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Fuel Cells I pp 55–126Cite as

Structural and Morphological Features of Acid-Bearing Polymers for PEM Fuel Cells

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Part of the book series: Advances in Polymer Science ((POLYMER,volume 215))

Abstract

Chemical structure, polymer microstructure, sequence distribution, and morphology of acid-bearing polymers are important factors in the design of polymer electrolyte membranes (PEMs) for fuel cells. The roles of ion aggregation and phase separation in vinylic- and aromatic-based polymers in proton conductivity and water transport are described. The formation, dimensions, and connectivity of ionic pathways are consistently found to play an important role in determining the physicochemical properties of PEMs. For polymers that possess low water content, phase separation and ionic channel formation significantly enhance the transport of water and protons. For membranes that contain a high content of water, phase separation is less influential. Continuity of ionic aggregates is influential on the diffusion of water and electroosmotic drag within a membrane. A balance of these properties must be considered in the design of the next generation of PEMs.

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References

  1. EG & G Technical Services Inc. Science Application International Corporation (2002) Fuel Cell Handbook. US Department of Energy, p 82

    Google Scholar 

  2. Miyatake K, Shouji E, Yamamoto K, Tsuchida E (1997) Macromolecules 30:2941

    CAS  Google Scholar 

  3. Lufrano F, Squadrito G, Patti A, Passalacqua E (2000) J Appl Polym Sci 77:1250

    CAS  Google Scholar 

  4. Lufrano F, Gatto I, Staiti A, Antonucci V, Passalacqua E (2001) Solid State Ionics 145:47

    CAS  Google Scholar 

  5. Karlsson LE, Jannasch P (2004) J Membr Sci 230:61

    CAS  Google Scholar 

  6. Miyatake K, Oyaizu K, Tsuchida E, Hay AS (2001) Macromolecules 34:2065

    CAS  Google Scholar 

  7. Miyatake K, Hay AS (2001) J Polym Sci A Polym Chem 39:3211

    CAS  Google Scholar 

  8. Miyatake K, Hay AS (2001) J Polym Sci A Polym Chem 39:3770

    CAS  Google Scholar 

  9. Meng YZ, Tjong SC, Hay AS, Wang SJ (2001) J Polym Sci A Polym Chem 39:3218

    CAS  Google Scholar 

  10. Meng YZ, Tjong SC, Hay AS, Wang SJ (2003) Eur Polym J 39:627

    CAS  Google Scholar 

  11. Vetter S, Ruffmann B, Buder I, Nunes SP (2005) J Membr Sci 260:181

    CAS  Google Scholar 

  12. Zhang Y, Litt M, Savinell RF, Wainright JS (1999) Polym Prepr 40:480

    CAS  Google Scholar 

  13. Zhang Y, Litt M, Savinell RF, Wainright JS, Vendramini J (2000) Polym Prepr 41:1561

    CAS  Google Scholar 

  14. Yin Y, Fang J, Cui Y, Tanaka K, Kita H, Okamoto K (2003) Polymer 44:4509

    CAS  Google Scholar 

  15. Einsla BR, Hong YT, Kim HS, Wang F, Gunduz N, McGrath JE (2004) J Polym Sci A Polym Chem 42:862

    CAS  Google Scholar 

  16. Guo Q, Pintauro PN, Tang H, O'Connor S (1999) J Membr Sci 154:175

    CAS  Google Scholar 

  17. Tang H, Pintauro PN (2001) J Appl Polym Sci 79:49

    CAS  Google Scholar 

  18. Allcock HR, Hofmann MA, Ambler CM, Lvov SN, Zhou XY, Chalkova E, Weston J (2002) J Membr Sci 201:47

    CAS  Google Scholar 

  19. Allcock HR, Hofmann MA, Ambler CM, Morford RV (2002) Macromolecules 35:3484

    CAS  Google Scholar 

  20. Gupta B, Büchi FN, Staub M, Grman D, Scherer GG (1996) J Polym Sci A Polym Chem 34:1873

    CAS  Google Scholar 

  21. Nasef MM, Saidi H, Nor HM, Foo OM (2000) Polym Int 49:1572

    CAS  Google Scholar 

  22. Peled E, Duvdevani T, Aharon A, Melman A (2000) Electrochem Solid State Lett 3:525

    CAS  Google Scholar 

  23. Miyake N, Wainright JS, Savinell RF (2001) J Electrochem Soc 148:A905

    CAS  Google Scholar 

  24. Bonnet B, Jones DJ, Rozière J, Tchicaya L, Alberti G, Casciola M, Massinelli L, Bauer B, Peraio A, Ramunni E (2000) New Mater Electrochem Syst 3:87

    CAS  Google Scholar 

  25. Mokrini A, Acosta JL (2001) Polymer 42:9

    CAS  Google Scholar 

  26. Nácher A, Escribano P, Del Río C, Rodríguez A, Acosta JL (2003) J Polym Sci A Polym Chem 41:2809

    Google Scholar 

  27. Edmondson CA, Fontanella JJ, Chung SH, Greenbaum SG, Wnek GE (2001) Electrochim Acta 46:1623

    CAS  Google Scholar 

  28. Serpico JM, Ehrenberg SG, Fontanella JJ, Jiao X, Perahia D, McGrady KA, Sanders EH, Kellogg GE, Wnek GE (2002) Macromolecules 35:5916

