Abstract
Polybasic carboxylic hydroxy and amino acid aided synthetic routes directed towards obtaining mixed inorganic materials, especially for battery and fuel cell applications, are overviewed. It has been shown that, in spite of enormous number of papers on the subject, significant efforts should be undertaken in order to understand the basic principles of these routes. Possible influence of the structure of reactants employed in the process (acids, poly hydroxy alcohols, metal salts) is put forward, and some directions of future work in the field are outlined.
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REFERENCES
Materials for Lithium Ion Batteries, Ed. by C. Julien and Z. Stoynov, NATO Science Series 3. High Technology, Vol. 85, Kluwer, Dordreht, 2000.
Kirillov, S. A., Tsiakaras, P. E., Romanova, I. V., Adsorption and oxidation of methanol and ethanol on the surface of metallic and ceramic catalysts, J. Mol. Struct., 651–653, 365–370 (2003).
Pechini, M., Method of preparing lead and alkaline earth titanates and niobates and coating method using the same form a capacitor, U.S.Pat. # 3330697, July 11, 1967.
Weidenkaff, A., Ebbinghaus, S. G., Lippert, T., Ln1-xAxCoO3 (Ln=Er, La; A=Ca, Sr)/carbon nanotube composite materials applied for rechargeable Zn/Air batteries, Chem. Mater. 14, 1797–1805 (2002).
Tas, A. C., Majewski, P. J., Aldinger, F., Chemical preparation of pure and strontium-and/or magnesium-doped lanthanum gallate powders, J. Am. Ceram. Soc. 83, 2954–2960 (2000).
Alonso, J. A., Martinez-Lopez, M. J., Casais, M. T., Martinez, J. L., Demaseau, G., Largeteau, A., Garcia-Munoz, J. L., Munoz, A., Fernandez-Diaz, M. T., High-pressure preparation, crystal structure, magnetic properties, and phase transitions in GdNiO3 and DyNiO3 perovskites, Chem. Mater. 11, 2463–2469 (1999).
Todorovsky, D. S., Dumanova, D. G., Todorovska, R. V., Getsova, M. M., Preparation and characterization of yttrium-iron citric acid complexes, Croat. Chem. Acta 75, 155164 (2002).
Kwon, Y.J., Kim, K.H., Lim, C.S., Shim, K.B., Characterization of ZnO nanopowders synthesized by the polymerized complex method via an organochemical route, Journ. Ceram. Proc. Res. 3, 146–149 (2002).
Castro, R.H.R., Hidalgo, P., Mucillo, R., Gouvea, D., Microstructure and structure of NiO-SnO2 and Fe2O3-SnO2 systems, Appl. Surf. Sci. 214, 172–177 (2003).
Pereira-Ramos, J.-P., Electrochemical properties of cathodic materials synthesized by low-temperature techniques, J. Power Sources 54, 120–126 (1995).
Franger, S., Bach, S., Pereira-Ramos, J.-P, Baffier, N., Highly rechargeable LixMnO2+δ oxides synthesized via low temperature techniques, J. Power Sources 97–98, 344–348 (2001).
Franger, S., Bach, S., Farcy, J., Pereira-Ramos, J.-P, Baffier, N., Synthesis, structural and electrochemical characterization of the sol-gel birnessite Mn1,84 .0,6H2O, J. Power Sources 109, 344–348 (2001).
Julien, C., Letranchant, C., Rangan, S., Lemal, M., Ziolkiewicz, S., Castro-Garcia, S., El-Farh, L., Benkaddour, M., Layered LiNi0,5Co0,5O2 cathode materials grown by soft-chemistry via various solution methods, Mater. Sci. Eng. B76, 145–165 (2000).
Julien, C., Letranchant, C., Lemal, M., Ziolkiewicz, S., Castro-Garcia, S., Layered LiNi0,5Co0,5O2 compounds synthesized by a glycine-assisted combustion method for lithium batteries, J. Mater. Sci. 37, 2367–2375 (2002).
Castro-Garcia, S., Julien, C., Senaris-Rodriguez, M. A., Structural and electrochemical properties of Li-Ni-Co oxides synthesized by wet chemistry via a succinic-acid-assisted technique, Int. J. Inorg. Mat. 3, 323–329 (2001).
Prabahan, S. R. S., Saparil, N. B., Michael, S. S., Massot, M., Julien, C., Soft-chemistry syntethis of electrochemically-active spinel LiMn2O4 for Li-ion batteries, Solid State Ionics 112, 25–34 (1998).
Chitra, S., Kalyani, P., Vebka, B., Mohan, T., Haro-Poniatowski, E., Gangadharan, R., Julien, C., Synthesis, characterization and electrochemical studies of LiNiVO4 cathode material in rechargeable lithium batteries, Mater. Chem. Phys. 65, 32–37 (2000).
Julien, C., Camacho-Lopez, M. A., Mohan, T., Chitra, S., Kalyani, P., Gopukumar, S., Combustion synthesis and characterization of substituted lithium cobalt oxides in lithium batteries, Solid State Ionics 135, 241–248 (2000).
Prasad, S., Vijayalakshmi, A., Gajbhiye, N.S., Synthesis of ultrafine cobalt ferrite by thermal decomposition of citrate precursor, J. Therm. Anal. Calorim. 52, 5–10 (1998).
Kostromina, N. A., Complex compounds of cerium, neodim, and samarium with glyconic acid, J. Inorg. Chem. (Russ). 5, 95–101 (1960).
Kostromina, N. A., Comparative stability of glyconate complexes of rare earth metals, Ukr. Khim. Zhurn. 26, 299–304 (1960).
Frontiers in Material Science: Glasses and Amorphous Materials, Special Issue, Science267, 1924–1953 (1995).
Kirillov, S. A., Spatial disorder and low-frequency Raman pattern of amorphous solid, with special reference to quasi-elastic scattering and its relation to Boson peak, J. Mol. Struct. 479, 279–284 (1999).
Kirillov, S. A., Yannopoulos, S. N., Charge-current contribution to low-frequency Raman scattering from glass-forming ionic liquids, Phys. Rev. B, 61, 11391–11399 (2000).
Kirillov, S. A., Yannopoulos, S. N., Vibrational dynamics as an indicator of short-time interactions in glass-forming liquids and their possible relation to cooperativity, J. Chem. Phys., 117, 1220–1230 (2002).
Kalampounias, A. G., Yannopoulos, S. N., Steffen, W., Kirillova, L. I., Kirillov, S. A., Short-time dynamics of glass-forming liquids: Phenyl salicylate (salol) in bulk liquid, dilute solution, and confining geometries, J. Chem. Phys., 118, 8340–8349 (2003).
Kirillov, S. A., Novel approaches in spectroscopy of interparticle interactions. Raman line profiles and dynamics in liquids and glasses, J. Mol. Liq. 110, 99–103 (2004).
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Kirillov, S., Romanova, I., Farbun, I. (2006). SYNTHESIS OF MIXED OXIDES USING POLYBASIC CARBOXYLIC HYDROXY-AND AMINO-ACID ROUTES: PROBLEMS AND PROSPECTS. In: Barsukov, I.V., Johnson, C.S., Doninger, J.E., Barsukov, V.Z. (eds) New Carbon Based Materials for Electrochemical Energy Storage Systems: Batteries, Supercapacitors and Fuel Cells. NATO Science Series II: Mathematics, Physics and Chemistry, vol 229. Springer, Dordrecht. https://doi.org/10.1007/1-4020-4812-2_40
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DOI: https://doi.org/10.1007/1-4020-4812-2_40
Publisher Name: Springer, Dordrecht
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