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Quantitative Determination of Volatiles in Polymers and Quality Control of Recycled Materials by Static Headspace Techniques

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Chromatography for Sustainable Polymeric Materials

Part of the book series: Advances in Polymer Science ((POLYMER,volume 211))

Abstract

A presentation is given of headspace (HS) extraction and headspace solid-phase microextraction (HS-SPME) techniques and their combination with multiple headspace (MHS) extraction to enable quantitative determination of volatiles in solid polymer matrixes. As an example, the development of HS, HS-SPME, and MHS-SPME methods for extraction of volatiles from thermo-oxidized and/or recycled polyamide 6.6 is reviewed with special focus on the problems encountered when extracting analytes from solid-sample matrixes including excessively long equilibrium times and adsorption of analytes to the sample matrix. Examples are also given of the application of HS-SPME in quality control of recycled materials, in durability assessment of polymeric materials and in degradation studies.

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Authors and Affiliations

  1. Department of Fibre and Polymer Technology, School of Chemical Science and Engineering, Royal Institute of Technology (KTH), 10044, Stockholm, Sweden

    Mikael Gröning, Minna Hakkarainen & Ann-Christine Albertsson

Authors
  1. Mikael Gröning
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  2. Minna Hakkarainen
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  3. Ann-Christine Albertsson
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Correspondence to Ann-Christine Albertsson .

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Ann-Christine Albertsson Minna Hakkarainen

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© 2007 Springer-Verlag Berlin Heidelberg

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Gröning, M., Hakkarainen, M., Albertsson, AC. (2007). Quantitative Determination of Volatiles in Polymers and Quality Control of Recycled Materials by Static Headspace Techniques. In: Albertsson, AC., Hakkarainen, M. (eds) Chromatography for Sustainable Polymeric Materials. Advances in Polymer Science, vol 211. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_2007_117

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