    CAS  Google Scholar 

  29. Jones DJ, Rozière J (2001) J Membr Sci 185:41

    CAS  Google Scholar 

  30. Ma YL, Wainright JS, Litt M, Savinell RF (2004) J Electrochem Soc 151:A8

    CAS  Google Scholar 

  31. Savadogo O (1998) J New Mater Electrochem Syst 1:47

    CAS  Google Scholar 

  32. Rikukawa M, Sanui K (2000) Prog Polym Sci 25:1463

    CAS  Google Scholar 

  33. Kerres JA (2001) J Membr Sci 185:3

    CAS  Google Scholar 

  34. Alberti G, Casciola M, Massinelli L, Bauer B (2001) J Membr Sci 185:73

    CAS  Google Scholar 

  35. Li Q, He R, Jensen JO, Bjerrum NJ (2003) Chem Mater 15:4896

    CAS  Google Scholar 

  36. Alberti G, Casciola M (2003) Annu Rev Mater Res 33:129

    CAS  Google Scholar 

  37. Schuster MFH, Meyer WH (2003) Annu Rev Mater Res 33:233

    CAS  Google Scholar 

  38. Rozière J, Jones DJ (2003) Annu Rev Mater Res 33:503

    Google Scholar 

  39. Jannasch P (2003) Curr Opin Colloid Interf Sci 8:96

    CAS  Google Scholar 

  40. Hickner MA, Ghassemi H, Kim YS, Einsla BR, McGrath JE (2004) Chem Rev 104:4587

    CAS  Google Scholar 

  41. Savadogo O (2004) J Power Source 127:135

    CAS  Google Scholar 

  42. Smitha B, Sridhar S, Khan AA (2005) J Membr Sci 259:10

    CAS  Google Scholar 

  43. Harrison WL, Hickner MA, Kim YS, McGrath JE (2005) Fuel Cells 5:201

    CAS  Google Scholar 

  44. Kerres JA (2005) Fuel Cells 5:230

    CAS  Google Scholar 

  45. Jannasch P (2005) Fuel Cells 5:248

    CAS  Google Scholar 

  46. Gubler L, Gürsel SA, Scherer GG (2005) Fuel Cells 3:317

    Google Scholar 

  47. Souzy R, Ameduri B (2005) Prog Polym Sci 30:644

    CAS  Google Scholar 

  48. Nakao M, Yoshitake M (2003) In: Vielstich W, Lamm A, Gasteiger HA (eds) Handbook of fuel cells: fundamentals, technology and applications, part 3, vol 3. Wiley, Chichester, p 412

    Google Scholar 

  49. Kreuer KD (2003) In: Vielstich W, Lamm A, Gasteiger HA (eds) Handbook of fuel cells: fundamentals, technology and applications, part 3, vol 3. Wiley, Chichester, p 420

    Google Scholar 

  50. Wainright JS, Litt MH, Savinell RF (2003) In: Vielstich W, Lamm A, Gasteiger HA (eds) Handbook of fuel cells: fundamentals, technology and applications, part 3, vol 3. Wiley, Chichester, p 436

    Google Scholar 

  51. Jones DJ, Rozière J (2003) In: Vielstich W, Lamm A, Gasteiger HA (eds) Handbook of fuel cells: fundamentals, technology and applications, part 3, vol 3. Wiley, Chichester, p 447

    Google Scholar 

  52. Harris FW (2003) Advances in materials for proton exchange membranes fuel cell systems. Preprint Number 12, Asilomar CA

    Google Scholar 

  53. Genies C, Mercier R, Sillion B, Cornet N, Gebel G, Pinéri M (2001) Polymer 42:359

    CAS  Google Scholar 

  54. Guo X, Fang J, Watari T, Tanaka K, Kita H, Okamoto K (2002) Macromolecules 35:6707

    CAS  Google Scholar 

  55. Zaluski C, Xu G (1994) Macromolecules 27:6750

    CAS  Google Scholar 

  56. Mauritz KA, Moore RB (2004) Chem Rev 104:4535

    CAS  Google Scholar 

  57. Yang Y, Holdcroft S (2005) Fuel Cells 5:171

    CAS  Google Scholar 

  58. Hickner MA, Pivovar BS (2005) Fuel Cells 5:213

    CAS  Google Scholar 

  59. Büchi FN, Scherer GG (1996) J Electroanal Chem 404:37

    Google Scholar 

  60. Slade S, Campbell SA, Ralph TR, Walsh FC (2002) J Electrochem Soc 149:A1556

    CAS  Google Scholar 

  61. Wakizoe M, Velev OA, Srinivasan S (1995) Electrochim Acta 40:335

    CAS  Google Scholar 

  62. Healy J, Hayden C, Xie T, Olson K, Waldo R, Brundage A, Gasteiger H, Abbott J (2005) Fuel Cells 5:302

    CAS  Google Scholar 

  63. Scrosati B (1987) Electrode kinetics and electrochemical cells. In: MacCallum JR, Vincent CA (eds) Polymer electrolyte reviews 1. Elsevier, London, p 315

    Google Scholar 

  64. Hadjichristidis N, Pispas S, Floudas GA (2003) Block copolymers: synthetic strategies, physical properties, and applications. Wiley, New Jersey

