6 Summary
We have demonstrated that InAs-based narrow gap heterostructures exhibit a potential barrier at the p-n junction up to 300°C and are able to operate in positive and negative luminescence modes in the 3–5 µm spectral range: the latter being preferable for elevated temperatures in terms of the output power. The optimization of mid-IR diode construction by implementing rare earth gettering, and the use of a broad mirror anode contact and graded bandgap or heavily doped “windows” has lead to “universal” flip-chip devices that are able to operate as efficient LEDs with Fabry-Perot resonant features with an output as high as ∼0.5 mW/A and as photodiodes with a detectivity as high as 2×1010 cm Hz1/2W−1. Optical pumping using a GaAs LED appears to be an efficient way of realizing an InAsSb emitter with a conversion efficiency ∼10 µW/A in the 8 µm spectral region. The coupling of the flip-chip devices with immersion lenses or fibres through the use of high index chalcogenide glass together with an appropriate choice of the bias direction at the p-n junction can yield an additional performance enhancement of a factor of 3–5. Optically coupled LED-PD pairs can be used as precise low voltage or current sensors of gases and liquids, e.g. with an expected limit of detection for methane gas as small as LOD Δf=1 MHz =18 ppm·cm·mA·s1/2
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
P. Vujkovic-Cvijin, D.E. Cooper, J.E. van der Laan and R.E. Warren “Diode Laser Based Lidars: Next Generation” Proc.SPIE 1999,. 3758, 142 P. Vujkovic-Cvijin et al. “Mobile remote sensor for leak detection in natural gas pipelines”, Report on the Contract work #5097-260-3941 with the Gas Technology Institute, Des Plaines, IL, USA
Smith, S.D., Crowder, J.G. and Hardaway, H.R., “Recent developments in the application of mid-infrared lasers, LEDs and other solid state sources to gas detection”, Proc.SPIE 2002, 4651, 157–172
N.M. Kolchanova, A.A. Popov, A.B. Bogoslavskaya, U.S. Sukach, Tech.Phys.Lett., 1993, 19 64 (in russian)
G.A. Sukach, A.B. Bogoslavskaya, P.F. Oleksenko, Yu.Yu. Bilinets, “Effect of Auger recombination on thermal processes in InGaAs and InAsSbP IR-emitting diodes”, Infrared Physics & Technology 2000, 41, 299–306
M. Aidaraliev, N. V. Zotova, S. A. Karandashev et al. “Light Emitting Diodes for the Spectral Range of λ =3.3–4.3 µm Fabricated from the InGaAs-and InAsSbP-Based Solid Solutions: Electroluminescence in the Temperature Range of 20–180°C”, Semiconductors, 2000, 34, 102–105
L.G. Bubulak, A.M. Andrews, E.R. Gertner and D.T. Longo, “Backside-illuminated InAsSb/GaSb broadband detectors”, Appl.Phys.Lett., 1980, 36, 734–736
D.T. Cheung, A.M. Anfrews, E.R. Gertner et al. “Backside-illuminated InAs1–xSbx-InAs narrow-band photodetectors”, Appl.Phys.Lett., 1977, 30, 587–589
P.K. Chiang and S.M. Bedair, “p-n junction formation in InSb and InAs1−xSbx by metalorganic chemical vapor deposition”, Appl.Phys.Lett. 1985, 46,. 383–385
J.K. Abrokwah, M. Gershenson “Liquid phase growth and characterization of InAs1–xSbx and In1–xGaxSb on (111)B InSb substrates, Journal of Electronic materials 1981, 10, 379–420
B.A. Matveev, N.M. Stus’, G.N. Talalakin et al. “Microhardness of InGaAs, InGaAsSb, InAsSbP semiconductor alloys enriched with InAs” Izv.Akad.Nauk SSSR, Neorg.Mater, 1990, 26, 639
B.A. Matveev, N.M. Stus’, and G.N. Talalakin, “Inverse defect formation during growth of epitaxial InAsSbP/InAs structures”, Sov.Phys.Crystallogr., 1988, 33, 124–127
N.P. Esina, N.V. Zotova, B.A. Matveev et al. “Long wavelength uncooled light emitting diodes from InAs1–x–ySbxPy solid solutions”, Sov.Tech.Phys.Lett., 1983, 9, 167–168
