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Polymer Monolayer Dynamics

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Functional Materials and Biomaterials

Part of the book series: Advances in Polymer Science ((POLYMER,volume 209))

Abstract

This is to review viscoelastic properties of monomolecular layers of polymers on the air/water interface,as probed principally by surface light scattering. The method is a non-invasive one that makes useof spontaneous capillary waves, induced by density fluctuations within liquids under thermal equilibrium.The capillary waves are also called ripplons, and they propagate with temporal damping. The interface isdetermined to be molecularly smooth but still dielectric permittivity difference between air and water islarge enough to give rise to strong light scattering. Thus, the scattering amounts to a surface analogof Brillouin scattering in bulk liquid wherein spontaneously propagating phonons interact with light. Thus,the power spectra of scattered light from the interface provide the propagation rate and the damping coefficient.Analysis is based on the resonant mode-coupling of lateral and transverse waves that are recast into thelateral storage modulus and the corresponding loss modulus. By virtue of the two-dimensional characterof the monolayers, many intriguing observations have been made with respect to amphiphilic properties andchain architecture of homopolymers and copolymers. Close connection and correspondence between the staticproperties of polymer monolayers and their rheological behavior have been established, and the review coversreports over the past two decades.

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Authors and Affiliations

  1. Department of Chemistry, University of Wisconsin, 53706, Madison, WI, USA

    Hyuk Yu

  2. Department of Chemistry, Virginia Polytechnic Institute and State University, 24061, Blacksburg, VA, USA

    Alan R. Esker

  3. Department of Physics & Division of Engineering & Applied Sciences, Harvard University, 02138, Cambridge, MA, USA

    Chanjoong Kim

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  1. Alan R. Esker
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  2. Chanjoong Kim
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  3. Hyuk Yu
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Correspondence to Hyuk Yu .

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Esker, A.R., Kim, C., Yu, H. (2007). Polymer Monolayer Dynamics. In: Functional Materials and Biomaterials. Advances in Polymer Science, vol 209. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_2007_113

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