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Dynamic Helical Structures: Detection and Amplification of Chirality

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Supramolecular Chirality

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 265))

Abstract

A unique feature of dynamic helical, chromophoric macromolecules that enables the detection of a small imbalance in chiral guest molecules through a noncovalent bonding interaction with high cooperativity is described. In sharp contrast to host–guest and supramolecular systems based on small synthetic receptor molecules, the chiral information of nonracemic guest molecules transfers with a significant amplification in a helical polymer as an excess of a single-handed helix, resulting in a highly efficient chirality-sensing system. Helical aggregates with controlled helicity based on small molecules and their chiral amplification and use in chirality sensing are also briefly described in this review.

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Authors and Affiliations

  1. Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, 464-8603, Nagoya, Japan

    Katsuhiro Maeda & Eiji Yashima

  2. Yashima Super-Structured Helix Project, Exploratory Research for Advanced Technology (ERATO), Japan Science and Technology Agency (JST), Creation Core Nagoya 101, 2266-22, Anagahora, Shimoshidami, Moriyama-ku, 463-0003, Nagoya, Japan

    Eiji Yashima

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  1. Katsuhiro Maeda
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Correspondence to Eiji Yashima .

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Mercedes Crego-Calama David N. Reinhoudt

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Maeda, K., Yashima, E. Dynamic Helical Structures: Detection and Amplification of Chirality. In: Crego-Calama, M., Reinhoudt, D.N. (eds) Supramolecular Chirality. Topics in Current Chemistry, vol 265. Springer, Berlin, Heidelberg. https://doi.org/10.1007/128_035

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