Abstract
The objective of the investigation was to ascertain the status of Aluminum in Delhi soils by studying its speciation in the soil profile and to assess if there was any spatial variability. Soils representing the Aravali Ridge and the alluvial floodplains of river Yamuna were collected as a single, undisturbed core up to a depth of lm and the profile differentiated into four layers- 0–17 cm, 17–37 cm, 37–57 cm, and 57–86 cm. “Pseudo” total Aluminum and Iron in the soils were speciated into the “operationally” defined species (weakly exchangeable, organic matter complexes, amorphous oxides and hydroxides, and crystalline or “free” oxides) by widely recommended selective extraction procedures. Both Al and Fe in these soils are bound predominantly as Fe oxides and silicates and have only very low percentages in the easily mobilizable pools.
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References
Evans, C.E., Kamprath, E. J., Lime response as related to percent Al saturation, solution Al and organic matter content, Soil Sci Soc Am Proc 34, 1970, 893–896.
Barnhisel, R., Bertsch, P. M., Aluminum, in: Methods of Soil Analysis, Part 2, Chemical and Microbiological properties, ed. A. L. Page, Agronomy Monograph 9, ASA-SSSA, Madison, WI, 1982, pp. 275–300, ASIN 0891180729.
Driscoll, C.T., Aluminum in acidic surface waters: Chemistry, transport and effects, Environ Hlth Persp 63, 1985, 93–104.
Driscoll, C. T., Schecher, W. D., The chemistry of aluminum in the environment, Environ Geochem Health 12, 1990, 28–49.
Driscoll, C. T., Postek, K. M., The Chemistry of aluminum in surface waters, in: The environmental Chemistry of Aluminum, ed. G. Sposito, 2nd edition, CRC Lewis Publishers, Boca Raton, FL, 1996, pp. 364–418, ISBN 1566700302.
Zhu, X. P., Kotowski, M., Pawlowski, L., The relative importance of aluminum solid-phase component in agricultural soils treated with oxalic and sulphuric acids, in: Chemistry for the Protection of the Environment, 3, eds. L. Pawlowski, M.A. Gonzalez, M.R. Dudzinska, W.J. Lacy, Environmental Science Research, vol. 55, Plenum Press, N.York, 1998, pp. 245–254, ISBN 0-306-46026-2.
Haldar, A., Profiles and speciation of some heavy metals in Delhi soils, Ph. D. Thesis, Jawaharlal Nehru University, New Delhi, India, 1997.
Chibbar, R. K., Soils of Delhi and their management, in: Soils of India and their management, eds. B. C. Biswas, D. S. Yadav, S. Maheshwari, The Fertilizer Association of India, 1985, pp. 72–86.
Thomas, G. W., Exchangeable cations, in: Methods of Soil Analysis, Part 2, Chemical and Microbiological properties, ed. A. L. Page, Agronomy Monograph 9, ASA-SSSA, Madison, WI, 1982, pp. 159–165. ASIN 0891180729.
Juo, A. S. R., Kamprath, E. J., Copper chloride as an extractant for estimating the potentially reactive aluminum pool in acid soils, Soil Sci Soc Am J 43, 1979, 35–38.
McKeague, J. A., An evaluation of 0.1 M pyrophosphate and pyrophosphate-dithionite in comparison with oxalate as extractants of the accumulation products in podzols and some other soils, Can J Soil Sci, 47, 1967, 95–99.
McKeague, J. A., Day J. H., Dithionite-and oxalate-extractable Fe and Al as aids in differentiating various classes of soils, Can J Soil Sci 46, 1966, 13–22.
Holmgren, C. G. S., A rapid citrate dithionite extractable iron procedure, Soil Sci Soc Am Proc, 31, 1967, 210–211.
Netush, D., Hopke, P., Analytical aspects of environmental chemistry, John Wiley and Sons, NY, 1983, pp. 219–262.
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Muthukrishnan, S., Banerjee, D.K. (2005). Chemical Speciation of Aluminum in Delhi Soils. In: Mournighan, R., Dudzińska, M.R., Barich, J., Gonzalez, M.A., Black, R.K. (eds) Chemistry for the Protection of the Environment 4. Environmental Science Research, vol 59. Springer, Boston, MA. https://doi.org/10.1007/0-387-27448-0_6
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DOI: https://doi.org/10.1007/0-387-27448-0_6
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