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Homogeneous Gold Catalysis pp 63–94Cite as

Gold-Catalyzed Transformation of Unsaturated Alcohols

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Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 357))

Abstract

The use of gold-complexes to activate carbon–carbon π-bonds has become a well-known and highly reliable mode of reactivity for applications in organic synthesis. This review covers the use of gold-catalysts for activation of unsaturated alcohols to effect substitution with concomitant loss of water and is mostly focused on reactions where the π-acidity appears to overcome the inherent Lewis acidity of the complexes for alcohol activation. Select examples from the literature which demonstrate advances made between 2011 and 2014 are presented.

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Authors and Affiliations

  1. Department of Chemistry, Center for Heterocyclic Compounds, University of Florida, 117200, Gainesville, FL, 32607, USA

    Paulo H. S. Paioti & Aaron Aponick

Authors
  1. Paulo H. S. Paioti
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  2. Aaron Aponick
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Correspondence to Aaron Aponick .

Editor information

Editors and Affiliations

  1. Department of Chemistry, University of North Texas, Denton, Texas, USA

    LeGrande M. Slaughter

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Paioti, P.H.S., Aponick, A. (2014). Gold-Catalyzed Transformation of Unsaturated Alcohols. In: Slaughter, L. (eds) Homogeneous Gold Catalysis. Topics in Current Chemistry, vol 357. Springer, Cham. https://doi.org/10.1007/128_2014_590

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