    Google Scholar 

  65. Hamley IW (1998) The physics of block copolymers. Oxford University Press, New York

    Google Scholar 

  66. Morrison FA, Winter HH (1989) Macromolecules 22:3533

    CAS  Google Scholar 

  67. Kotaka T, Okamoto M, Kojima A, Kwon YK, Nojima S (2001) Polymer 42:3223

    CAS  Google Scholar 

  68. Stevens MP (1999) Polymer chemistry: an introduction, 3rd edn. Oxford University Press, New York, p 63

    Google Scholar 

  69. Brinkmann S, Stadler R, Thomas EL (1998) Macromolecules 31:6566

    CAS  Google Scholar 

  70. Funaki Y, Kumano K, Nakao T, Jinnai H, Yoshida H, Kimishima K, Tsutsumi K, Hirokawa Y, Hashimoto T (1999) Polymer 40:7147

    CAS  Google Scholar 

  71. Kim G, Libera M (1998) Macromolecules 31:2569

    CAS  Google Scholar 

  72. Heck B, Arends P, Ganter M, Kressler J, Stühn B (1997) Macromolecules 30:4559

    CAS  Google Scholar 

  73. Moore RB, Martin CR (1986) Anal Chem 58:2569

    CAS  Google Scholar 

  74. Gebel G, Aldebert P, Pinéri M (1987) Macromolecules 20:1425

    CAS  Google Scholar 

  75. Banerjee S, Curtin DE (2004) J Fluorine Chem 125:1211

    CAS  Google Scholar 

  76. Gierke TD, Hsu WY (1982) In: Eisenberg A, Yeager HL (eds) Perfluorinated ionomer membranes. ACS Symp Ser 180, chap 13, p 283

    Google Scholar 

  77. Pourcelly G, Gavach C (1992) In: Colomban P (ed) Proton conductors, solids, membranes, and gels—materials and devices. Cambridge University Press, Cambridge

    Google Scholar 

  78. Heitner-Wirguin C (1996) J Membr Sci 120:1

    CAS  Google Scholar 

  79. Grot WG (1994) Macromol Symp 82:161

    CAS  Google Scholar 

  80. Doyle M, Rajendran G (2003) Perfluorinated membranes. In: Vielstich W, Lamm A, Gasteiger HA (eds) Handbook of fuel cells: fundamentals, technology and applications, part 3, vol 3. Wiley, Chichester, p 351

    Google Scholar 

  81. Fernandez RE (1999) Perfluorinated ionomers. In: Polymer data handbook. Oxford University Press, Oxford, p 233

    Google Scholar 

  82. Eisman GA (1990) J Power Sources 29:389

    CAS  Google Scholar 

  83. Prater K (1990) J Power Sources 29:239

    CAS  Google Scholar 

  84. Ghielmi A, Vaccarono P, Troglia C, Arella V (2003) Ann NY Acad Sci 984:226

    Google Scholar 

  85. Rivard LM, Pierpont D, Freemeyer HT, Thaler A, Hamrock SJ (2003) Development of a new electrolyte membrane for PEM fuel cells. Fuel cell seminar, Miami Beach

    Google Scholar 

  86. Hoshi N, Uematsu N, Saito H, Hattori M, Aoyagi T, Ikeda M (2005) US Patent 2005130006

    Google Scholar 

  87. Watakabe A (2005) US Patent 2005037265

    Google Scholar 

  88. Savett SC, Atkins JR, Sides CR, Harris JL, Thomas BH, Creager SE, Pennington WT, DesMarteau DD (2002) J Electrochem Soc 149:A1527

    CAS  Google Scholar 

  89. Atkins JR, Sides CR, Creager SE, Harris JL, Pennington WT, Thomas BH, DesMarteau DD (2003) J New Mater Electrochem Syst 6:9

