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Sulfonated Polyimides

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Fuel Cells II

Part of the book series: Advances in Polymer Science ((POLYMER,volume 216))

Abstract

Sulfonated polyimides have been designed to be used as proton conducting membranes in fuel cells. These materials present most of the required properties for this application, including a high level of ionic conductivity, a low gas and methanol permeability, and good mechanical properties. However, they exhibit a low stability when immersed in liquid water and in hydrogen peroxide solutions at elevated temperature due to a high sensitivity of the imide functions to hydrolysis. The aim of this article is to review the different routes of synthesis, the membrane-specific properties, the structural and transport property characteristics, and finally their behavior in fuel cells in terms of performance and stability.

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Authors and Affiliations

  1. Laboratoire des Matériaux Organiques à Propriétés Spécifiques, UMR 5041, Chemin du Canal, Echangeur de Solaize, 69360, Solaize, France

    Catherine Marestin & Régis Mercier

  2. Structure et Propriétés des Architectures Moléculaires, Groupe Polymères Conducteurs Ioniques UMR 5819 (CEA-CNRS-UJF), INAC, CEA-Grenoble, 17 rue des Martyrs, cedex 9, 38054, Grenoble, France

    Gérard Gebel & Olivier Diat

Authors
  1. Catherine Marestin
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  2. Gérard Gebel
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  3. Olivier Diat
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  4. Régis Mercier
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Correspondence to Gérard Gebel .

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Günther G. Scherer

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Marestin, C., Gebel, G., Diat, O., Mercier, R. (2008). Sulfonated Polyimides. In: Scherer, G.G. (eds) Fuel Cells II. Advances in Polymer Science, vol 216. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_2008_155

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