Abstract
Changes and developments in the markets for synthesis gas and hydrogen, driven largely by environmental and remote gas monetization, are leading to innovation in the reaction engineering of syngas generation. The opportunities vary in scale from the order of liter volumes of catalyst (fuel cell hydrogen preparation) up to 100 te catalyst (gas-to-liquids). A variety of process options are available, based on steam reforming, partial oxidation and combinations thereof, with varying degrees of integration. Autothermal and Gas-Heated reforming designs are compared. The performance of a reforming process is critically dependent on design, operation and maintenance and aspects of this are reviewed.
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11. References
Abbott PEJ, Conduit MR & Mansfield K (1989) Methanol-A New Process for the 1990s, Proc. World Methanol Conf., Crocco & Associates Inc., Houston TX, Paper 14-1
Anon (1998) Looking Beyond the Internal Combustion Engine: the Promise of Methanol Fuel Cell Vehicles, American Methanol Institute Report, May 1998
Atkins M (2003) The transition from oil to natural gas as a fuel and feedstock, NATO-Advanced Study Institute, Sustainable Strategies for the Upgrading of Natural Gas: Fundamentals, Challenges, and Opportunities, Vilamoura, Portugal, 6–18 July, 2003
Fleisch, T (2003) Strategies, technologies and opportunities for oxygenates derived from light alkanes, NATO-Advanced Study Institute, Sustainable Strategies for the Upgrading of Natural Gas: Fundamentals, Challenges, and Opportunities, Vilamoura, Portugal, 6–18 July, 2003
Kvisle S et al. (2000) Methanol to Olefins Future Challenges, The Catalyst Group, CAP2000 Meeting, Lisbon, 13–14 Feb. 2000.
Prigent M (1997) On Board Hydrogen Generation for Fuel Cell Powered Electric Cars: Revue IFP, 52(3), 349–360.
Van Dijk CP & Fraley LD (1993) Process for Producing and Utilizing Oxygen Enriched Gas US Patent 5,245,110, 14 Sept 1993.
Agee KL (1989) Process and apparatus for the production of heavier hydrocarbons from gaseous light hydrocarbons US Patent 4,833,170, 23 May 1989.
Agee KL (1990) Apparatus for the production of heavier hydrocarbons from gaseous light hydrocarbons, US Patent 4,973,453, 27 Nov 1990.
Charlesworth RJ, Gough A & Ramshaw C (1995): Combustion and Steam Reforming of Methane on Thin Layer Catalysts for Use in Catalytic Plate Reactors: Proc 1st Int Conf.Sci.Eng.& Technol. of Intensive Processing, p85, Nottingham.
Piga A & Varykios XE, (2000) An advanced reactor configuration for partial oxidation of methane to synthesis gas, Catalysis Today, 60, 63–71.
Frauhammer J, Eigenberger G, Von Hippel L & Arntz (1999): A New Reactor Concept for Endothermic High Temperature Reactions: Chem. Eng. Sci, 54, 3661–3670.
Brophy JH & Telford CD (1988) Process for Producing Synthesis Gas by Partial Combustion of Hydrocarbons, US Patent 4,758,375, 19 July 1988
Sie ST (1993) Partial oxidation of a hydrocarbon-containing fuel using entrained catalyst, GB Patent 2,249,555, 16 Feb. 1993.
Hickman DA & Schmidt LD (1993) Production of Syngas by Direct Catalytic Oxidation of Methane, Science, 259, 343.
Pena MA, Gomez JP & Fierro JLG (1996) New Catalytic Routes for Syngas and Hydrogen Production: Applied. Catalysis A, 144, 7–57.
Eisenberg B et al. (1994) Advanced Gas Conversion Technology for Remote Natural Gas Utilisation, 73rd Gas Processors Association, New Orleans.
Armitage PM, Elkins KJ, Kitchen D & Pinto A (1992) Leading Concept Ammonia Process: First Two Years; AIChE Ammonia Plant Safety Meeting, 32.
Farnell PW (1995) Commissioning and Operation of ICI Katalco's Leading Concept Methanol Process, AIChE Ammonia Plant Safety Meeting.
Sogge J & Strom T (1997) Membrane Reactors-A New Technology for Production of Synthesis Gas by Steam Reforming: Studies Surf. Sci. Cat., 107, 561–566.