N.V. Zotova, A.V. Losev, B.A. Matveev et al., “Absorption edge of variable-gap InAs1–xSbx (x < 0.54) epitaxial layers”, Sov.Tech.Phy.Lett., 1990, 16, 155–157
B.A. Matveev, N.V. Zotova, S.A. Karandashev, M.A. Remenniy, N.M. Stus’, G.N. Talalakin, “III–V optically pumped mid-IR LEDs”. Proc. SPIE, 2001, 4278, 189–196
B.V. Morozov, Yu.B. Bolkhovityanov, R.S. Gabaraev et al., Sov.Phys.Semicond, 1980, 14, 883
M. Fisher, A. Krier, “Photoluminescence of epitaxial InAs produced by different growth methods”, Infrared Physics & Technolog, 1997, 38, 405–413
G.R. Nash, N.T. Gordon, M.T. Emeny, T. Ashley, “Perspectives on dynamic infrared scene projection using positive and negative luminescence” Proc. SPIE, 2003, 5092, 138–144
B. A. Matveev, N. V. Zotova, N.D. Il’inskaya et al. “Towards efficient mid-IR LED operation: optical pumping, extraction or injection of carriers?”, J.Mod.Optics, 2002, 49,. 743–756
Matveev, B.A.; Zotova N.V., Karandashev S.A. et al. “Backside illuminated In(Ga)As/InAsSbP DH photodiodes for methane sensing at 3.3 µm”, Proc. SPIE 2002, 4650, 173–178
Z.M. Fang, K.Y. Ma, D.H. Jaw et al. “Photoluminescence of InSb, InAs, and InAsSb grown by organometallic vapor phase epitaxy”, J.Appl.Phys. 1990, 67, 7034–7039
X.Y. Gong, T. Yamaguchi, H. Kan et al. “Mid-Infrared Photoluminescence from Liquid Phase Epitaxial InAsSb/InAs Multilyers”, Jpn.J.Appl.Phys, 1997, 36, 738–742
Esina N.P., Zotova N.V. “Mechanisms of recombination of excess carriers in InAs and related solid solusions” Sov.Phys.Sem., 1980, 14 (Fizika & Technika Poluprovodnikov, v.14, No 3, pp. 316–322, in Russian).
A. Krier, “Physics and technology of mid-infrared light emitting diodes”, Phil. Trans. R. Soc. Lond. A 2001, 359, 599–619
N.V. Zotova, S.A. Karandashov, B.A. Matveev et al. “Gadolinium-doped InGaAsSb solid solusions on an InAs substrate for light-emitting diodes operating in the spectral interval λ=3–5 µm”, Semiconductors, 1999,. 33, 920–923
A. Rogalski “Heterostructure infrared photovoltaic detectors” Infrared Physics and Technology 2000, 41, 213–238
A.A. Bergh & P.J. Dean, “Light-emitting diodes”, Claredon Press, Oxford, 1976, (Russian translation:, “Mir”, Moscow 1979).
Http://www.ioffe.rssi.ru/SVA/NSM/Nano/index.html.
J.G. Crowder, T. Ashley, C.T. Eliott et al. “Minimally cooled InSb/InAlSb LED and photodiode devices applied to nitrogen dioxide detection at ppm levels”, Electronics Lett., 2000, 36, 1867–1869
M.J. Kane, G. Braithwaite, M.T. Ereny et al. “Bulk and surface recombination in InAs/AlAs0.16 Sb0.84 3.45 µm light emitting diodes”, Appl.Phys.Lett., 2000, 76, 943–945
A. Krier, D. Chubb, S.E. Krier et al. “Light sources for wavelengths >2 µm grown by MBE on InP using a strain relaxed buffer, IEE Proceedings, Optoelectronics 1998, 145, 292–296
M Aidaraliev, N V Zotova, N D Il’inskaya et al. “InAs and InAsSb LEDs with built-in cavities” Semicond. Sci. Technol. 2003, 18, 269–272
Zh.I. Alferov, A.T. Gorelenok, V.G. Gruzdov et al. “InGaAsP/InP DH LEDs (λ=1.55 µm) with external efficiency ηe≈30%(300 K)” Phys.Tech.Lett 1982, 8, (Pis’ma v zhurnal technicheskoy fiziki, 1992, 8, 257–262, in Russian)
V. K. Malyutenko, O.Yu. Malyutenko, A. D. Podoltsev et al., “Current crowding in InAsSb LED structures”, Applied Physics Letters, 2001, 79, 4228–4230
D.A. Wright, V.V. Sherstnev, A. Krier et al. “Mid-infrared whispering gallery mode ring lasers and LEDs” IEE Proc.-Optoelectronics 2003, 150, 314–317
M.A. Remennyi, B.A. Matveev, N.V. Zotova et al. “InGaAsSb negative luminescent devices with built-in cavities emitting at 3.9 µm”, Physica E: Low-dimensional Systems and Nanostructures, 2004, 20, 548–552
