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Doping of Metal-Organic Frameworks with Functional Guest Molecules and Nanoparticles

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Functional Metal-Organic Frameworks: Gas Storage, Separation and Catalysis

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 293))

Abstract

Nanoparticle synthesis within metal-organic frameworks (MOFs) is performed by the adsorption of suitable precursor molecules for the metal component and subsequent decomposition to the composite materials nanoparticles@MOF. This chapter will review different approaches of loading MOFs with more complex organic molecules and metal-organic precursor molecules. The related reactions inside MOFs are discussed with a focus on stabilizing reactive intermediates in the corresponding cavities. The syntheses of metal and metal oxide nanoparticles inside MOFs are reviewed, and different synthetic routes compared. Emphasis is placed on the micro structural characterization of the materials nanoparticles@MOF with a particular focus on the location of embedded nanoparticles using TEM methods. Some first examples of applications of the doped MOFs in heterogeneous catalysis and hydrogen storage are described.

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Abbreviations

bdc:

1,4-Benzene-dicarboxylate

bpdc:

4,4′,-Biphenyldicarboxylate

BPTC:

1,1´-Biphenyl-2,2´,6,6´-tetracarboxylate

CNtBu:

Tertiary-butyl isonitrile

cod:

cis,cis-1,5-Cyclooctane

COF:

Covalent organic framework

cot:

cis,cis,cis-1,3,5-Cyclooctatriene

Cp:

Cyclopentadienyl-anion (C5H5)

cyclam:

1,4,8,11-Tetraaza-cyclotetradecane

dabco:

1,4-Diazabicyclo[2.2.2]octane

DMA:

N,N-Dimethylacetamide

dmf:

Dimethylformamide

EXAFS:

Extended X-ray absorption fine structure

FT-IR:

Fourier transform infrared spectroscopy

FWHM:

Full width at half maximum

HAADF:

High-angle annular dark field

HKUST:

Hong Kong University of Science and Technology

JUC:

Jilin University China

Me:

Methyl

MIL:

Matérial Institute Lavoisier

MOCVD:

Metal-organic vapor deposition

MOF:

Metal-organic framework

mtb:

methanetetra-benzoate

OiPr:

Iso-propoxide

pyz:

Pyrazine

SAED:

Selected area electron diffraction

STEM:

Scanning transmission electron microscopy

TATB:

triazine-1,3,5-tribenzoate

TEM:

Transmission electron microscopy

THF:

Tetrahydrofuran

wt%:

Weight percent

XANES:

X-ray absorption near edge structure

XAS:

X-ray absorption spectroscopy

XRD:

X-ray powder diffraction

ZIF:

Zeolite A imidazolate framework

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Authors and Affiliations

  1. Lehrstuhl für Anorganische Chemie II-Organometallics and Materials, Ruhr Universität Bochum, Bochum, Germany

    Felicitas Schröder & Roland A. Fischer

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  1. Felicitas Schröder
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  2. Roland A. Fischer
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Correspondence to Roland A. Fischer .

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Editors and Affiliations

  1. Faculty of Science, School of Chemistry, University of Nottingham, University Park, Nottingham, NG72RD, United Kingdom

    Martin Schröder

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Schröder, F., Fischer, R.A. (2009). Doping of Metal-Organic Frameworks with Functional Guest Molecules and Nanoparticles. In: Schröder, M. (eds) Functional Metal-Organic Frameworks: Gas Storage, Separation and Catalysis. Topics in Current Chemistry, vol 293. Springer, Berlin, Heidelberg. https://doi.org/10.1007/128_2009_4

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