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Paramagnetic Solid-State Magic-Angle Spinning NMR Spectroscopy

  • Guido PintacudaEmail author
  • Gwendal Kervern
Part of the Topics in Current Chemistry book series (TOPCURRCHEM, volume 335)

Abstract

A number of technical improvements have recently opened up solid-state NMR to the analysis of new classes of substrates with wide ranging implications for molecular and biological sciences, with an immediate impact on a large community of researchers. A wealth of information can be extracted from the analysis of solid-state NMR signals of paramagnetic compounds, as the changes induced by the paramagnetic center depend in a well-defined way on the structure of the molecule. Solid-state NMR is in a position to allow direct, straightforward experimental access to the fine details of the molecular electronic configuration, which is in turn a sensible reporter of the molecular geometry in small catalysts as well as in larger biomolecules.

Keywords

Hyperfine coupling Magic angle spinning Paramagnetism Solid-state NMR 

Notes

Acknowledgments

A big “thanks” to Lyndon Emsley, Anne Lesage, Moreno Lelli, Andrew J. Pell, and Michael J. Knight, as well as to Ivano Bertini, Claudio Luchinat, Roberta Pierattelli, and Isabella C. Felli. The work on paramagnetic NMR in Lyon has been supported by the Agence Nationale de la Recherche (ANR 08-BLAN-0035-01 and 10-BLAN-0713-1) and by Joint Research Activity in the 6th and 7th Framework Program of the EC (EU-NMR and Bio-NMR).

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© Springer-Verlag Berlin Heidelberg 2012

Authors and Affiliations

  1. 1.Centre de RMN à Très Hauts Champs, Institut de Sciences AnalytiquesUniversité de Lyon, UMR 5280 CNRS/Ecole Normale Supérieure de Lyon/Université Claude Bernard Lyon 1VilleurbanneFrance
  2. 2.Faculté des Sciences et TechniquesUniversité Henri Poincaré (UHP), Nancy-UniversitéVandœuvre-lès-NancyFrance

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