrid magnetic latex. Adv Polym Sci. doi:10.1007/12_2010_59

    Google Scholar 

  10. Guo JS, Sudol ED, Vanderhoff JW, El-Aasser MS (1992) In: Daniels ES, Sudol ED, El-Aasser MS (eds) ACS symposium series: polymer latexes – preparation, characterization and applications, vol 492. American Chemical Society, Washington, DC, p 99

    Chapter  Google Scholar 

  11. Tang H-I, Sudol ED, Adams ME, Silebi CA, El-Aasser MS (1992) In: Daniels ES, Sudol ED, El-Aasser MS (eds) ACS symposium series: polymer latexes – preparation, characterization and applications, vol 492. American Chemical Society, Washington, DC, p 72

    Chapter  Google Scholar 

  12. Lovell PA, El-Aasser MS (eds) (1996) Emulsion polymerization and emulsion polymers. Wiley, Chichester

    Google Scholar 

  13. Blackley DC (1997) Polymer latices, science and technology. Chapman & Hall, London

    Book  Google Scholar 

  14. Warson H, Finch CA (2001) Applications of synthetic resin latices. Wiley, Chichester

    Google Scholar 

  15. Urban D, Takamura A (2002) Polymer dispersions and their industrial applications. Wiley, Weinheim

    Book  Google Scholar 

  16. Gilbert RG (1995) Emulsion polymerization, a mechanistic approach. Academic, London

    Google Scholar 

  17. van Herk AM (2005) Chemistry and technology of emulsion polymerization. Blackwell, Oxford

    Book  Google Scholar 

  18. Harkins WD (1947) J Am Chem Soc 69:1428–1430

    Article  CAS  Google Scholar 

  19. Smith WV, Ewart RW (1948) J Chem Phys 16:592–596

    Article  CAS  Google Scholar 

  20. Goodall AR, Wilinson MC, Hearn JJ (1977) Polym Sci 15:2193–2198

    CAS  Google Scholar 

  21. Fitch RM, Tsai CH (1971) In: Fitch RM (ed) Polymer colloids. Plenum, New York, p 73

    Chapter  Google Scholar 

  22. Vandezande GA, Rudin A (1994) J Coat Technol 66:99–108

    CAS  Google Scholar 

  23. Lovell PA (1995) Macromol Symp 92:71–92

    Article  CAS  Google Scholar 

  24. Sundberg DC, Casassa AP, Pantazopoulos J, Muscato MR, Kronberg B, Berg J (1990) J Appl Polym Sci 41:1425–1442

    Article  CAS  Google Scholar 

  25. Chen YC, Dimonie VL, El-Aasser MS (1991) J Appl Polym Sci 42:1049–1063

    Article  CAS  Google Scholar 

  26. Chen YC, Dimonie VL, El-Aasser MS (1992) Pure Appl Chem 64:1691–1696

    Article  CAS  Google Scholar 

  27. Chern CS, Poehlein GW (1990) J Polym Sci Polym Chem Ed 28:3073–3099

    Article  CAS  Google Scholar 

  28. Mills MF, Gilbert RG, Napper DH (1990) Macromolecules 23:4247–4257

    Article  CAS  Google Scholar 

  29. Chen YC, Dimonie VL, Shaffer OL, El-Aasser MS (1993) Polym Int 30:185–189

    Article  CAS  Google Scholar 

  30. González-Ortiz LJ, Asua JM (1996) Macromolecules 28:3135–3145

    Article  Google Scholar 

  31. González-Ortiz LJ, Asua JM (1996) Macromolecules 29:383–389

    Article  Google Scholar 

  32. Maxwell IA, Morrison BR, Gilbert RG, Napper DH (1991) Macromolecules 24:1629–1640

    Article  CAS  Google Scholar 

  33. Weiss CK, Landfester K (2010) Miniemulsion polymerization as a means to encapsulate organic and inorganic materials. Adv Polym Sci. doi:10.1007/12_2010_61

    Google Scholar 

  34. Godard P, Wertz JL, Biebuyck JJ, Mercier JP (1989) Pol Eng Sci 29:127–133

    Article  CAS  Google Scholar 

  35. Kendall K (1978) Br Polym J 10:35–38

    Article  CAS  Google Scholar 

  36. Hawthorne DG, Hodgkin JH, Loft BC, Solomon DH (1974) J Macromol Sci Chem A8:649–657

    Google Scholar 

  37. Dekkers MEJ, Heikens D (1983) J Appl Polym Sci 28:3809–3815

    Article  CAS  Google Scholar 

  38. Kendall K, Sherliker FR (1980) Br Polym J 12:85–88

    Article  CAS  Google Scholar 

  39. Ono T (1986) Org Coat 18:279–296

    CAS  Google Scholar 

  40. Laible R, Hamann K (1980) Adv Colloid Interface Sci 13:65–99

    Article  CAS  Google Scholar 

  41. Templeton-Knight RL (1990) J Oil Colour Chem Assoc 1:459–464

    Google Scholar 

  42. Hoy KL, Smith OW (1991) Polymeric material science and engineering. Abstracts of ACS Fall Meeting 1991, New York 65:78–79

