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Copper Biomolecules in Solution

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Biomedical EPR, Part A: Free Radicals, Metals, Medicine, and Physiology

Part of the book series: Biological Magnetic Resonance ((BIMR,volume 23))

Abstract

For copper(II) in biological systems, and even for small copper complexes in fluid solution at room temperature, the CW lineshapes are strongly influenced by molecular motion. The intermediate tumbling lineshapes for Cu(II) complexes have been analyzed using the stochastic Liouville equations. Various methods of analysing Cu(II) spectra are presented. Examples are given for complexes of peptides, phenanthroline plus glutathione, bleomycin, and β-casomorphins The methods could be extended to other paramagnetic metal ions.

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  1. Department of Chemistry, University of Siena, Siena, Italy

    Riccardo Basosi, Giovanni Della Lunga & Rebecca Pogni

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  1. Riccardo Basosi
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  1. University of Denver, Denver, Colorado

    Sandra R. Eaton , Gareth R. Eaton  & Lawrence J. Berliner ,  & 

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Basosi, R., Della Lunga, G., Pogni, R. (2005). Copper Biomolecules in Solution. In: Eaton, S.R., Eaton, G.R., Berliner, L.J. (eds) Biomedical EPR, Part A: Free Radicals, Metals, Medicine, and Physiology. Biological Magnetic Resonance, vol 23. Springer, Boston, MA. https://doi.org/10.1007/0-387-26741-7_13

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