Abstract
Design concepts and strategies concerning the preparation of a variety of block copolymerarchitectures are presented. These aspects are discussed in relation to the self-organization ofnovel block copolymers on surfaces, utilizing a series of self-assembling processes, includingmicrophase separation, aggregation, amphiphilicity, crystallization, and liquid-crystal formation.
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Abbreviations
- ABA:
-
Linear triblock copolymer
- ABC:
-
Linear triblock terpolymer
- AFM:
-
Atomic force microscopy
- DMADPE:
-
1-(4-Dimethylaminophenyl)-1-phenylethylene
- DMAPLi:
-
3-(Dimethylamino)propyl lithium
- DTMAB:
-
Dodecyltrimethylammonium bromide
- MMA:
-
Methyl methacrylate
- MPPHM:
-
6-[4-(4-Methoxyphenyl)phenoxy]hexyl methacrylate
- n-BuLi:
-
n-Butyl lithium
- ODT:
-
Order–disorder transition
- P2VP:
-
Poly(2-vinylpyridine)
- PB:
-
Polybutadiene
- PBO:
-
Poly(butylene oxide)
- PCL:
-
Poly(ε-caprolactone)
- PEO:
-
Poly(ethylene oxide)
- PHEMA:
-
Poly(2-hydroxyethyl methacrylate)
- PI:
-
Polyisoprene
- PILi:
-
Polyisoprenyl lithium
- PMMA:
-
Poly(methyl methacrylate)
- PS:
-
Polystyrene
- PSLi:
-
Polystyryl lithium
- PtBMA:
-
Poly(tert-butyl methacrylate)
- RI:
-
Refractive index
- SAXS:
-
Small-angle X-ray scattering
- s-BuLi:
-
Sec-Butyl lithium
- SDS:
-
Sodium dodecylsulfate
- SEC:
-
Size-exclusion chromatography
- TEM:
-
Transmission electron microscopy
- T g :
-
Glass transition
- THF:
-
Tetrahydrofuran
- UV:
-
Ultraviolet
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Hadjichristidis, N., Pispas, S. (2006). Designed Block Copolymers for Ordered Polymeric Nanostructures. In: Vancso, G.J. (eds) Ordered Polymeric Nanostructures at Surfaces. Advances in Polymer Science, vol 200. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_069
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DOI: https://doi.org/10.1007/12_069
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