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Photoinitiated Synthesis of Grafted Polymers

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Surface-Initiated Polymerization I

Part of the book series: Advances in Polymer Science ((POLYMER,volume 197))

Abstract

We review various methods for the photochemical grafting of organic polymers to various substrates including, organic films, membranes, planar gold, silicon wafers, glass, silica gel, silica nanoparticles, and polydimethylsiloxane micro-channels. An emphasis is placed on photoinitiated synthesis of polymer brushes from planar gold and silicon.

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Abbreviations

AFM:

atomic force microscopy

AIBN:

2,2′-azobisisobutyronitrile

ATR:

attenuated total reflection

ATRP:

atom transfer radical polymerization

BP:

benzophenone

GF:

grafting from

GT:

grafting to

IR:

infrared

M n :

number-average molecular weight

M w :

weight-average molecular weight

MMA:

methyl methacrylate

NIPAAm:

N-isopropylacrylamide

NMR:

nuclear magnetic resonance

PAN:

polyacrylonitrile

PDMS:

polydimethylsiloxane

PE:

polyethylene

PET:

polyethylene terephthalate

PDI:

polydispersity index

PMMA:

poly(methyl methacrylate)

PS:

polystyrene

QCM:

quartz crystal microbalance

RAIRS:

reflection-absorption infrared spectroscopy

SAM:

self-assembled monolayer

SBDC:

N,N-(diethylamino)dithiocarbamoylbenzyl(trimethoxy)silane

SFM:

scanning force microscopy

SIP:

surface-initiated polymerization

THF:

tetrahydrofuran

UV:

ultra-violet

XPS:

X-ray photoelectron spectroscopy

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Authors and Affiliations

  1. Department of Chemistry, Southern Illinois University, 62901-4409, Carbondale, Il, USA

    Daniel J. Dyer

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  1. Daniel J. Dyer
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Correspondence to Daniel J. Dyer .

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Rainer Jordan

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Dyer, D.J. Photoinitiated Synthesis of Grafted Polymers. In: Jordan, R. (eds) Surface-Initiated Polymerization I. Advances in Polymer Science, vol 197. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_064

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