Balachandran U et al (1997) Ceramic Membrane Reactor for Converting Methane to Syngas: Catalysis Today, 36(3), 265–272
Sammells AF (1999) Catalytic Membrane Reactor Improvements for Syngas and Gas to Liquids: The Catalyst Group, CAP Annual Meeting, Clearwater Beach
a) Anon (1997) Oil & Gas Jnl, 95(31) p35 28 July 1997, & b) Anon (1997) Oil & Gas Jnl, 95(37) p37 8 Sept 1997
Brun-Tsekhovoi, AR Kurdumov SS, Sidorov NV & Katsobashvili YaR (1988) The Process of Catalytic Steam Reforming of Hydrocarbons in the Presence of a Carbon Dioxide Acceptor, Proc. 7th World Hydrogen Energy Conference, 2, 885
Kurdumov SS, Brun-Tsekhovoi AR & Rozental AL (1996) Steam conversion of Methane in the Presence of a Carbon Dioxide Acceptor: Petroleum Chemistry, 36(2), 139–143
Balasubramanian B, Lopez-Ortiz, Kaytakoglu S & Harrison DP (1999) Hydrogen from Methane in a Single Step Process, Chem. Eng. Sci. 54, 3543–3552
Anand M et al, Hufton J, Mayorga S, Nataraj S, Sircar S & Gaffney T (1996): Sorption Enhanced Reaction Process (SERP) for Production of Hydrogen, Proc US DOE Hydrogen Program Review, 1, 537–552
Farnell PW (1995) Commissioning and Operation of ICI Katalco's Leading Concept Methanol Process, AIChE Ammonia Plant Safety Meeting
Farnell PW (1999) Synetix's Advanced Gas Heated Reformer: AIChE Ammonia Plant Safety Meeting, Seattle, (27–30 Sept 1999)
Fitzpatrick TJ (2002) Large Scale Methanol Production using AGHR-based Syngas Generation, World Methanol Conference, Rome, 9–11 December, 2002
Tindall R (1998) Natural Gas Reforming Technologies: Intertech Conf, Gas to Liquids Processing, San Antonio, 18–20 Mar 1998
Karp AD & Dickenson RL (1998) Syngas Production for Gas-to-Liquids Applications: Technologies, Issues and Outlook: 2nd Annual Conf. Monetizing Stranded Gas Reserves, San Francisco, 14–16 Dec.1998
Abbott PEJ & Crewdson BJ (2003) Syngas Production for GTL Using Gas Heated Reforming — A Highly Efficient, Environmentally Friendly Process, CatCon 2003, Houston, TX, 5–6 May, 2003
Kirpatrick R & Fitzpatrick TJ (1999) A Methanol Technology for the 21st Century, World Methanol Conference, San Diego, 29 Nov–1 Dec (1999)
Cotton WC, Davies M & Fisher B (2003) Modeling Tools and Applications for Methanol Plants, IMTOF, London, July 2003
Lywood WJ (1996) Process Design, Rating and Performance. Twigg MV (Ed) Catalyst Handbook (2 nd Ed.), Manson Publishing
Farnell PW & Hughes RJ (1994) Secondary Reforming: Theory and Application, AIChE Ammonia Plant Safety Conf.
Mantle MD, Sederman AJ & Gladden LF (2001) Single-and two-phase flow in fixed-bed reactors: MRI flow visualization and lattice-Boltzmann simulations, Chem. Eng. Sci. 56, 523–529
Nijemeisland MJ & Dixon AG (2003) Simulation and Analysis of Gas Flow and Heat Transfer in a Wall-segment Model of an N=4 Fixed Bed of Spheres, A.I.Ch.E. Journal, submitted for publication
Dixon G, Nijemeisland MJ & Stitt EH (2003) CFD Simulation of Reaction and Heat Transfer Near the Wall of a Fixed Bed, Int. J. Chem. Reactor Eng, Vol. 1, paper A22 http://www.bepress.com/ijcre/vol1/A22.
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Stitt, E.H. (2005). Reactor Technology for Syngas and Hydrogen. In: Derouane, E.G., Parmon, V., Lemos, F., Ramôa Ribeiro, F. (eds) Sustainable Strategies for the Upgrading of Natural Gas: Fundamentals, Challenges, and Opportunities. NATO Science Series II: Mathematics, Physics and Chemistry, vol 191. Springer, Dordrecht. https://doi.org/10.1007/1-4020-3310-9_10
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DOI: https://doi.org/10.1007/1-4020-3310-9_10
Publisher Name: Springer, Dordrecht
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