    CAS  Google Scholar 

  90. Zhou Z, Dominey RN, Rolland JP, Maynor BW, Pandya AA, De Simone JM (2006) J Am Chem Soc 128:12963

    CAS  Google Scholar 

  91. Dargaville TR, George GA, Hill DJT, Whittaker AK (2003) Prog Polym Sci 28:1355

    CAS  Google Scholar 

  92. Nasef MM, Hegazy ESA (2004) Prog Polym Sci 29:499

    CAS  Google Scholar 

  93. Kabanov VY (2004) High Energ Chem 38:57

    CAS  Google Scholar 

  94. Ogawa T, Marvel CS (1985) J Polym Sci Polym Chem 23:1231

    CAS  Google Scholar 

  95. Bishop MT, Karasz FE, Russo PS, Langley KH (1985) Macromolecules 18:86

    CAS  Google Scholar 

  96. Wang F, Hickner M, Ji Q, Harrison W, Mecham J, Zawodzinski TA, McGrath JE (2001) Macromol Symp 175:387

    CAS  Google Scholar 

  97. Wang F, Hickner M, Kim YS, Zawodzinski TA, McGrath JE (2002) J Membr Sci 197:231

    CAS  Google Scholar 

  98. Harrison WL, Wang F, Mecham JB, Bhanu VA, Hill M, Kim YS, McGrath JE (2003) J Polym Sci A Polym Chem 41:2264

    CAS  Google Scholar 

  99. Xing P, Robertson GP, Guiver MD, Mikhailenko SD, Kaliaguine S (2004) Macromolecules 37:7960

    CAS  Google Scholar 

  100. Gao Y, Robertson GP, Guiver MD, Mikhailenko SD, Li X, Kaliaguine S (2005) Macromolecules 38:3237

    CAS  Google Scholar 

  101. Xing P, Robertson GP, Guiver MD, Mikhailenko SD, Kaliaguine S (2005) Polymer 46:3257

    CAS  Google Scholar 

  102. Asensio JA, Borrs S, Gmez-Romero P (2002) J Polym Sci A Polym Chem 40:3703

    CAS  Google Scholar 

  103. Einsla BR, McGrath JE (2004) Prepr Symp Am Chem Soc Div Fuel Chem 49:616

    CAS  Google Scholar 

  104. Ghassemi H, McGrath JE (2004) Polymer 45:5847

    CAS  Google Scholar 

  105. Schuster M, Kreuer KD, Anderson HT, Maier J (2007) Macromolecules 40:598

    CAS  Google Scholar 

  106. Schmeisser J, Holdcroft S, Yu J, Ngo T, McLean G (2005) Chem Mater 17:387

    CAS  Google Scholar 

  107. Cho KY, Jung HY, Shin SS, Choi NS, Sung SJ, Park JK, Choi JH, Park KW, Sung YE (2004) Electrochim Acta 50:588

    Google Scholar 

  108. Gebel G, Diat O (2005) Fuel Cells 5:261

    CAS  Google Scholar 

  109. Hsu WY, Gierke TD (1983) J Membr Sci 13:307

    CAS  Google Scholar 

  110. Fujimura M, Hashimoto T, Kawai H (1982) Macromolecules 15:136

    CAS  Google Scholar 

  111. Dreyfus B, Gebel G, Aldebert P, Pinéri M, Escoubes M, Thomas M (1990) J Phys France 51:1341

    CAS  Google Scholar 

  112. Litt MH (1997) Polym Prepr 38:80

    CAS  Google Scholar 

  113. Haubold HG, Vad T, Jungbluth H, Jiller P (2001) Electrochim Acta 46:1559

    CAS  Google Scholar 

  114. Gebel G (2000) Polymer 41:5829

    CAS  Google Scholar 

  115. Rubatat L, Rollet AL, Gebel G, Diat O (2002) Macromolecules 35:4050

    CAS  Google Scholar 

  116. Gierke TD, Munn GE, Wilson FC (1981) J Polym Sci Polym Phys Ed 19:1687

    CAS  Google Scholar 

  117. Xue T, Trent JS, Osseo-Asare K (1989) J Membr Sci 45:261

    CAS  Google Scholar 

  118. Porat Z, Fryer JR, Huxham M, Rubinstein I (1995) J Phys Chem 99:4667

    CAS  Google Scholar 

  119. McLean RS, Doyle M, Sauer BB (2000) Macromolecules 33:6541

    CAS  Google Scholar 

  120. Moore RB, Martin CR (1988) Macromolecules 21:1334

    CAS  Google Scholar 

  121. Laporta M, Pegoraro M, Zanderighi L (2000) Macromol Mater Eng 282:22

    CAS  Google Scholar 

  122. Halim J, Scherer GG, Stamm M (1994) Macromol Chem Phys 195:3783

    CAS  Google Scholar 

  123. Grot WG, Chadds C (1982) European Pat 0066369

    Google Scholar 

  124. Martin CR, Rhoades TA, Ferguson JA (1982) Anal Chem 54:161

    Google Scholar 

  125. Aldebert P, Dreyfus B, Pinéri M (1986) Macromolecules 19:2651

    CAS  Google Scholar 

  126. Aldebert P, Dreyfus B, Gebel G, Nakamura N, Pinéri M Volino F (1988) J Phys (Paris) 49:2101

    CAS  Google Scholar 

  127. Loppinet B, Gebel G, Williams CE (1997) J Phys Chem B 101:1884

    CAS  Google Scholar 

  128. Loppinet B, Gebel G (1998) Langmuir 14:1977

    CAS  Google Scholar 

  129. Lee SJ, Yu TL, Lin HL, Liu WH, Lai CL (2004) Polymer 45:2853

    CAS  Google Scholar 

  130. pK a database 4.0 by Advanced Chemistry Development, Inc. (Toronto), http://www.acdlabs.com/products/phys_chem_lab/pKa

  131. Ma C, Zhang L, Mukerjee S, Ofer D, Nair N (2003) J Membr Sci 219:123

    CAS  Google Scholar 

  132. Weast RC (ed) (1983) CRC handbook of chemistry and physics, 64th edn. CRC, Boca Raton, p 167

    Google Scholar 

  133. Essafi W, Gebel G, Mercier R (2004) Macromolecules 37:1431

    CAS  Google Scholar 

  134. Kreuer KD (2001) J Membr Sci 185:29

    CAS  Google Scholar 

  135. Ise M (2000) Ph.D. thesis, University of Stuttgart

    Google Scholar 

  136. Kim YS, Dong L, Hickner MA, Pivovar BS, McGrath JE (2003) Polymer 44:5729

    CAS  Google Scholar 

  137. Kim YS, Wang F, Hickner M, Mccartney S, Hong YT, Harrison W, Zawodzinski TA, McGrath JE (2003) J Polym Sci B Polym Phys 41:2816

