Skip to main content

Part of the book series: NATO Science Series II: Mathematics, Physics and Chemistry ((NAII,volume 229))

Abstract

Polybasic carboxylic hydroxy and amino acid aided synthetic routes directed towards obtaining mixed inorganic materials, especially for battery and fuel cell applications, are overviewed. It has been shown that, in spite of enormous number of papers on the subject, significant efforts should be undertaken in order to understand the basic principles of these routes. Possible influence of the structure of reactants employed in the process (acids, poly hydroxy alcohols, metal salts) is put forward, and some directions of future work in the field are outlined.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

REFERENCES

  1. Materials for Lithium Ion Batteries, Ed. by C. Julien and Z. Stoynov, NATO Science Series 3. High Technology, Vol. 85, Kluwer, Dordreht, 2000.

    Google Scholar 

  2. Kirillov, S. A., Tsiakaras, P. E., Romanova, I. V., Adsorption and oxidation of methanol and ethanol on the surface of metallic and ceramic catalysts, J. Mol. Struct., 651–653, 365–370 (2003).

    Article  CAS  Google Scholar 

  3. Pechini, M., Method of preparing lead and alkaline earth titanates and niobates and coating method using the same form a capacitor, U.S.Pat. # 3330697, July 11, 1967.

    Google Scholar 

  4. Weidenkaff, A., Ebbinghaus, S. G., Lippert, T., Ln1-xAxCoO3 (Ln=Er, La; A=Ca, Sr)/carbon nanotube composite materials applied for rechargeable Zn/Air batteries, Chem. Mater. 14, 1797–1805 (2002).

    Article  CAS  Google Scholar 

  5. Tas, A. C., Majewski, P. J., Aldinger, F., Chemical preparation of pure and strontium-and/or magnesium-doped lanthanum gallate powders, J. Am. Ceram. Soc. 83, 2954–2960 (2000).

    Article  CAS  Google Scholar 

  6. Alonso, J. A., Martinez-Lopez, M. J., Casais, M. T., Martinez, J. L., Demaseau, G., Largeteau, A., Garcia-Munoz, J. L., Munoz, A., Fernandez-Diaz, M. T., High-pressure preparation, crystal structure, magnetic properties, and phase transitions in GdNiO3 and DyNiO3 perovskites, Chem. Mater. 11, 2463–2469 (1999).

    Article  CAS  Google Scholar 

  7. Todorovsky, D. S., Dumanova, D. G., Todorovska, R. V., Getsova, M. M., Preparation and characterization of yttrium-iron citric acid complexes, Croat. Chem. Acta 75, 155164 (2002).

    CAS  Google Scholar 

  8. Kwon, Y.J., Kim, K.H., Lim, C.S., Shim, K.B., Characterization of ZnO nanopowders synthesized by the polymerized complex method via an organochemical route, Journ. Ceram. Proc. Res. 3, 146–149 (2002).

    Google Scholar 

  9. Castro, R.H.R., Hidalgo, P., Mucillo, R., Gouvea, D., Microstructure and structure of NiO-SnO2 and Fe2O3-SnO2 systems, Appl. Surf. Sci. 214, 172–177 (2003).

    Article  CAS  Google Scholar 

  10. Pereira-Ramos, J.-P., Electrochemical properties of cathodic materials synthesized by low-temperature techniques, J. Power Sources 54, 120–126 (1995).

    Article  CAS  Google Scholar 

  11. Franger, S., Bach, S., Pereira-Ramos, J.-P, Baffier, N., Highly rechargeable LixMnO2+δ oxides synthesized via low temperature techniques, J. Power Sources 97–98, 344–348 (2001).

    Article  Google Scholar 

  12. Franger, S., Bach, S., Farcy, J., Pereira-Ramos, J.-P, Baffier, N., Synthesis, structural and electrochemical characterization of the sol-gel birnessite Mn1,84 .0,6H2O, J. Power Sources 109, 344–348 (2001).

    Article  Google Scholar 

  13. Julien, C., Letranchant, C., Rangan, S., Lemal, M., Ziolkiewicz, S., Castro-Garcia, S., El-Farh, L., Benkaddour, M., Layered LiNi0,5Co0,5O2 cathode materials grown by soft-chemistry via various solution methods, Mater. Sci. Eng. B76, 145–165 (2000).

