Abstract
Sustainable chemistry is a broad framework that starts with the function that a chemical product is offering. Not only chemical but also economic and ethical aspects come into focus throughout the complete lifecycle of chemical products. Green chemistry is an important building block for sustainable chemistry and addresses the issue of greener synthesis and, to a certain degree, the more benign properties of chemicals. The principles of green chemistry clearly aim at making chemical reactions and processes more environmentally friendly. Aspects such as atom efficiency, energy efficiency, harmless reactants, renewable resources, and pollution prevention are considered. Despite the progress made toward a “greener” chemistry, biotechnological processes, as processes for the conversion of biomass into value-added products, have not been properly adapted to new developments. Processes used in industrial biotechnology are predominantly linear. This review elaborates on the potential contributions of green chemistry to industrial biotechnology and vice versa. Examples are presented of how green chemistry and biotechnology can be connected to make substrate supply, upstream and downstream processing, and product formation more sustainable. The chapter ends with a case study of adipic acid production from lignin to illustrate the importance of a strong connection between green chemistry and biotechnology.
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References
Matlin SA, Mehta G, Hopf H, Krief A (2015) The role of chemistry in inventing a sustainable future. Nat Chem 7:941. https://doi.org/10.1038/nchem.2389
Kümmerer K, Clark J (2016) Green and sustainable chemistry. In: Heinrichs H, Martens P, Michelsen G, Wiek A (eds) Sustainability science: an introduction. Springer Netherlands, Dordrecht, pp 43–59. https://doi.org/10.1007/978-94-017-7242-6_4
Anastas PT, Warner JC (1998) Green chemistry: theory and practice. Oxford University Press, Oxford
Kümmerer K (2017) Sustainable chemistry: a future guiding principle. Angew Chem Int Ed 56:16420–16421. https://doi.org/10.1002/ange.201709949
Festel G (2018) Economic aspects of industrial biotechnology. Adv Biochem Eng Biotechnol. https://doi.org/10.1007/10_2018_70
MacLean H, Saville B (2018) Environmental aspects of industrial biotechnology. Adv Biochem Eng Biotechnol
Koutinas AA et al (2014) Valorization of industrial waste and by-product streams via fermentation for the production of chemicals and biopolymers. Chem Soc Rev 43:2587–2627. https://doi.org/10.1039/C3CS60293A
Pleissner D, Qi Q, Gao C, Rivero CP, Webb C, Lin CSK, Venus J (2016) Valorization of organic residues for the production of added value chemicals: a contribution to the bio-based economy. Biochem Eng J 116:3–16. https://doi.org/10.1016/j.bej.2015.12.016
Moncada JB, Aristizábal VM, Cardona CA (2016) Design strategies for sustainable biorefineries. Biochem Eng J 116:122–134. https://doi.org/10.1016/j.bej.2016.06.009
Benoît Norris C (2018) Social life cycle assessment for industrial biotechnology. Adv Biochem Eng Biotechnol
Geldermann J et al (2016) Improved resource efficiency and cascading utilisation of renewable materials. J Clean Prod 110:1–8. https://doi.org/10.1016/j.jclepro.2015.09.092
Ahmadi N, Khosravi-Darani K, Mortazavian AM (2017) An overview of biotechnological production of propionic acid: from upstream to downstream processes. Electron J Biotechnol 28:67–75. https://doi.org/10.1016/j.ejbt.2017.04.004
Özdenkçi K et al (2017) A novel biorefinery integration concept for lignocellulosic biomass. Energy Convers Manag 149:974–987. https://doi.org/10.1016/j.enconman.2017.04.034
de Jong E, Jungmeier G (2015) Biorefinery concepts in comparison to petrochemical refineries. https://doi.org/10.1016/B978-0-444-63453-5.00001-X
Baum R, Wajszczuk K, Pepliński B, Wawrzynowicz J (2013) Potential for agricultural biomass production for energy purposes in Poland: a review. Contemp Econ 7:63–74
Liverpool-Tasie LSO, Omonona BT, Sanou A, Ogunleye WO (2017) Is increasing inorganic fertilizer use for maize production in SSA a profitable proposition? Evidence from Nigeria. Food Pol 67:41–51. https://doi.org/10.1016/j.foodpol.2016.09.011
Gorazda K et al (2017) Fertilisers production from ashes after sewage sludge combustion – a strategy towards sustainable development. Environ Res 154:171–180. https://doi.org/10.1016/j.envres.2017.01.002
Zhang F, Wang Q, Hong J, Chen W, Qi C, Ye L (2017) Life cycle assessment of diammonium- and monoammonium-phosphate fertilizer production in China. J Clean Prod 141:1087–1094. https://doi.org/10.1016/j.jclepro.2016.09.107
Demichelis F, Pleissner D, Fiore S, Mariano S, Navarro Gutiérrez IM, Schneider R, Venus J (2017) Investigation of food waste valorization through sequential lactic acid fermentative production and anaerobic digestion of fermentation residues. Bioresour Technol 241:508–516. https://doi.org/10.1016/j.biortech.2017.05.174