    CAS  Google Scholar 

  138. Beattie PD, Orfino FP, Basura VI, Zychowska K, Ding JF, Chuy C, Schmeisser J, Holdcroft S (2001) J Electroanal Chem 503:45

    CAS  Google Scholar 

  139. Yarusso DJ, Cooper SL (1983) Macromolecules 16:1871

    CAS  Google Scholar 

  140. Orifino FP, Holdcroft S (2000) J New Mater Electrochem Syst 3:287

    Google Scholar 

  141. Gebel G, Diat O, Stone C (2003) J New Mater Electrochem Syst 6:17

    CAS  Google Scholar 

  142. Kroschwitz JI et al. (eds) (1985) Encyclopedia of polymer science and technology, vol 2. Wiley, New York, p 324

    Google Scholar 

  143. Cornet N, Diat O, Gebel G, Jousse F, Marsacq D, Mercier R, Pinéri M (2000) J New Mater Electrochem Syst 3:33

    CAS  Google Scholar 

  144. Faure S, Cornet N, Gebel G, Mercier R, Pinéri M, Sillion B (1997) In: Savadogo O, Roberge PR (eds) Proceedings of the second international symposium on new materials for fuel cell and modern battery systems. Montreal, 6–10 July 1997, p 818

    Google Scholar 

  145. Cornet N, Beaudoing G, Gebel G (2001) Sep Purif Technol 22–23:681

    Google Scholar 

  146. Piroux F, Espuche E, Mercier R, Pinéri M (2003) J Membr Sci 223:127

    CAS  Google Scholar 

  147. Kim J, Kim B, Jung B (2002) J Membr Sci 207:129

    CAS  Google Scholar 

  148. Kim J, Kim B, Jung B, Kang YS, Ha HY, Oh IH, Ihn KJ (2002) Macromol Rapid Commun 23:753

    CAS  Google Scholar 

  149. Kim B, Kim J, Jung B (2005) J Membr Sci 250:175

    CAS  Google Scholar 

  150. Elabd YA, Walker CW, Beyer FL (2004) J Membr Sci 231:181

    CAS  Google Scholar 

  151. Elabd YA, Napadensky E, Walker CW, Winey KI (2006) Macromolecules 39:399

    CAS  Google Scholar 

  152. Webster OW (1991) Science 251:887

    CAS  Google Scholar 

  153. Wang J, Matyjaszewski K (1995) J Am Chem Soc 117:5614

    CAS  Google Scholar 

  154. Wang J, Matyjaszewski K (1995) Macromolecules 28:7901

    CAS  Google Scholar 

  155. Matyjaszewski K (ed) (1998) Controlled radical polymerization, ACS Symp Ser 685. American Chemical Society, Washington

    Google Scholar 

  156. Matyjaszewski K, Xia J (2001) Chem Rev 101:2921

    CAS  Google Scholar 

  157. Zhang Z, Ying S, Shi Z (1999) Polymer 40:1341

    CAS  Google Scholar 

  158. Yang YS, Shi Z, Holdcroft S (2004) Eur Polym J 40:531

    CAS  Google Scholar 

  159. Yang YS, Shi Z, Holdcroft S (2004) Macromolecules 37:1678

    CAS  Google Scholar 

  160. Kerres J, Ullrich A, Häring T, Baldauf M, Gebhardt U, Preidel W (2000) J New Mater Electrochem Syst 3:229

    CAS  Google Scholar 

  161. Destarac M, Matyjaszewski K, Silverman E, Ameduri B, Boutevin B (2000) Macromolecules 33:4613

    CAS  Google Scholar 

  162. Shi Z, Holdcroft S (2004) Macromolecules 37:2084

    CAS  Google Scholar 

  163. Shi Z, Holdcroft S (2005) Macromolecules 38:4193

    CAS  Google Scholar 

  164. Jokela K, Serimaa R, Torkkeli M, Sundholm F, Kallio T, Sundholm G (2002) J Polym Sci B Polym Phys 40:1539

    CAS  Google Scholar 

  165. Hietala S, Paronen M, Holmberg S, Näsman J, Juhanoja J, Karjalainen M, Serimaa R, Toivola M, Lehtinen T, Parovuori K, Sundholm G, Ericson H, Mattsson B, Torell L, Sundholm F (1999) J Polym Sci A Polym Chem 37:1741

    CAS  Google Scholar 

  166. Ding J, Chuy C, Holdcroft S (2002) Macromolecules 35:1348

    CAS  Google Scholar 

  167. Ding J, Chuy C, Holdcroft S (2001) Chem Mater 13:2231

    CAS  Google Scholar 

  168. Ding J, Chuy C, Holdcroft S (2002) Adv Funct Mater 12:389

    CAS  Google Scholar 

  169. Norsten TB, Guiver MD, Murphy J, Astill T, Navessin T, Holdcroft S, Frankamp BL, Rotello VM, Ding JF (2006) Adv Funct Mater 16:1814

