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Recent Progress in Molecular Design of Ionic Second-order Nonlinear Optical Materials

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Non-Linear Optical Properties of Matter

Part of the book series: Challenges and Advances in Computational Chemistry and Physics ((COCH,volume 1))

Abstract

This chapter deals with recent and important developments in the field of the molecular design of ionic organic materials with and without metals for second-order nonlinear optics. The first section discusses 1) the origin of optical nonlinearity, 2) the relationship between microscopic and macroscopic polarizabilities and 3) the importance of ionic chromophores as second-order nonlinear optical (NLO) materials. The second section reviews 4) the current experimental and theoretical developments in the design of dipolar and octupolar ionic chromophores for second-order nonlinear optics and 5) the progress on zwitterionic second-order NLO materials. The third section presents 6) possible device applications based on ionic chromophores

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Authors and Affiliations

  1. Department of Chemistry, Jackson State University, 1400 J.R. Lynch Street, Jackson, MS, USA

    Paresh Chandra Ray

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  1. Paresh Chandra Ray
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Editors and Affiliations

  1. National Hellenic Research Foundation, Greece

    Manthos G. Papadopoulos

  2. Nicolaus Copernicus University, Poland

    Andrzej J. Sadlej

  3. Jackson State University, USA

    Jerzy Leszczynski

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Ray, P.C. (2006). Recent Progress in Molecular Design of Ionic Second-order Nonlinear Optical Materials. In: Papadopoulos, M.G., Sadlej, A.J., Leszczynski, J. (eds) Non-Linear Optical Properties of Matter. Challenges and Advances in Computational Chemistry and Physics, vol 1. Springer, Dordrecht. https://doi.org/10.1007/1-4020-4850-5_13

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