Abstract
Performances of Zr(IV) loaded Diaion CRP200 (crosslinked polystyrene based methylenephosphonic acid resin) as specific adsorbent for phosphate, arsenate, and arsenite were evaluated by columnar approach. Phosphate and arsenate were adsorbed under weakly acidic conditions. Adsorbed phosphate and arsenate were quantitatively eluted by 0.1 M aqueous sodium hydroxide. After the elution operation, the adsorbent was able to regenerate by supplying a dilute sulfuric acid solution containing Zr(IV) to the column. Interestingly, breakthrough capacities were enhanced by repeating these adsorption-elution-regeneration operations up to 10 times and attained to the stationary ones of ca. 0.14 – 0.15 mmol/ml-Resin at until 1% breakthrough points. In addition, the proposed adsorbent was able to take up selectively both phosphate and arsenate even in the presence and chloride and sulfate in large excess. The most outstanding performances were observed in the adsorption of arsenite after complete washing the alkali-treated column with water; arsenite was much more strongly adsorbed than phosphate and arsenate. Then, the regeneration of the column was able to achieve by complete washing with water. The adsorption-elution-regeneration cycle was totally repeated by more than 40 times for ca. 2 years but no deterioration of the column performances was observed.
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Jyo, A., Kudo, S., Zhu, X., Yamabe, K. (2005). Zirconium(IV) Loaded Diaion CRP200 Resin as a Specific Adsorbent to as(III) and as(V). In: Mournighan, R., Dudzińska, M.R., Barich, J., Gonzalez, M.A., Black, R.K. (eds) Chemistry for the Protection of the Environment 4. Environmental Science Research, vol 59. Springer, Boston, MA. https://doi.org/10.1007/0-387-27448-0_3
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DOI: https://doi.org/10.1007/0-387-27448-0_3
Publisher Name: Springer, Boston, MA
Print ISBN: 978-0-387-23020-7
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