D. Gevaux, A. Green, C. Palmer et al., “Resonant-cavity light emitting diodes (RC-LEDs) and detectors for mid-IR gas-sensing applications”, IEE Proc. Optoelectron., 2003, 150, 360–364
N.V. Zotova, N.D. Il’inskaya, S.A. Karandashev et al. “InAs light-emitting diodes with cavity formed by anode contact and semiconductor/air interface” Semiconductors 2004, 38, 1–4
B. A. Matveev, M. Aidaraliev, N. V. Zotova et al., In(Ga)As-and InAs(Sb)-Based Heterostructure LEDs and Detectors for the 3,-5 µm Spectral Range”, Book of MIOMD-V Abstracts 2002, 97–98
B. Matveev., N. Zotova, N. Il’inskaya et al., “Spontaneous and stimulated emission in InAs LEDs with cavity formed by gold anode and semiconductor/Air interface”, phys. stat. sol. (c) 2005, 2, 927–930
M. AÏdaraliev, N. V. Zotova, S. A. Karandashev, et al., “Light Emitting Diodes for the Spectral Range λ = 3.3–4.3 µm Fabricated from InGaAs and InAsSbP Solid Solutions: Electroluminescence in the Temperature Range 20–180°C (Part 2)” Semiconductors, 2001, 35, 598–604.
V. I. Ivanov-Omskii, B. T. Kolomiets, and V. A. Smirnov, “Radiative recombination in InSb at magneto-concentration effect”, 1965 161 Dokl. Ak. Nauk SSSR 1956, 161, [Sov. Phys. Dokl. 10, 345 (1965)].
J. R. Lindle, W. W. Bewley, I. Vurgaftman et al. “Negative luminescence from mid-wave infrared HgCdTe diode arrays” Physica E: Low-dimensional Systems and Nanostructures 2004, 20, 558–562
B. A. Matveev, N. V. Zotova, S. A. Karandashev et al., “Towards longwave (5÷ 6 µm) LED operation at 80°C: injection or extraction of carriers?”, IEE Proceedings-Optoelectronics 2002, 149, 33–35
G.R. Nash, N.T. Gordon, D.J. Hall et al., “Infrared negative luminescent devices and higher operating temperature detectors”, Physica E: Low-dimensional Systems and Nanostructures 2004, 20, 540–547
B.A. Matveev, M. A’daraliev, N.V. Zotova, et al. “Negative luminescence from InAsSbP-based diodes in the 4.0–4.3 µm range”, Proc SPIE 2001, 4285, 109–117
B.I. Stepanov, “Basics for spectroscopy utilizing negative light beams”, Minsk, 1961
A.M. White, “Generation-recombination processes and Auger suppression in small-bandgap detectors”, Journal of Crystal Growth 1988, 86, 840–848
L.J. Olafsen, I. Vurgaftman, W.W. Bewley et al. “Negative luminescence from Type-II InAs/GaSb superlattice photodiodes”, Appl.Phys.Lett. 1999, 74, 2681–2683
W. W. Bewley, M. J. Jurkovic, C. L. Felix et al.,“HgCdTe Photodetectors with Negative Luminescent Efficiencies > 80%”, Appl.Phys.Lett., 2001, 78, 3082–3084.
M A Remennyi, N V Zotova, S A Karandashev et al. “Low voltage episide down bonded mid-IR diode optopairs for gas sensing in the 3.3–4.3 µm spectral range” Sensors & Actuators B: Chemical, 2003, 91, 256–261
A.M. White, “Generation-recombination processes and Auger suppression in small-bandgap detectors”, Journal of Crystal Growth 1988, 86, 840–848
N.P. Esina, N.V. Zotova, D.N. Nasledov, “Electroluninescence in InAs p-n junctions”, Fiz. Tech. Polupr., 1969, 3, 1370–1373 (in Russian).
A. Krier and Y. Mao, “High performance InAsSbP/InGaAs photodiodes for the 1.8–3.4 µm wavelength range”, Infrared Physics & Technology, 1997, 38, 397–403
J.L. Malin, C.L. Felix, J.R. Meyer et al., “Type II mid-IR lasers operating above room temperature”, Electron. Lett., 1996, 32, 1593–1594
M. Boroditsky, T.F. Krauss, R. Cocciol et al., “Light extraction from optically pumped light-emitting diode by thin-slab photonic crystals”, Appl.Phys.Lett., 1999, 75, 1036–1038.
Adrian John Maldan, Patent of GB No 2102942, G01N26/31, 21/35, published 09.02.83.