    CAS  Google Scholar 

  170. Basura VI, Chuy C, Beattie PD, Holdcroft S (2001) J Electroanal Chem 501:77

    CAS  Google Scholar 

  171. Doyle M, Lewittes ME, Roelofs MG, Perusich SA (2001) J Phys Chem B 105:9387

    CAS  Google Scholar 

  172. Carretta N, Tricoli V, Picchioni F (2000) J Membr Sci 166:189

    CAS  Google Scholar 

  173. Elabd YA, Napadensky E, Sloan JM, Crawford DM, Walker CW (2003) J Membr Sci 217:227

    CAS  Google Scholar 

  174. Kim YS, Hickner MA, Dong L, Pivovar BS, McGrath JE (2004) J Membr Sci 243:317

    CAS  Google Scholar 

  175. Silva RF, Francesco MD, Pozio A (2004) Electrochim Acta 49:3211

    CAS  Google Scholar 

  176. Slade S, Campbell SA, Ralph TR, Walsh FC (2002) J Electrochem Soc 149:A1556

    CAS  Google Scholar 

  177. Dimitrova P, Friedrich KA, Vogt B, Stimming U (2002) J Electroanal Chem 532:75

    CAS  Google Scholar 

  178. Kreuer KD, Paddison SJ, Spohr E, Schuster M (2004) Chem Rev 104:4637

    CAS  Google Scholar 

  179. Eigen M, De Maeyer L (1958) Proc R Soc Lond A Math Phys Sci 247:505

    Article  CAS  Google Scholar 

  180. Zundel G, Metzger H (1968) Z Phys Chem 58:225

    CAS  Google Scholar 

  181. Zundel G, Fritch J (1986) In: Dogonadze R, Kalman E, Kornyshev AA, Ulstrup J (eds) Spectroscopy of solvation, the chemical physics of solvation, part B. Elsevier, Amsterdam, p 21

    Google Scholar 

  182. Spohr E, Commer P, Kornyshev AA (2002) J Phys Chem B 106:10560

    CAS  Google Scholar 

  183. Agmon N (1995) Chem Phys Lett 244:456

    CAS  Google Scholar 

  184. Kreuer KD (2000) Solid State Ionics 136–137:149

    Google Scholar 

  185. Bender G (1999) Master thesis. University of Stuttgart

    Google Scholar 

  186. Paddison SJ, Bender G, Kreuer KD, Nicoloso N, Zawodzinski TA (2000) J New Mater Electrochem Syst 3:293

    Google Scholar 

  187. Tuckerman ME, Marx D, Klein ML, Parrinello M (1997) Science 275:817

    CAS  Google Scholar 

  188. Kreuer KD (1996) Chem Mater 8:610

    CAS  Google Scholar 

  189. Siu A, Schmeisser J, Holdcroft S (2006) J Phys Chem B 110:6072

    CAS  Google Scholar 

  190. Peckham TJ, Schmeisser J, Holdcroft S. J Phys Chem B (in press)

    Google Scholar 

  191. Zawodzinski TA, Derouin C, Radzinski S, Sherman RJ, Smith VT, Springer TE, Gottesfeld S (1993) J Electrochem Soc 140:1041

    CAS  Google Scholar 

  192. Pivovar AA, Pivovar BS (2005) J Phys Chem B 109:785

    CAS  Google Scholar 

  193. Sondheimer SJ, Bunce NY, Fyfe CA (1986) J Macromol Sci Rev Macromol Chem Phys C26:353

    Google Scholar 

  194. Hatakeyama H, Hatakeyama T (1998) Thermochim Acta 308:3

    CAS  Google Scholar 

  195. Kim YS, Dong L, Hickner MA, Glass TE, Webb V, McGrath JE (2003) Macromolecules 36:6281

    CAS  Google Scholar 

  196. Gupta B, Haas O, Scherer GG (1995) J Appl Polym Sci 57:855

    CAS  Google Scholar 

  197. Kanekiyo M, Kobayashi M, Ando I, Kurosu H, Ishii T, Amiya S (1998) J Mol Struct 447:49

    CAS  Google Scholar 

  198. Ghi PY, Hill DJT, Whittaker AK (2002) Biomacromolecules 3:991

    CAS  Google Scholar 

  199. Saito M, Hayamizu K, Okada T (2005) J Phys Chem B 109:3112

    CAS  Google Scholar 

  200. Elomaa M, Hietala S, Paronen M, Walsby N, Jokela K, Serimaa R, Torkkeli M, Lehtinen T, Sundholm G, Sundholm F (2000) J Mater Chem 10:2678

    CAS  Google Scholar 

  201. Lafitte B, Karlsson LE, Jannasch P (2002) Macromol Rapid Commun 23:896

    CAS  Google Scholar 

  202. Siu A, Pivovar B, Horsfall J, Lovell KV, Holdcroft S (2006) J Polym Sci B Polym Phys 44:2240

    CAS  Google Scholar 

  203. Randin JP (1982) J Electrochem Soc 129:1215

    CAS  Google Scholar 

  204. Paddison SJ (2003) Annu Rev Mater Res 33:289

    CAS  Google Scholar 

  205. Uosaki K, Okazaki K, Kita H (1990) J Electroanal Chem 287:163

    CAS  Google Scholar 

  206. Cappadonia M, Erning JW, Stimming U (1994) J Electroanal Chem 376:189

    CAS  Google Scholar 

  207. Cappadonia M, Erning JW, Niaki SMS, Stimming U (1995) Solid State Ionics 77:65

    CAS  Google Scholar 

  208. Zawodzinski TA, Neeman M, Sillerud LO, Gottesfeld S (1991) J Phys Chem 95:6040

    CAS  Google Scholar 

  209. Zawodzinski TA, Springer TE, Davey J, Jestel R, Lopez C, Valerio J, Gottesfeld S (1993) J Electrochem Soc 140:1981

    CAS  Google Scholar 

  210. Edmondson CA, Stallworth PE, Chapman ME, Fontanella JJ, Wintersgill MC, Chung SH, Greenbaum SG (2000) Solid State Ionics 135:419

