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Thermodynamic and Kinetic Aspects of Spontaneus Crystallization of Diamond and Cubic Boron Nitride

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Innovative Superhard Materials and Sustainable Coatings for Advanced Manufacturing

Part of the book series: NATO Science Series II: Mathematics, Physics and Chemistry ((NAII,volume 200))

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Abstract

Spontaneous crystallizations of diamond and cubic boron nitride at high pressure have been analyzed in terms of phase diagrams and rate of nucleation and crystal growth. It is shown that the position of low-temperature boundary of the diamond crystallization region in the p,T-diagram of carbon is defined by the line of metal-carbon eutectic (peritectic) reaction. Diamond-graphite equilibrium line defines the position of high-temperature boundary of the diamond crystallization region. For the fluid-containing systems, the position of the low-temperature boundary of the cBN crystallization region in the p,T-diagram of boron nitride is defined either by the line of the incongruent melting of the BN compound with the solvent, or by the kinetics of the cBN nucleation and crystal growth. The position of the high-temperature boundary of the p,T-region of the cBN crystallization is always defined by the kinetic factors.

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Author information

Authors and Affiliations

  1. Institute for Superhard Materials of the National Academy of Sciences of Ukraine, Ukraine

    V.Z. Turkevich

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  1. V.Z. Turkevich
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Editor information

Editors and Affiliations

  1. NSF Center for Intelligent Maintenance Systems, University of Wisconsin at Milwaukee, WI, USA

    Jay Lee

  2. Institute for Superhard Materials, National Academy of Sciences of Ukraine, Kiev, Ukraine

    Nikolay Novikov  & Vladimir Turkevich  & 

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Turkevich, V. (2005). Thermodynamic and Kinetic Aspects of Spontaneus Crystallization of Diamond and Cubic Boron Nitride. In: Lee, J., Novikov, N., Turkevich, V. (eds) Innovative Superhard Materials and Sustainable Coatings for Advanced Manufacturing. NATO Science Series II: Mathematics, Physics and Chemistry, vol 200. Springer, Dordrecht. https://doi.org/10.1007/1-4020-3471-7_2

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