B.A. Matveev, N.V. Zotova, N.D. Il’inskaya et al., “Radiation Source”, GB patent #2363906 filed 21 April, 2000.
M. Aidaraliev, N. V. Zotova, S. A. Karandashev et al., “Optically Pumped “Immersion-Lens” Infrared Light Emitting Diodes Based on Narrow-Gap III–V Semiconductors”, Semiconductors, 2002, 36, 828–831
N.V. Zotova, S.A. Karandashev, B.A. Matveev, M.A. Remennyi, N.M. Stus’, and N.G. Tarakanova. “Luminescence of Multilayer Structures Based on InAsSb at λ= 6–9 µm”. Semiconductors 2005, 39, 214–217
V.N. Brudnyi, N.G. Kolin_, A.I. Potapov V.D. Kuznetsov “Electrophysical properties of proton-irradiated InAs” Semiconductors 2003, 37, 390–395
C. Sirtori, F. Capasso, J. Faist et al., “Quantum cascade unipolar intersubband light emitting diodes in the 8—13 µm wavelength region” Appl.Phys.Lett. 1998, 74, 2384–2386
A. Green, D. Gevaux, C. Roberts, and C. Philips, “Resonant-cavity-enhanced photodetectors and LEDs in the mid-infrared”, Physica E: Low-dimensional Systems and Nanostructures, 2004, 20, 531–535
R. Windish et al., “40% efficient thin-film surface textured light-emitting diodes by optimization of natural lithography” IEEE. T.Electron.Dev. 2000, 47, 1492–1498
Ashley T., Dutton D.T., Elliott C.T. et al., “Optical Concentrators for Light Emitting Diodes”, Proc. SPIE 1998, 3289, 43
R.C. Johnes. “Immersed radiation detectors”, Appl.Opt., 1962, 1, 607–613
A.G. Fischer and C.J. Nuese, “Highly Refractive Glasses to Improve Electroluminescent Diode Efficiencies”. J.Electrochem.Soc. SOLID STATE SCIENCE 1969, 116, 1718–1722
Jaw W. Chey, Peter Sultan, Hendrik J. Gerritsen, “Resonant photoacoustic detection of methane in nitrogen using a room temperature infrared light emitting diode” Appl.Optics, 1987, 26, 3192–3194
Esina N.P, Zotova N.V., Markov I.I. et al. “Gas analyzer based on semiconductor components”, J.Appl.Spectrosc., 1985, 42, 465–467
V.K. Malyutenko, 0.Yu. Malyutenko, A. Dazzi et al., “Heat transfer mapping in 3–5 µm planar light emitting structures”, J. Appl. Phys. 2003, 93, 9398–9400.
B.A. Matveev, M. Aydaraliev, N.V. Zotova et al., «Flip-chip bonded InAsSbP and InGaAs LEDs and detectors for the 3 µm Spectral Region” IEE Proc.-Optoelectronics 2003, 150, 356–359
S. McCabe and B.D. MacCraith, “Novel mid-infrared LED as a source for optical fibre gas sensing”, Electron. Lett., 1993, 29, 1719–1721
Messica, A., Greenstein, A., and Katzir, A., “Theory of Fiber-Optic, Evanescent-Wave Spectroscopy and Sensors,” Appl.Opt., 1996, 35, 2274–2284
B. Mizaikoff, “Mid-Infrared Fiberoptic Evanescent Wave Sensors — A Novel Approach for Subsea Monitoring”, Meas. Sci. Technol., 1999, 10, 1185–1194
Rick K. Nubling and James A. Harrington, “Optical properties of single-crystal sapphire fibers”, Appl.Opt., 1997, 36, 5934–5940
B. A. Matveev, N.V. Zotova, S. A. Karandashev et al. “3.4 µm “Flip-chip” LEDs for Fiber Optic Liquid Sensing” Proceedings of the 1-st International Conference on Advanced Optoelectronics and Lasers (CAOL’2003), 2003 Alushta, Crimea, Ukraine v.2, 138–140
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2006 Springer-Verlag London Limited
About this chapter
Cite this chapter
Matveev, B.A. (2006). LED-Photodiode Opto-pairs. In: Krier, A. (eds) Mid-infrared Semiconductor Optoelectronics. Springer Series in Optical Sciences, vol 118. Springer, London . https://doi.org/10.1007/1-84628-209-8_12
Download citation
DOI: https://doi.org/10.1007/1-84628-209-8_12
Publisher Name: Springer, London
Print ISBN: 978-1-84628-208-9
Online ISBN: 978-1-84628-209-6
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)