    CAS  Google Scholar 

  211. Edmondson CA, Fontanella JJ (2002) Solid State Ionics 152–153:355

    Google Scholar 

  212. Saito M, Arimura N, Hayamizu K, Okada T (2004) J Phys Chem B 108:16064

    CAS  Google Scholar 

  213. Dong L, Kim YS, Wang F, Hickner M, Glass TE, McGrath JE (2003) Polym Prepr 44:355

    CAS  Google Scholar 

  214. Collings AF, Mills R (1970) J Chem Soc Faraday Trans 66:2761

    CAS  Google Scholar 

  215. Ye X, LeVan MD (2003) J Membr Sci 221:147

    CAS  Google Scholar 

  216. Ge S, Li X, Yi B, Hsing IM (2005) J Electrochem Soc 152:A1149

    CAS  Google Scholar 

  217. Rivin D, Kendrick CE, Gibson PW, Schneider NS (2001) Polymer 42:623

    CAS  Google Scholar 

  218. Gates CM, Newman J (2000) AIChE J 46:2076

    CAS  Google Scholar 

  219. Krtil P, Trojánek A, Samec Z (2001) J Phys Chem 105:7979

    CAS  Google Scholar 

  220. Okada T, Xie G, Gorseth O, Kjelstruo S, Nakamura N, Arimura T (1998) Electrochim Acta 43:3741

    CAS  Google Scholar 

  221. Yeo SC, Eisenberg A (1977) J Appl Polym Sci 21:875

    CAS  Google Scholar 

  222. Motupally S, Becker AJ, Weidner JW (2000) J Electrochem Soc 147:3171

    CAS  Google Scholar 

  223. Webber AZ, Newman J (2004) J Electrochem Soc 146:2049

    Google Scholar 

  224. Fuller TF, Newman J (1992) J Electrochem Soc 139:1332

    CAS  Google Scholar 

  225. Breslau BR, Miller IF (1971) Ind Eng Chem Fundam 10:554

    CAS  Google Scholar 

  226. Xie G, Okada T (1995) J Electrochem Soc 142:3057

    CAS  Google Scholar 

  227. Okada T, Xie G, Meeg M (1998) Electrochim Acta 43:2141

    CAS  Google Scholar 

  228. Zawodzinski TA, Davey J, Valerio J, Gottesfeld S (1995) Electrochim Acta 40:297

    CAS  Google Scholar 

  229. Ren X, Henderson W, Gottesfeld S (1997) J Electrochem Soc 144:L267

    CAS  Google Scholar 

  230. Ren X, Gottesfeld S (2001) J Electrochem Soc 148:A87

    CAS  Google Scholar 

  231. Ise M, Kreuer KD, Maier J (1999) Solid State Ionics 125:213

    CAS  Google Scholar 

  232. Pivovar BS, Smyrl WH, Cussler EL (2005) J Electrochem Soc 152:A53

    CAS  Google Scholar 

  233. Antolini E (2004) J Appl Electrochem 34:563

    CAS  Google Scholar 

  234. Mathias MF, Roth J, Fleming J, Lehnert W (2003) Diffusion media materials and characterization. In: Vielstich W, Lamm A, Gasteiger HA (eds) Handbook of fuel cells: fundamentals, technology and applications, part 3, vol 3. Wiley, Chichester, p 517

    Google Scholar 

  235. Kocha SS (2003) Principles of MEA preparation. In: Vielstich W, Lamm A, Gasteiger HA (eds) Handbook of fuel cells: fundamentals, technology and applications, part 3, vol 3. Wiley, Chichester, p 538

    Google Scholar 

  236. Kinoshita K, Stonehart P (1977) In: Bockris JO, Conway BE (eds) Modern aspects of electrochemistry, vol 12. Plenum, New York, chap 4

    Google Scholar 

  237. Lee SJ, Mukerjee S, McBreen J, Rho YW, Kho YT, Lee TH (1998) Electrochim Acta 43:3693

    CAS  Google Scholar 

  238. Cheng XL, Yi BL, Han M, Zhang JX, Qiao YG, Yu JR (1999) J Power Sources 79:75

    CAS  Google Scholar 

  239. Navessin T, Holdcroft S, Wang Q, Song D, Lin Z, Eikerling M, Horsfall J, Lovell KV (2004) J Electroanal Chem 567:111

    CAS  Google Scholar 

  240. Navessin T, Eikerling M, Wang Q, Song D, Lin Z, Horsfall J, Lovell KV, Holdcroft S (2005) J Electrochem Soc 152:A796

