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Emissive Materials Nanomaterials pp 189–260Cite as

Conducting Polymer Nanomaterials and Their Applications

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Part of the book series: Advances in Polymer Science ((POLYMER,volume 199))

Abstract

A paradigm shift takes place in the fabrication of conducting polymers from bulky features with microsize to ultrafine features with nanometer range. Novel conducting polymer nanomaterials require the potential to control synthetic approaches of conducting polymer on molecular and atomic levels. In this article, the synthetic methodology of conducting polymer has been briefly considered with chemical oxidation polymerization and electrochemical polymerization. The recent achievements in the fabrication of conducting polymer nanomaterials have been extensively reviewed with respect to soft template method, hard template method and template-free method. It also details the morphological spectrum of conducting polymer nanomaterials such as nanoparticle, core-shell nanomaterial, hollow nanosphere, nanofiber/nanorod, nanotube, thin film and nanopattern and nanocomposite. In addition, their applications are discussed under nanometer-sized dimension.

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Abbreviations

AAO:

Anodic aluminum oxide

AFM:

Atomic force microscopy

AOT:

Sodium bis(2-ethylhexyl) sulfosuccinate

APS:

Ammonium persulfate

CNT:

Carbon nanotube

C-PPV:

Poly(p-phenylene vinylene) with crown ether substituents

CSA:

Camphorsulfonic acid

CVD:

Chemical vapor deposition

1-D:

One-dimensional

2-D:

Two-dimensional

3-D:

Three-dimensional

DBSA:

Dodecylbenzenesulfonic acid

DeTAB:

Decyltrimethylammonium bromide

DTAB:

Dodecyltrimethylammonium bromide

E 0 :

Oxidation potential

EDOT:

3,4-ethylenedioxythiophene

EMI:

Electromagnetic interference

h:

Hour(s)

ICP:

Inherently conducting polymer

ITO:

Indium tin oxide

LB:

Langmuir–Blodgett

LBL:

Layer-by-layer

LED:

Light emitting diode

min:

Minute(s)

mm:

Millimeter(s)

μm:

Micrometer(s)

MEH-PPV:

Poly[2-methoxy-5-(2-ethylhexyloxy)-p-phenylenevinylene]

MH-PPV:

Poly[2-methoxy-5-(n-hexadecyloxy)-p-phenylenevinylene]

MIMIC:

Micromolding in capillaries

nm:

Nanometer(s)

NMP:

N-methylpyrrolidone

NSA:

Naphthalene sulphonic acid

OTAB:

Octyltrimethylammonium bromide

p :

Para

PADPA:

p-amino-diphenylamine

PANI:

Polyaniline

PC:

Polycarbonate

PEDOT:

Poly(3,4-ethylenedioxythiophene)

PEO:

Poly(ethylene oxide)

P3HT:

Poly(3-hexylthiophene)

PL:

Photoluminescence

PMMA:

Poly(methyl methacrylate)

PPV:

Poly(p-phenylene vinylene)

PPy:

Polypyrrole

PS:

Polystyrene

PS-PIAT:

Diblock copolymer consisting of 40 styrene and 50 3-(isocyano-1-alanylaminoethyl)thiophene

PSS:

Poly(sodium 4-styrenesulfonate)

PT:

Polythiophene

PVA:

Poly(vinyl alcohol)

PVD:

Physical vapor deposition

PVG:

Polyaniline-porous Vycor glass

PVK:

Poly(N-vinylcarbazole)

PVP:

Poly(vinyl pyrrolidone)

RT:

Room temperature

s:

Second(s)

SDS:

Sodium dodecyl sulfate

SEM:

Scanning electron microscopy

SPIAD:

Surface polymerization by ion-assisted deposition

T g :

Glass transition temperature

TEM:

Transmission electron microscopy

THF:

Tetrahydrofuran

TPPS:

5-, 10-, 15-, 20-tetrakis(4-sulfonatophenyl)porphyrin

p-TSA:

p-toluenesulfonic acid

UV-vis:

Ultraviolet-visible

VDP:

Vapor deposition polymerization

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Acknowledgments

This work has been financially supported by the Brain Korea 21 program of the Korean Ministry of Education and the Hyperstructured Organic Materials Research Center supported by Korea Science and Engineering Foundation.

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  1. Hyperstructured Organic Materials Research Center and School of Chemical and Biological Engineering, Seoul National University, Shinlimdong 56-1, 151-742, Seoul, Korea

    Jyongsik Jang

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Jang, J. (2006 ). Conducting Polymer Nanomaterials and Their Applications. In: Emissive Materials Nanomaterials. Advances in Polymer Science, vol 199. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_075

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