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Metal Catalyzed Reductive C–C Bond Formation pp 209–248Cite as

Reductive Coupling of Unactivated Alkenes and Alkynes

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Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 279))

Abstract

Significant advances have been made in the study of catalytic reductive coupling of alkenes and alkynes over the past 10 years. This work will discuss the progress made in early transition metal and lanthanide series catalytic processes using alkyl metals or silanes as the stoichiometric reductants and the progress made in the use of late transition metals for the same reactions using silanes, stannanes and borohydrides as the reductant. The mechanisms for the reactions are discussed along with stereoselective variants of the reactions.

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Authors and Affiliations

  1. Department of Chemistry, Bowdoin College, 6600 College Station, 04011-8466, Brunswick, ME, USA

    Richard D. Broene

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  1. Richard D. Broene
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Correspondence to Richard D. Broene .

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Michael J. Krische

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© 2007 Springer-Verlag Berlin Heidelberg

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Broene, R.D. (2007). Reductive Coupling of Unactivated Alkenes and Alkynes. In: Krische, M.J. (eds) Metal Catalyzed Reductive C–C Bond Formation. Topics in Current Chemistry, vol 279. Springer, Berlin, Heidelberg. https://doi.org/10.1007/128_2007_123

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