    CAS  Google Scholar 

  43. Kroker R, Hamann K (1978) Angew Makromol Chemie 13:1–22

    Google Scholar 

  44. van Herk AM, German AL (1998) Microencapsulated pigments and fillers. In Arshady R (ed) Microspheres, microcapsules & liposomes, vol 1. Preparation & chemical applications, Citus Books, London

    Google Scholar 

  45. Arshady R (1993) Biomaterials 14:5–15

    Article  CAS  Google Scholar 

  46. Buske N, Goetze T (1983) Acta Polym 34:184–185

    Article  CAS  Google Scholar 

  47. Cohen B, Wong TK, Hargitay B (1986) Magnetically responsive reagent carrier. Eur Pat. 180384 A2, CA 105 P 75418n.

    Google Scholar 

  48. Caris CHM, van Elven LPM, van Herk AM, German AL (1989) Br Polym J 21:133–140

    Article  CAS  Google Scholar 

  49. Caris CHM, Kuijpers RPM, van Herk AM, German AL (1990) Makromol Chem Makromol Symp 35/36:535–548

    Google Scholar 

  50. Janssen RQF, van Herk AM, German AL (1993) J Oil Colour Chem Assoc 11:455–461

    Google Scholar 

  51. Lorimer JP, Mason TJ, Kershaw D, Livsey I, Templeton-Knight R (1991) Colloid Polym Sci 269:392–397

    Article  CAS  Google Scholar 

  52. Meguro K, Yabe T, Ishioka S, Kato K, Esumi K (1986) Bull Chem Soc Jpn 59:3019–3021

    Article  CAS  Google Scholar 

  53. Chaimberg M, Parnas R, Cohen Y (1989) J Appl Polym Sci 37:2921–2931

    Article  CAS  Google Scholar 

  54. Nagai K, Ohishi Y, Ishiyama K, Kuramoto N (1989) J Appl Polym Sci 38:2183–2189

    Article  CAS  Google Scholar 

  55. Hergeth W, Starre P, Schmutzler K, Wartewig S (1988) Polymer 29:1323–1328

    Article  CAS  Google Scholar 

  56. Janssen EAWG, van Herk AM, German AL (1993) Polym Prepr Am Chem Soc Div Polym Chem 34:532–533

    CAS  Google Scholar 

  57. Rittigstein P, Torkelson JM (2006) J Polym Sci B Polym Phys 44:2935–2943

    Article  CAS  Google Scholar 

  58. Park JS, Ruckenstein E (1990) Polymer 31:175–179

    Article  CAS  Google Scholar 

  59. Jackson S, Reboiras MD, Lyle IG, Jones MN (1986) Faraday Discuss Chem Soc 85:291–301

    Article  Google Scholar 

  60. Jung M, Hubert DHW, Bomans PHH, Frederik PM, Meuldijk J, van Herk AM, Fischer H, German AL (1997) Langmuir 13:6877–6880

    Article  CAS  Google Scholar 

  61. Jung M, Hubert DHW, Bomans P, Frederik PM, van Herk AM, German AL (2000) Adv Mater 12:210–213

    Article  CAS  Google Scholar 

  62. Jung M, den Ouden I, Montoya-Goñi A, Hubert DHW, Frederik PM, van Herk AM, German AL (2000) Langmuir 16:4185–4195

    Article  CAS  Google Scholar 

  63. Voorn DJ, Ming W, Van Herk AM (2006) Macromolecules 39:4654–4656

    Article  CAS  Google Scholar 

  64. Ali SI, Heuts JPA, Hawkett BS, van Herk AM (2009) Langmuir 25:10523–10533

    Article  CAS  Google Scholar 

  65. Voorn DJ, Ming W, van Herk AM (2006) Macromolecules 39:2137–2143

    Article  CAS  Google Scholar 

  66. Xue Z, Wiese H (2004) US patent 6833401 B1

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. M. van Herk .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2010 Springer

About this chapter

Cite this chapter

van Herk, A.M. (2010). Historical Overview of (Mini)emulsion Polymerizations and Preparation of Hybrid Latex Particles. In: van Herk, A., Landfester, K. (eds) Hybrid Latex Particles. Advances in Polymer Science, vol 233. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_2010_62

Download citation

Publish with us

Policies and ethics