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Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions?: A Fruitful Interplay Anyway

Part 3: Catalysis by Group 10 and 11 Elements and Bimetallic Catalysis

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Radicals in Synthesis III

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 320))

Abstract

This review summarizes the current status of transition metal catalyzed reactions involving radical intermediates in organic chemistry. This part focuses on radical-based methods catalyzed by group 10 and group 11 metal complexes. Reductive and redox-neutral C–C bond formations catalyzed by low-valent metal complexes as well as catalytic oxidative methods are reviewed. Catalytic processes which rely on the combination of two metal complexes are also covered.

For Part 1, see [1]; for Part 2, see [2]

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Acknowledgments

This manuscript is dedicated to the memory of Professor Dr. Athelstan L. J. Beckwith, a pioneer of radical chemistry. Generous funding of the work by the Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic (Z4 055 0506), and the Grant Agency of the Czech Republic (203/09/1936) is gratefully acknowledged. I thank my group for critical reading of the manuscript and many helpful comments and discussions. I apologize to all colleagues for the omission of their work that were necessary due to space constraints of the manuscript.

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  1. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo namesti 2, 16610, Prague 6, Czech Republic

    Ullrich Jahn

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  1. Ullrich Jahn
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  1. LS für Organische Chemie I, TU München, Lichtenbergstr. 4, Garching, 85747, Germany

    Markus Heinrich

  2. Kekulé-Institut für Organische, Chemie und Biochemie, Universität Bonn, Gerhard-Domagk-Str. 1, Bonn, 53121, Germany

    Andreas Gansäuer

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Jahn, U. (2011). Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions?: A Fruitful Interplay Anyway. In: Heinrich, M., Gansäuer, A. (eds) Radicals in Synthesis III. Topics in Current Chemistry, vol 320. Springer, Berlin, Heidelberg. https://doi.org/10.1007/128_2011_288

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