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THREE-GOLD CLUSTER AS PROTON ACCEPTOR IN NONCONVENTIONAL HYDROGEN BONDS O-H…Au AND N-H…Au

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Recent Advances in the Theory of Chemical and Physical Systems

Part of the book series: Progress in Theoretical Chemistry and Physics ((PTCP,volume 15))

Abstract

The present work extends the family of nonconventional proton acceptors to the coinage metal Au. Based on high level computations, we demonstrate the ability of the triangle three-gold cluster to behave as nonconventional proton acceptor and hence to form hydrogen bonds with conventional hydrogen bond donors. Three molecules: formic acid, alanine, and adenine, involving O-H and N-H groups as typical conventional hydrogen bond donors, are chosen for this purpose.

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Authors and Affiliations

  1. Department of Chemistry, Bat. B6c, University of Liege, Sart-Tilman, Liege 1, B-4000, Belgium

    E. S. KRYACHKO

  2. Bogoliubov Institute for Theoretical Physics, Kiev, 03143, Ukraine

    E. S. KRYACHKO

  3. Maítre de Recherche, FNRS (Belgium), Department of Chemistry, Bat. B6c, University of Liege, Sart-Tilman, Liege 1, B-4000, Belgium

    F. REMACLE

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  1. E. S. KRYACHKO
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Editors and Affiliations

  1. Laboratoire d&Etudes des Propriétés Electroniques des Solides, CNRS and UJF, Grenoble, France

    JEAN-PIERRE JULIEN

  2. Laboratoire de Chimie Physique, CNRS and UPMC, Paris, France

    JEAN MARUANI

  3. Laboratoire d&Etudes des Propriétés Electroniques des Solides, CNRS and UJF, Grenoble, France

    DIDIER MAYOU

  4. Rutherford Appleton Laboratory, Oxfordshire, U.K.

    STEPHEN WILSON

  5. Instituto de Matemáticas y Física Fundamental, CSIC, Madrid, Spain

    GERARDO DELGADO-BARRIO

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KRYACHKO, E., REMACLE, F. (2006). THREE-GOLD CLUSTER AS PROTON ACCEPTOR IN NONCONVENTIONAL HYDROGEN BONDS O-H…Au AND N-H…Au. In: JULIEN, JP., MARUANI, J., MAYOU, D., WILSON, S., DELGADO-BARRIO, G. (eds) Recent Advances in the Theory of Chemical and Physical Systems. Progress in Theoretical Chemistry and Physics, vol 15. Springer, Dordrecht. https://doi.org/10.1007/1-4020-4528-X_21

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