Abstract
Features of the formation of cage oligomeric silsesquioxanes, including several new compounds, are described and possible reaction mechanism is proposed. Synthesis of phenyl oligomeric silsesquioxanes selectively functionalized at the 4-position is reported. Formation and utilization of incompletely condensed oligomeric silsesquioxanes are also described.
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Abbreviations
- AP:
-
Azidopropyl
- 4-BrPh:
-
4-Bromo-substituted phenyl
- BzTMAH:
-
Benzyltrimethylammonium hydroxide
- CHCl3 :
-
Chloroform
- dba:
-
Dibenzylideneacetone
- DMF:
-
N,N-Dimethylformamide
- DMS:
-
Dimethylsilyl
- dvs:
-
1,3-Divinyl-1,1,3,3-tetramethyldisiloxane
- Et:
-
Ethyl
- EtOH:
-
Ethanol
- GPC:
-
Gel permeation chromatography
- i-Bu:
-
2-Methylpropyl
- i-Bu7T8Cl:
-
1-Chloro-3,5,7,9,11,13,15-hepta(2-methylpropyl)-pentacyclo[9.5.1.13, 9.15, 15.17, 13]octasiloxane
- i-Bu7T8H:
-
1-Hydro-3,5,7,9,11,13,15-hepta(2-methylpropyl)-pentacyclo[9.5.1.13, 9.15, 15.17, 13]octasiloxane
- i-Bu7T8OH:
-
1-Hydroxy-3,5,7,9,11,13,15-hepta(2-methylpropyl)-pentacyclo[9.5.1.13, 9.15, 15.17, 13]octasiloxane
- i-Bu7T7-triol:
-
1,3,5,7,9,11,14-Hepta(2-methylpropyl)-tricyclo[7.3.3.15, 11]heptasiloxane-3,7,14-triol
- i-Bu7T8ODMS:
-
1-[Di(methylsilyl)oxy]-3,5,7,9,11,13,15-hepta(2-methylpropyl)pentacyclo[9.5.1.13, 9.15, 15.17, 13]-octasiloxane
- i-Bu,H;i-Bu,H-B10 :
-
5,15-Di(2-methylpropyl)-5,15-dihydro-1,3,7,9,11,13,17,19-octaphenylpentacylo[11.7.1.13, 11.17, 19.19, 17]decasiloxane
- i-Bu,OH;i-Bu,OH-B10 :
-
5,15-Di(2-methylpropyl)-5,15-dihydroxy-1,3,7,9,11,13,17,19-octaphenylpentacylo[11.7.1.13, 11.17, 19.19, 17]decasiloxane
- i-Pr:
-
1-Methylethyl
- LAH:
-
Lithium aluminum hydride
- M:
-
Methyl
- M2B9-diol:
-
3,3-Dimethyl-1,5,7,9,11,13,15,17-octaphenyl-tetracyclo[11.5.1.15, 11.17, 17]nonasiloxane-9,15-diol
- M2;BS-B10 :
-
5,5-Dimethyl-15,15-propylene-1,3,7,9,11,13,17,19-octaphenylpentacyclo[11.7.1.13, 11.17, 19.19, 17]-decasiloxane
- M,EP;M,EP-B10 :
-
5,15-Di[(2-triethoxysilyl)ethyl]-5,15-dimethyl-1,3,7,9,11,13,17,19-octaphenyl-pentacyclo[11.7.1.13, 11.17, 19.19, 17]decasiloxane
- M,H;M,H-B10 :
-
5,15-Dimethyl-5,15-dihydro-1,3,7,9,11,13,17,19-octaphenylpentacyclo[11.7.1.13, 11.17, 19.19, 17]-decasiloxane
- M2;M2-B10 :
-
5,5,15,15-Tetramethyl-1,3,7,9,11,13,17,19-octaphenyl-pentacyclo[11.7.1.13, 11.17, 19.19, 17]decasiloxane
- M,OE;M,OE-B10 :
-
5,15-[Di(triethoxysilyl)oxy]-5,15-dimethyl-1,3,7,9,11,13,17,19-octaphenylpentacyclo-[11.7.1.13, 11.17, 19.19, 17]decasiloxane
- M,OH;M,OH-B10 :
-
5,15-Dimethyl-5,15-dihydroxy-1,3,7,9,11,13,17,19-octaphenylpentacyclo[11.7.1.13, 11.17, 19.19, 17]-decasiloxane
- MALDI:
-
Matrix assisted laser desorption ionization
- M n :
-
Number-average molecular weight
- MS:
-
Mass spectrometry
- M w :
-
Weight-average molecular weight
- NMR:
-
Nuclear magnetic resonance spectroscopy
- Np:
-
Naphthyl
- Ph:
-
Phenyl
- POSS:
-
Polyhedral oligomeric silsesquioxane
- Q8 :
-
Spherooctasilicate
- R f :
-
Relative distance of development of solutes
- SEC:
-
Size exclusion chromatography
- TBAF:
-
Tetrabutylammonium fluoride
- T d5 :
-
5% Weight loss by thermogravimetric analysis
- TFB:
-
Tris(pentafluorophenyl)borane
- T g :
-
Glass transition temperature
- TGA:
-
Thermogravimetric analysis
- THF:
-
Tetrahydrofuran
- T m :
-
Melting temperature
- TMS:
-
Trimethylsilyl
- TMSPh:
-
Trimethylsilylphenyl
- Tn :
-
Number of silicon atoms in the POSS frame structure
- TOF:
-
Time of flight
- Tolyl:
-
4-Methylphenyl
- T s :
-
Softening temperature
- Vi:
-
Vinyl
- XRD:
-
X-ray diffraction
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Kawakami, Y., Kakihana, Y., Miyazato, A., Tateyama, S., Hoque, M.A. (2010). Polyhedral Oligomeric Silsesquioxanes with Controlled Structure: Formation and Application in New Si-Based Polymer Systems. In: Muzafarov, A. (eds) Silicon Polymers. Advances in Polymer Science, vol 235. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_2010_55
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