Pleissner D, Demichelis F, Mariano S, Fiore S, Navarro Gutiérrez IM, Schneider R, Venus J (2017) Direct production of lactic acid based on simultaneous saccharification and fermentation of mixed restaurant food waste. J Clean Prod 143:615–623. https://doi.org/10.1016/j.jclepro.2016.12.065
Alexandri M, Papapostolou H, Vlysidis A, Gardeli C, Komaitis M, Papanikolaou S, Koutinas AA (2016) Extraction of phenolic compounds and succinic acid production from spent sulphite liquor. J Chem Technol Biotechnol 91:2751–2760. https://doi.org/10.1002/jctb.4880
Galbe M, Zacchi G (2002) A review of the production of ethanol from softwood. Appl Microbiol Biotechnol 59:618–628. https://doi.org/10.1007/s00253-002-1058-9
Ji W, Shen Z, Wen Y (2015) Hydrolysis of wheat straw by dilute sulfuric acid in a continuous mode. Chem Eng J 260:20–27. https://doi.org/10.1016/j.cej.2014.08.089
Zhuo K, Du Q, Bai G, Wang C, Chen Y, Wang J (2015) Hydrolysis of cellulose catalyzed by novel acidic ionic liquids. Carbohydr Polym 115:49–53. https://doi.org/10.1016/j.carbpol.2014.08.078
Haiß A, Jordan A, Westphal J, Logunova E, Gathergood N, Kümmerer K (2016) On the way to greener ionic liquids: identification of a fully mineralizable phenylalanine-based ionic liquid. Green Chem 18:4361–4373. https://doi.org/10.1039/C6GC00417B
Fenila F, Shastri Y (2016) Optimal control of enzymatic hydrolysis of lignocellulosic biomass. Resour Effic Technol 2:S96–S104. https://doi.org/10.1016/j.reffit.2016.11.006
Revin V, Atykyan N, Zakharkin D (2016) Enzymatic hydrolysis and fermentation of ultradispersed wood particles after ultrasonic pretreatment. Electron J Biotechnol 20:14–19. https://doi.org/10.1016/j.ejbt.2015.11.007
Jantasee S, Kienberger M, Mungma N, Siebenhofer M (2017) Potential and assessment of lactic acid production and isolation – a review. J Chem Technol Biotechnol 92(12):2885–2893. https://doi.org/10.1002/jctb.5237
Pleissner D, Lau KY, Schneider R, Venus J, Lin CSK (2015) Fatty acid feedstock preparation and lactic acid production as integrated processes in mixed restaurant food and bakery wastes treatment. Food Res Int 73:52–61. https://doi.org/10.1016/j.foodres.2014.11.048
Pleissner D, Schneider R, Venus J, Koch T (2017) Separation of lactic acid and recovery of salt-ions from fermentation broth. J Chem Technol Biotechnol 92:504–511. https://doi.org/10.1002/jctb.5023
Chemarin F et al (2017) New insights in reactive extraction mechanisms of organic acids: an experimental approach for 3-hydroxypropionic acid extraction with tri-n-octylamine. Sep Purif Technol 179:523–532. https://doi.org/10.1016/j.seppur.2017.02.018
Roopan SM (2017) An overview of natural renewable bio-polymer lignin towards nano and biotechnological applications. Int J Biol Macromol 103:508–514. https://doi.org/10.1016/j.ijbiomac.2017.05.103
Sonoda T, Ona T, Yokoi H, Ishida Y, Ohtani H, Tsuge S (2001) Quantitative analysis of detailed lignin monomer composition by pyrolysis-gas chromatography combined with preliminary acetylation of the samples. Anal Chem 73:5429–5435. https://doi.org/10.1021/ac010557c
Dai J, Patti AF, Saito K (2016) Recent developments in chemical degradation of lignin: catalytic oxidation and ionic liquids. Tetrahedron Lett 57:4945–4951. https://doi.org/10.1016/j.tetlet.2016.09.084
Ma Y, Du Z, Liu J, Xia F, Xu J (2015) Selective oxidative C-C bond cleavage of a lignin model compound in the presence of acetic acid with a vanadium catalyst. Green Chem 17:4968–4973. https://doi.org/10.1039/C5GC00645G
Harwood CS, Parales RE (1996) The β-ketoadipate pathway and the biology of self-identity. Annu Rev Microbiol 50:553–590. https://doi.org/10.1146/annurev.micro.50.1.553
Kohlstedt M et al (2018) From lignin to nylon: cascaded chemical and biochemical conversion using metabolically engineered Pseudomonas putida. Metab Eng 47:279–293. https://doi.org/10.1016/j.ymben.2018.03.003
van Duuren JBJH, Wijte D, Karge B, Martins dos Santos VAP, Yang Y, Mars AE, Eggink G (2012) pH-stat fed-batch process to enhance the production of cis, cis-muconate from benzoate by Pseudomonas putida KT2440-JD1. Biotechnol Prog 28:85–92. https://doi.org/10.1002/btpr.709
Johnson CW, Salvachúa D, Khanna P, Smith H, Peterson DJ, Beckham GT (2016) Enhancing muconic acid production from glucose and lignin-derived aromatic compounds via increased protocatechuate decarboxylase activity. Metab Eng Commun 3:111–119. https://doi.org/10.1016/j.meteno.2016.04.002
Capelli S et al (2017) Bio-adipic acid production by catalysed hydrogenation of muconic acid in mild operating conditions. Appl Catal B Environ 218:220–229. https://doi.org/10.1016/j.apcatb.2017.06.060
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Pleissner, D., Kümmerer, K. (2018). Green Chemistry and Its Contribution to Industrial Biotechnology. In: Fröhling, M., Hiete, M. (eds) Sustainability and Life Cycle Assessment in Industrial Biotechnology. Advances in Biochemical Engineering/Biotechnology, vol 173. Springer, Cham. https://doi.org/10.1007/10_2018_73
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DOI: https://doi.org/10.1007/10_2018_73
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