    Article  Google Scholar 

  14. Julien, C., Letranchant, C., Lemal, M., Ziolkiewicz, S., Castro-Garcia, S., Layered LiNi0,5Co0,5O2 compounds synthesized by a glycine-assisted combustion method for lithium batteries, J. Mater. Sci. 37, 2367–2375 (2002).

    Article  Google Scholar 

  15. Castro-Garcia, S., Julien, C., Senaris-Rodriguez, M. A., Structural and electrochemical properties of Li-Ni-Co oxides synthesized by wet chemistry via a succinic-acid-assisted technique, Int. J. Inorg. Mat. 3, 323–329 (2001).

    Article  CAS  Google Scholar 

  16. Prabahan, S. R. S., Saparil, N. B., Michael, S. S., Massot, M., Julien, C., Soft-chemistry syntethis of electrochemically-active spinel LiMn2O4 for Li-ion batteries, Solid State Ionics 112, 25–34 (1998).

    Article  Google Scholar 

  17. Chitra, S., Kalyani, P., Vebka, B., Mohan, T., Haro-Poniatowski, E., Gangadharan, R., Julien, C., Synthesis, characterization and electrochemical studies of LiNiVO4 cathode material in rechargeable lithium batteries, Mater. Chem. Phys. 65, 32–37 (2000).

    Article  Google Scholar 

  18. Julien, C., Camacho-Lopez, M. A., Mohan, T., Chitra, S., Kalyani, P., Gopukumar, S., Combustion synthesis and characterization of substituted lithium cobalt oxides in lithium batteries, Solid State Ionics 135, 241–248 (2000).

    Article  CAS  Google Scholar 

  19. Prasad, S., Vijayalakshmi, A., Gajbhiye, N.S., Synthesis of ultrafine cobalt ferrite by thermal decomposition of citrate precursor, J. Therm. Anal. Calorim. 52, 5–10 (1998).

    Article  Google Scholar 

  20. Kostromina, N. A., Complex compounds of cerium, neodim, and samarium with glyconic acid, J. Inorg. Chem. (Russ). 5, 95–101 (1960).

    CAS  Google Scholar 

  21. Kostromina, N. A., Comparative stability of glyconate complexes of rare earth metals, Ukr. Khim. Zhurn. 26, 299–304 (1960).

    CAS  Google Scholar 

  22. Frontiers in Material Science: Glasses and Amorphous Materials, Special Issue, Science267, 1924–1953 (1995).

    Google Scholar 

  23. Kirillov, S. A., Spatial disorder and low-frequency Raman pattern of amorphous solid, with special reference to quasi-elastic scattering and its relation to Boson peak, J. Mol. Struct. 479, 279–284 (1999).

    Article  Google Scholar 

  24. Kirillov, S. A., Yannopoulos, S. N., Charge-current contribution to low-frequency Raman scattering from glass-forming ionic liquids, Phys. Rev. B, 61, 11391–11399 (2000).

    Article  CAS  Google Scholar 

  25. Kirillov, S. A., Yannopoulos, S. N., Vibrational dynamics as an indicator of short-time interactions in glass-forming liquids and their possible relation to cooperativity, J. Chem. Phys., 117, 1220–1230 (2002).

    Article  CAS  Google Scholar 

  26. Kalampounias, A. G., Yannopoulos, S. N., Steffen, W., Kirillova, L. I., Kirillov, S. A., Short-time dynamics of glass-forming liquids: Phenyl salicylate (salol) in bulk liquid, dilute solution, and confining geometries, J. Chem. Phys., 118, 8340–8349 (2003).

    Article  CAS  Google Scholar 

  27. Kirillov, S. A., Novel approaches in spectroscopy of interparticle interactions. Raman line profiles and dynamics in liquids and glasses, J. Mol. Liq. 110, 99–103 (2004).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2006 Springer

About this paper

Cite this paper

Kirillov, S., Romanova, I., Farbun, I. (2006). SYNTHESIS OF MIXED OXIDES USING POLYBASIC CARBOXYLIC HYDROXY-AND AMINO-ACID ROUTES: PROBLEMS AND PROSPECTS. In: Barsukov, I.V., Johnson, C.S., Doninger, J.E., Barsukov, V.Z. (eds) New Carbon Based Materials for Electrochemical Energy Storage Systems: Batteries, Supercapacitors and Fuel Cells. NATO Science Series II: Mathematics, Physics and Chemistry, vol 229. Springer, Dordrecht. https://doi.org/10.1007/1-4020-4812-2_40

Download citation

Publish with us

Policies and ethics