    CAS  Google Scholar 

  241. Chuy C, Basura VI, Simon E, Holdcroft S, Horsfall J, Lovell KV (2000) J Electrochem Soc 147:4453

    Google Scholar 

  242. Horsfall J, Lovell KV (2001) Fuel Cells 1:186

    CAS  Google Scholar 

  243. Huslage J, Rager T, Schnyder B, Tsukada A (2002) Electrochim Acta 48:247

    CAS  Google Scholar 

  244. Easton EB, Langsdorf BL, Hughes JA, Sultan JM, Qi Z, Kaufman A, Pickup PG (2003) J Electrochem Soc 150:C735

    CAS  Google Scholar 

  245. Baradie B, Dodelet JP, Guay D (2000) J Electroanal Chem 489:101

    CAS  Google Scholar 

  246. Kim YS, Sumner MJ, Harrison WL, Riffle JS, McGrath JE, Pivovar BS (2004) J Electrochem Soc 151:A2150

    CAS  Google Scholar 

  247. Easton EB, Astill TD, Holdcroft S (2005) J Electrochem Soc 152:A752

    CAS  Google Scholar 

  248. Horsfall JA, Lovell KV (2002) Polym Adv Technol 13:381

    CAS  Google Scholar 

  249. Brack HP, Büchi FN, Huslage J, Scherer GG (1998) In: Gottesfeld S, Fuller TF (eds) Proceedings of the 2nd symposium on proton conducting membrane fuel cells II, proceedings vol 98-27. The Electrochemical Society, Boston, p 52

    Google Scholar 

  250. Gubler L, Kuhn H, Schmidt TJ, Scherer GG, Brack HP, Simbeck K (2004) Fuel Cells 4:196

    CAS  Google Scholar 

  251. Steck AE, Stone C (1997) In: Savadogo O, Roberge PR Valeriu A (eds) New materials for fuel cell and modern battery systems II: proceedings of the second international symposium on new materials for fuel cell and modern battery systems. l'Ecole Polytechnique de Montreal, Montreal, p 792

    Google Scholar 

  252. Bauer B, Jones DJ, Rozière J, Tchicaya L, Alberti G, Casciola M, Massinelli L, Peraio A, Besse S, Ramunni E (2000) J New Mater Electrochem Syst 3:93

    CAS  Google Scholar 

  253. Soczka-Guth T, Baurmeister J, Frank G, Knauf R (1999) WO Patent 99/29763

    Google Scholar 

  254. Blazquez JA, Iruin JJ, Eceolaza S, Marestin C, Mercier R, Mecerreyes D, Miguel O, Vela A, Marcilla R (2005) J Power Sources 151:63

    CAS  Google Scholar 

  255. Besse S, Capron P, Diat O, Gebel G, Jousse F, Marsacq D, Pinéri M, Marestin C, Mercier R (2002) J New Mater Electrochem Syst 5:109

    CAS  Google Scholar 

  256. Ehrenberg SG, Serpico JM, Sheikh-Ali BM, Tangredi TN, Zador E, Wnek GE (1997) In: Savadogo O, Roberge PR, Valeriu A (eds) New materials for fuel cell and modern battery systems II: proceedings of the second international symposium on new materials for fuel cell and modern battery systems. l'Ecole Polytechnique de Montreal, Montreal, p 828

    Google Scholar 

  257. Kallio T, Lundstrom M, Sundholm G, Walsby N, Sundholm F (2002) J Appl Electrochem 32:11

    CAS  Google Scholar 

  258. Kallio T, Jokela K, Ericson H, Serimaa R, Sundholm G, Jacobsson P, Sundholm F (2003) J Appl Electrochem 33:505

    CAS  Google Scholar 

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Author notes

  1. Steven Holdcroft

    Present address: Department of Chemistry, Simon Fraser University, 8888 University Drive, V5A 1S6, Burnaby, BC, Canada

  2. Timothy J. Peckham

    Present address: Institute for Fuel Cell Innovation, National Research Council Canada, 3250 East Mall, V6T 1W5, Vancouver, BC, Canada

Authors and Affiliations

  1. Department of Chemistry, Simon Fraser University, 8888 University Drive, V5A 1S6, Burnaby, BC, Canada

    Yunsong Yang, Ana Siu & Timothy J. Peckham

  2. Institute for Fuel Cell Innovation, National Research Council Canada, 3250 East Mall, V6T 1W5, Vancouver, BC, Canada

    Steven Holdcroft

  3. Ballard Power Systems Inc., 9000 Glenlyon Parkway, V5J 5J8, Burnaby, BC, Canada

    Yunsong Yang

  4. Risø National Laboratory, The Danish Polymer Centre Risø, Building 111, P.O. Box 49, 4000, Risø, Denmark

    Ana Siu

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  1. Yunsong Yang
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  2. Ana Siu
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  4. Steven Holdcroft
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Correspondence to Steven Holdcroft .

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Günther G. Scherer

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Yang, Y., Siu, A., Peckham, T.J., Holdcroft, S. (2008). Structural and Morphological Features of Acid-Bearing Polymers for PEM Fuel Cells. In: Scherer, G.G. (eds) Fuel Cells I. Advances in Polymer Science, vol 215. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_2008_134

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